Resistive superconducting transition of κ-type BEDT-TTF organic superconductors in a magnetic field

The superconducting transition of the organic compoundsκ-(BEDT-TTF)₂ X is studied by resistive measurement in a magnetic field up to 10 T applied normal to the conducting plane. For the salts withX=Cu[N(CN)₂]Br andX=CuCN[N(CN)₂] the transition shows fanshaped broadening caused by superconductivity fluctuation. For theX=Cu(NCS)₂ salt the resistivity shows a peak in the transition region in a magnetic field below 4 T.This phenomenon is suppressed in defect-reduced samples for intralayer conduction. We discuss this peak in relation to the thermal fluctuation on the Josephson junction structures in this salt.     

Plastic deformation of bcc metal thin foils without dislocation

Heavy plastic deformation of fcc metal thin foils to fracture has been found recently to proceed without involving dislocations, and it results in the formation of high density of vacancy clusters. Thin foil specimens of bcc metals such as V and Mo were plastically deformed to fracture in in situ elongation experiments under an electron microscope. Morphology of thinning and fracture was found to be similar to fcc metals, and no dislocation was observed during heavy deformation. Electron diffraction analysis at the tip of a crack during deformation confirmed a large elastic deformation of up to 5%. Unlike in fcc metal thin foil specimens, point defect clusters were not observed near fractured tips. This difference is attributed to the difference in vacancy reaction, though the deformation in bcc metals without dislocation most likely does produce vacancies.     

Ethanol production from raw starch by a recombinant yeast having saccharification and fermentation activities

In order to develop a method for converting raw starch into ethanol efficiently, direct fermentation of ozonized raw starch using a recombinant yeast was investigated. Ozonolysis was carried out as a pretreatment to convert raw starch into ethanol rapidly and efficiently, and then the effect of the ozone degradation conditions on the degree of polymerization and the amount of amylose in a raw starch was determined. Since the degree of polymerization was low and the amount of amylose was high, raw starch treated with an ozone concentration of 40 gm^?3 and an ozonation time of 30 min was the material chosen for alcohol fermentation. Though the recombinant yeast could not convert the untreated raw starch, it converted the soluble starch and the ozonized raw starch at a comparatively high yield into ethanol. About 56% of the ozonized raw starch decomposed, and the ethanol concentration obtained from the ozonized raw starch was markedly greater than that obtained from untreated raw starch. The dynamic behavior of cell growth, substrate degradation, and ethanol production was examined in a continuous culture under various dilution rates, and the optimal dilution rate, ie 0.15 h^?1, was determined for maximizing the ethanol productivity (amount of ethanol produced per unit time). © 2002 Society of Chemical Industry     

Efficient usage of highly dispersed Pt on carbon nanotubes for electrode catalysts of polymer electrolyte fuel cells

A Pt-deposited carbon nanotube (CNT) shows higher performance than a commercial Pt-deposited carbon black (CB) with reducing 60% Pt load per electrode area in polymer electrolyte fuel cells (PEFCs) below 500 mA/cm². K₂PtCl₄ and H₂PtCl₆·6(H₂O) are used for the Pt deposition onto multi-walled CNTs (MWCNTs), which are produced by the catalytic decomposition of hydrocarbons. The electric power densities produced using the Pt/CNT electrodes are greater than that of the Pt/CB by a factor of two to four on the basis of the Pt load per power. CNTs are thus found to be a good support of Pt particles for PEFC electrodes. TEM images show 2–4-nm Pt nanoparticles dispersed on the CNT surfaces. These high performances are considered to be due to the efficient formation of the triple-phase boundaries of gas–electrode–electrolyte. The mechanisms of Pt deposition are discussed for these Pt-deposited CNTs.     

Corrosion of silicon nitride ceramics under hydrothermal conditions

Corrosion behaviour of Si₃N₄ ceramics containing Y₂O₃, Al₂O₃ and AIN as sintering aids was investigated under hydrothermal conditions at 200–300 C and saturated vapour pressures of water for 1–10 days. Hydrothermal corrosion resulted in the dissolution of the Si₃N₄ matrix and the formation of a product layer consisting of the original grain-boundary phases and hydrated silica. The dissolution rate of Si₃N₄ ceramics decreased with decreasing crystallinity of the grain-boundary phase. The dissolution rate could be adequately described by a parabolic plot in the initial stage of the reaction. The apparent activation energies were 83.5–108 kJ mol^–1, and the bending strength of the corroded samples decreased from 600 to 400 MPa in the initial stage of the reaction upto a weight loss of 0.004 g cm^–2, and then was almost constant up to a weight loss of 0.012 g cm^–2.     

A high‐performance sorting algorithm for multicore single‐instruction multiple‐data processors

Many sorting algorithms have been studied in the past, but there are only a few algorithms that can effectively exploit both single‐instruction multiple‐data (SIMD) instructions and thread‐level parallelism. In this paper, we propose a new high‐performance sorting algorithm, called aligned‐access sort (AA‐sort), that exploits both the SIMD instructions and thread‐level parallelism available on today's multicore processors. Our algorithm consists of two phases, an in‐core sorting phase and an out‐of‐core merging phase. The in‐core sorting phase uses our new sorting algorithm that extends combsort to exploit SIMD instructions. The out‐of‐core algorithm is based on mergesort with our novel vectorized merging algorithm. Both phases can take advantage of SIMD instructions. The key to high performance is eliminating unaligned memory accesses that would reduce the effectiveness of SIMD instructions in both phases. We implemented and evaluated the AA‐sort on PowerPC 970MP and Cell Broadband Engine platforms. In summary, a sequential version of the AA‐sort using SIMD instructions outperformed IBM's optimized sequential sorting library by 1.8 times and bitonic mergesort using SIMD instructions by 3.3 times on PowerPC 970MP when sorting 32 million random 32‐bit integers. Also, a parallel version of AA‐sort demonstrated better scalability with increasing numbers of cores than a parallel version of bitonic mergesort on both platforms. Copyright © 2011 John Wiley & Sons, Ltd.     

粉末注射成形奥氏体不锈钢的疲劳和冲击强度

本文的目的是研究粉末性能对粉末注射成形奥氏体不锈钢的力学性能(特别是疲劳和冲击强度)的影响。试样用混有聚酰氨粘结剂系的水雾化(WA)和气雾化(GA)粉末制成。注射坯在空气中脱粘，而后在不同温度、不同保温时间下真空烧结。粉末性能对烧结体的密度、显微组织和力学性能有显著影响。孔和析出物显示出Ostward时效，而孔和析出物的长大满足Lifshitz-Wagner方程。WA和GA粉末试样的疲劳极限分别约为300MPa和310MPa。它们的疲劳强度略低于常规锻材。烧结体的冲击值随密度增加线性增大。     

LaBGeO5 single crystals in glass and second-harmonic generation

Flower-shaped crystals with diameters of 100–200 μm consisting of LaBGeO₅ (LBGO) single crystals similar to petals were observed in the interior of transparent LBGO surface-crystallized glasses. Each flower-shaped crystal was radially grown from the surface of the included bubbles. A more intense second-harmonic generation was observed from the LBGO crystallized glasses with the flower-shaped LBGO single crystals compared to the samples without such crystals based on the Maker fringe technique and second-harmonic (SH) generation microscopy. The SH intensity for the flower-shaped LBGO single crystals monotonically decreased with increasing temperature up to 350 °C, less than the Curie temperature reported so far (530 °C). It is considered that the internal compressive stress induced by the difference in the thermal expansion between the LBGO single crystal and the corresponding glass affect the ferroelectric property of the flower-shaped LBGO single crystals in glass.