Phase-amplitude coupling factor of single-mode gain-switchedInGaAsP laser diodes

The phase amplitude coupling factor (α-factor) of gain-switched InGaAsP laser diodes is deduced from chirp measurements. A tunable laser scheme makes it possible to obtain the wavelength dependence of α over ~40 nm. The α-values are found to be higher than those deduced from spontaneous emission spectra below threshold. It is shown that the difference is explained by the dependence of α with carrier density. Time-resolved measurements of spontaneous emission during pulse buildup reveal that the carrier density at maximum can be 1.5 times higher than the threshold carrier density. Experimental evolutions of α are well reproduced by calculations     

Investigation of relaxation of nanodiamond surface in real and reciprocal spaces

The structure of a nanodiamond powder with an average grain size of 5 nm was investigated using large-Q neutron diffraction. Both Bragg scattering and PDF analysis were employed. The effect of annealing under vacuum at temperatures up to 1200 °C was studied. The studies lead to a tentative model of nanocrystalline diamond, where the core with a perfect diamond lattice is surrounded by a shell of compressed diamond lattice, and this core–shell structure is enveloped in a non-diamond carbon. The non-diamond envelope of nanograins, a “gas-like” carbon, is stable up to 1000 °C and transforms into a graphite phase (an onion-type structure) at about 1200 °C. The amount of non-crystalline carbon in the powder annealed below 1000 °C is about 10%. In the sample annealed at 1200 °C a graphite-type carbon, with a total of about 15% of sp² bonds is formed.     

Healing Effect of Controlled Anti‐Electromigration on Conventional and High‐Tc Superconducting Nanowires

The electromigration process has the potential capability to move atoms one by one when properly controlled. It is therefore an appealing tool to tune the cross section of monoatomic compounds with ultimate resolution or, in the case of polyatomic compounds, to change the stoichiometry with the same atomic precision. As demonstrated here, a combination of electromigration and anti‐electromigration can be used to reversibly displace atoms with a high degree of control. This enables a fine adjustment of the superconducting properties of Al weak links, whereas in Nb the diffusion of atoms leads to a more irreversible process. In a superconductor with a complex unit cell (La_2?x Ce_x CuO₄), the electromigration process acts selectively on the oxygen atoms with no apparent modification of the structure. This allows to adjust the doping of this compound and switch from a superconducting to an insulating state in a nearly reversible fashion. In addition, the conditions needed to replace feedback controlled electromigration by a simpler technique of electropulsing are discussed. These findings have a direct practical application as a method to explore the dependence of the characteristic parameters on the exact oxygen content and pave the way for a reversible control of local properties of nanowires.     

A linear algorithm for conformal 3D-to-flatness coordinates conversion

Data conversion from a 3D raster to spiral coordinates is the key function in the scanning process for Roll Powder Sintering (RPS) additive manufacturing technology. Conversion process is especially important, as it produces the basis for a processed object. There are many equations for such conformal transformation, but there is still room to improve the computation efficiency. This paper presents an efficient conversion algorithm, which processes 3D objects and linear transforming it into rolling ribbon. The new algorithm has several significant advantages over the old ones due to applying only one main linear equation. The program based on the linear algorithm is simpler, more compact and faster in comparison to other programs which use trigonometric, transcendental or other equations. The proposed algorithm has been developed and extensively tested on several parts of computer-aided design models for RPS processing.     

Tunable picosecond blue and ultraviolet pulses from a diode-pumped laser system seeded by a gain-switched laser diode

Picosecond pulses emitted from a gain-switched laser diode have been amplified in a Ti:sapphire regenerative amplifier indirectly pumped by a 4-W laser diode. This all-solid-state system produced microjoule pulses tunable from 803 to 840 nm at repetition rates up to 25 kHz with durations of 70-100 ps. By frequency doubling and tripling the output, we generated blue and UV pulses tunable from 401 to 420 nm and from 268 to 280 nm, respectively. Average powers larger than 4 mW were reached in these two wavelength regions.     

A natural gas cash-out problem: A bilevel programming framework and a penalty function method

One of the many complex problems that arise from the transmission and marketing of natural gas is when a shipper draws a contract with a pipeline company to deliver a certain amount of gas among several points. What is actually delivered is often different from the amount that had been originally agreed upon. This phenomenon is called an imbalance. When an imbalance occurs, the pipeline penalizes the shipper by imposing a cash-out penalty policy. Since this penalty is a function of the operating daily imbalances, an important decision-making problem for the shippers is how to carry out their daily imbalances so as to minimize their incurred penalty. In this paper, we introduce the problem of minimizing the cash-out penalty costs from the point of view of a natural gas shipping party. We present a mixed integer bilevel linear programming model and discuss its underlying assumptions. To solve it efficiently, we reformulate it as a standard mathematical program and describe a penalty-function algorithm functions for its solution. The algorithm is well-founded and its convergence is proved. Results of numerical experiments support the algorithm’s robustness providing a valuable solution technique for this very important and complex problem in the natural gas market.     

