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1.
2.
Synthesis, absolute configuration, and analysis of malathion, malaoxon, and isomalathion enantiomers
Syntheses of the enantiomers of malathion, malaoxon, and isomalathion are reported herein. Malathion enantiomers were prepared from (R)- or (S)-malic acid in three steps. Enantiomers of malathion were converted to the corresponding enantiomers of malaoxon in 52% yield by oxidation with monoperoxyphthalic acid, magnesium salt. The four isomalathion stereoisomers were prepared via two independent pathways using strychnine to resolve the asymmetric phosphorus moiety. The absolute configurations of the four stereoisomers of isomalathion were determined by X-ray crystallographic analysis of an alkaloid salt precursor. A high-performance liquid chromatography technique was developed to resolve the four stereoisomers of isomalathion, and to determine their stereoisomeric ratios. 相似文献
3.
Thai Binh Wan Rachel Seneviratne Aruna Rakotoarivelo Thierry 《Mobile Networks and Applications》2003,8(1):27-36
The high expectations and demand for users to access the Internet from anywhere at anytime has made user mobility an important part of the design and development of the next generation mobile communications and computing. Traditionally user mobility has been divided into two areas: Terminal Mobility and Personal Mobility. In recent years terminal mobility has focused on the movement of the terminal and developed extensions to IP protocols such as Mobile IP. In contrast, personal mobility has only received limited attention, and is somewhat lagging behind. This research has either focussed on personal mobility in communications or personalisation of operating environments. As a result, to date no framework for providing true personal mobility has emerged. In this paper, we introduce a new personal mobility framework called IPMoA (Integrated Personal Mobility Architecture), which integrates both aspects of personal mobility to provide a complete personal mobility solution, and illustrate the viability of this approach through a proof-of-concept implementation. 相似文献
4.
In order to know the limit of validity of the concept of hydrical diffusivity, DW, we tried to validate the Boltzmann's method used to identify it. We show that for a medium strictly satisfying the equation of diffusion, the method gives quite good results with nevertheless some inaccuracies for the extreme values of water contents. For the real studied material, a backed clay, its identification becomes more difficult because of the dispersion of the wetting phenomenon observed for different specimens of the same material. We are showing that the mean behaviour of one sample is near to be the same as the more probable behaviour of all the samples. Otherwise the values of DW determined for a wetting cannot be used to describe a drying process. It practical interest is then considerably reduced. In order to test the influence of the gas phase pressure effects on the behaviour of the material, we have determined all the parameters necessary to describe, numerically, wetting and drying processes without to resort to DW. We noticed an overpressure of the gas phase inside the material due to drying. If the gas pressure effects are, numerically, switched off, we cannot notice any influence on water content profiles for this type of material. 相似文献
5.
Giuseppe G. G. Manzardo Sandra Kürsteiner-Laube und Daniel Perrin 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1996,203(6):501-506
In diethyl ether extracts from celeriac (Apium graveolens L. var.rapaceum) all four stereoisomers of (3a–7a)-cis-3-butylhexahydrophthalide were found to be present. The analyses were carried out by means of GC, enantioselective GC and GC-MS. The assignment of the relative configuration of the diastereomers3 and4 was accomplished by NOE difference spectroscopy. 相似文献
6.
Mixture-proportioning of high-performance concrete 总被引:6,自引:0,他引:6
The paper presents a new approach to design concrete mixtures. It is based upon a set of models relating composition and engineering properties of concrete, to be implemented into software, linked with a material database. The principles underlying the various models are summarized, most of which focus on the granular structure of fresh/hardened concrete. A global approach to concrete is promoted, where performance specifications can be formulated in terms of fresh concrete (yield stress, plastic viscosity, slump and air content), hardening concrete (adiabatic temperature rise and autogenous shrinkage) and hardened concrete (compressive strength at any age, tensile strength, elastic modulus, creep and shrinkage). This approach is illustrated through the design of a special high-shrinkage high-performance concrete (HPC) for road application. To date, durability is lacking in the model and requires further research. 相似文献
7.
A new theory of similarity, rooted in the detection and recognition literatures, is developed. The general recognition theory assumes that the perceptual effect of a stimulus is random but that on any single trial it can be represented as a point in a multidimensional space. Similarity is a function of the overlap of perceptual distributions. It is shown that the general recognition theory contains Euclidean distance models of similarity as a special case but that unlike them, it is not constrained by any distance axioms. Three experiments are reported that test the empirical validity of the theory. In these experiments the general recognition theory accounts for similarity data as well as the currently popular similarity theories do, and it accounts for identification data as well as the longstanding "champion" identification model does. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
8.
M. Le Pallec C. Kazmierski E. Vergnol S. Perrin J.G. Provost P. Doussiere G. Glastre D. Carpentier S. Fabre 《Photonics Technology Letters, IEEE》2003,15(3):362-364
Integrated laser modulators are attractive devices for wavelength-division-multiplexing optical systems due to their compactness, high output power, and low cost. Their fabrication simplicity is a way to decrease further the transmitter cost and address new opening markets of short range and metropolitan networks. We report a new integration scheme electroabsorption-modulator distributed feedback (DFB) laser based on well-established industrial solutions for discrete buried ridge (BRS) DFB lasers and discrete shallow ridge modulators. Processing simplification with an identical active layer has been possible due to a good behavior of strongly positively detuned BRS lasers. The integrated devices demonstrated 30-dB extinction ratio with 10-GHz bandwidth and P/sub out/=10 dBm for emission in 1.55-/spl mu/m range. 相似文献
9.