Neutrophils Mediate Pulmonary Artery Thrombosis In Situ

Pulmonary embolism is a life-threatening condition, which can result in respiratory insufficiency and death. Blood clots occluding branches of the pulmonary artery (PA) are traditionally considered to originate from thrombi in deep veins (usually in legs). However, growing evidence suggests that occlusion of the vessels in the lungs can develop without preceding deep vein thrombosis (DVT). In this work, we used an inferior vena cava (IVC) complete ligation model of DVT in Wistar rats to explore the possibility and mechanisms of PA thrombosis under the conditions where all routes of thrombotic mass migration from peripheral veins are blocked. We demonstrate that rats both with normal and reduced neutrophil counts developed thrombi in the IVC, although, neutropenia caused a substantial decrease in thrombus size and a shift from fresh fibrin toward mature fibrin and connective tissue inside the thrombus. Massive fibrin deposition was found in the PA branches in the majority of DVT rats with normal neutrophil counts, but in none of the neutropenic animals. Neutrophil ablation also abolished macroscopic signs of lung damage. Altogether, the results demonstrate that thrombi in the lung vasculature can form in situ by mechanisms that require local neutrophil recruitment taking place in the DVT setting.     

Morphology, optical, and photoelectrochemical properties of electrodeposited nanocrystalline ZnO films sensitized with Cd x Zn1−x S nanoparticles

Nanocrystalline ITO/ZnO films formed by porous zinc oxide microplatelets 1–3 μm in size and 100–200 nm in thickness, which consist of 30–50 nm ZnO crystallites, were sensitized to visible light by Cd _x Zn_1?x S nanocrystals deposited using the method of successive ionic layer adsorption and reaction (SILAR). The composition of Cd _x Zn_1?x S nanocrystals as well as the dependence between molar Cd(II) fraction in the films and the ratio of cadmium and zinc nitrate concentrations in solutions used for the SILAR procedure were determined by a combination of electron, Raman, and energy-dispersive X-ray spectroscopies. The photovoltage observed at illumination of the ITO/ZnO/Cd _x Zn_1?x S heterostructures by white light (λ >400 nm) in aqueous Na₂S solution increases with a decrease of Cd(II) content proportionally to an increment in the conduction band potential of the Cd _x Zn_1?x S nanocrystals. The photocurrent density normalized to the light absorbance of the ITO/ZnO/Cd _x Zn_1?x S films increases by a factor of around four when the conduction band potential of Cd _x Zn_1?x S nanocrystals grows by 220 mV as a result of Cd(II) fraction changing from 1.0 to 0.62–0.67. The results show that Cd _x Zn_1?x S solid solutions are more advantageous sensitizers for the short-wavelength part of the sensitivity window of the liquid-junction solar cells (400–450 nm) than conventionally used cadmium sulfide.     

A Preparative Method for the Isolation of Calponin from Molluscan Catch Muscle

We describe the development of a preparative method to isolate molluscan catch muscle, calponin. This method is based on the ability of calponin to interact with actin in a temperature-dependent manner. After extracting thin filaments, as previously described, the extract was ultracentrifuged at 2 °C. While other surface proteins of thin filaments co-precipitated with actin, calponin, along with some minor contaminants, remained in the supernatant. Calponin was purified through cation-exchange chromatography. The yield of pure protein was four-fold higher than that achieved through high-temperature extraction. To evaluate functionally isolated proteins, we determined the effect of calponin on Mg²⁺-ATPase activity of hybrid and non-hybrid actomyosin. The degree of ATPase inhibition was consistent with previously published data but strongly dependent on the environmental conditions and source of actin and myosin used. Furthermore, at low concentrations, calponin could induce the ATPase activity of hybrid actomyosin. This result was consistent with data indicating that calponin can modulate actin conformation to increase the relative content of “switched on” actin monomers in thin filaments. We assume that calponin obtained by the isolation method proposed herein is a fully functional protein that can both inhibit and induce the ATPase activity.     

Interval and Twin Arithmetics

The problem of finding inner and outer estimations of the range of values of a real function is considered. An overview of interval arithmetics being used for improvement of outer estimations is given. The twin arithmetic is introduced for simultaneous inner and outer estimations and directed twin arithmetic is proposed as generalization of the directed interval arithmetic.