The IEEE 802.11e medium access control (MAC) layer protocol is an emerging standard to support quality of service (QoS) in
802.11 wireless networks. Some recent work shows that the 802.11e hybrid coordination function (HCF) can improve significantly
the QoS support in 802.11 networks. A simple HCF referenced scheduler has been proposed in the 802.11e which takes into account
the QoS requirements of flows and allocates time to stations on the basis of the mean sending rate. As we show in this paper,
this HCF referenced scheduling algorithm is only efficient and works well for flows with strict constant bit rate (CBR) characteristics.
However, a lot of real-time applications, such as videoconferencing, have some variations in their packet sizes, sending rates
or even have variable bit rate (VBR) characteristics. In this paper we propose FHCF, a simple and efficient scheduling algorithm
for 802.11e that aims to be fair for both CBR and VBR flows. FHCF uses queue length estimations to tune its time allocation
to mobile stations. We present analytical model evaluations and a set of simulations results, and provide performance comparisons
with the 802.11e HCF referenced scheduler. Our performance study indicates that FHCF provides good fairness while supporting
bandwidth and delay requirements for a large range of network loads.
Pierre Ansel received a multidisciplinary in-depth scientific training in different fields such as Pure and Applied Mathematics, Physics,
Mechanics, Computer Science and Economics from the Ecole Polytechnique, Palaiseau, France. Then, he joined the Ecole Nationale
Superieure des Telecommunications, Paris, France in 2005 where he went further into electronics, databases, computer network
security and high speed networks. He received a multidisciplinary master of sciences degree and an additional master of sciences
degree in telecommunications in 2005. He did a summer internship in 2003 in INRIA, Sophia Antipolis, France where he worked
on the Quality of Service in 802.11 networks at Planete Group, France. Then in 2004, he joined France Telecom R&D, Issy-les-Moulineaux,
France to work on Intranet Security issues. He designed a WiFi security supervision architecture based on WiFi Intrusion Detection
Sensors. He is currently a French civil servant and belongs to the French Telecommunications Corps.
Qiang Ni received the B.Eng., M.Sc. and Ph.D. degrees from Hua Zhong University of Science and Technology (HUST), Wuhan City, China
in 1993, 1996 and 1999 respectively. He is currently a faculty member in the Electronic and Computer Engineering Division,School
of Engineering and Design, Brunel University, West London, U.K. Between 2004 and 2005 he was a Senior Researcher at the Hamilton
Institute, National University of Ireland, Maynooth. From 1999 to 2001, he was a post-doctoral research fellow in the multimedia
and wireless communication laboratory, HUST, China. He visited and conducted research at the wireless and networking group
of Microsoft Research Asia Lab during the year of 2000. From Sept. 2001 until may 2004, he was a research staff member at
the Planète group of INRIA Sophia Antipolis France. Since 2002, he has been active as a voting member at the IEEE 802.11 wireless
LAN standard working group. His current research interests include communication protocol design and performance analysis
for wireless networks, cross-layer optimizations, vertical handover and mobility management in mobile wireless networks, and
adaptive multimedia transmission over hybrid wired/wireless networks. He has authored /co-authored over 40 international journal/conference
papers, book chapters, and standard drafts in this field. He is a member of IEEE. E-mail: Qiang.Ni@ieee.org
Thierry Turletti received the M.S. (1990) and the Ph.D. (1995) degrees in computer science both from the University of Nice – Sophia Antipolis,
France. He has done his PhD studies in the RODEO group at INRIA Sophia Antipolis. During the year 1995–96, he was a postdoctoral
fellow in the Telemedia, Networks and Systems group at LCS, MIT. He is currently a research scientist at the Planete group
at INRIA Sophia Antipolis. His research interests include multimedia applications, congestion control and wireless networking.
Dr. Turletti currently serves on the Editorial Board of Wireless Communications and Mobile Computing. 相似文献
10.
Didier Perrin Céline Guillermain Anne Bergeret José-Marie Lopez-Cuesta Gilles Tersac 《Journal of Materials Science》2006,41(12):3593-3602
A new process of management of waste of composite materials from Sheet Moulding Compounds (SMC), as reinforcing fillers for
thermoplastic materials, including both mechanical and chemical processes is proposed in this paper. Communited SMC being
composed of coated glass fibres intimately mixed with calcium carbonate powder, their reinforcing power is low. First, the
fibrous part was increased by partial dissolution of calcium carbonate present in the crushed products SMC. Second, a process
of partial solvolysis was developed aiming at strong increasing the interfacial mechanical properties by functionalising of
SMC load incorporated into polypropylene/grafted maleic anhydride polypropylene (PP/PPgma). At this effect, we investigated a treatment with a hot triamine (diethylenetriamine, DETA) in order to create a functionalisation,
after scission of the bond ester of unsaturated polyester, as bridging amino-succinimide.The effect of this recycling way
by partial solvolysis was checked from the mechanical properties of the resulting reinforced PP/PPgma material: Although a lower of Young modulus, better yield stress and especially resilience were observed. 相似文献