Electrical and magnetic properties of lithium borate glass containing iron

Journal of Materials Science Letters -     

Selectivity Enhancement to the Exclusive Formation of Ethyltoluenes and Hydrogen During Dehydroalkylation of Toluene with Ethane

The dehydroalkylation of toluene with ethane to the isomeric ethyltoluenes was studied on 0.4Pt/H-ZSM-5 at varying contact times (1/WHSV). At a high contact time of 1.0 h, toluene disproportionation and hydrogenolysis reactions dominate, resulting in low selectivity to the desired ethyltoluenes via the alkylation reaction. However, at a low contact time of 0.12 h side reactions are eliminated, resulting in maximum selectivities to the kinetically favored ethyltoluenes and hydrogen. Results at high selectivities to ethyltoluenes provide significant insight into reaction pathways.     

Effect of doping polyacrylic acid with some dopants as studied by different techniques

The molecular weight of polyacrylic acid (PAA) was determined by a viscometric method using NaNO₃ as solvent at 30°C. The specific electric conductivities (σ) of PAA as well as PAA doped with carbon black (CB), chromium oxide (Cr₂O₃), and cupferron with different concentrations (from 0.25 to 1 wt %) were measured at a temperature range 360–400 K. IR spectra of some polymers were determined and it was shown that when PAA was doped with 0.5 wt % CB, a C? O? C band appeared at 775–875 cm^?1. The positron annihilation lifetime (PAL) spectra in PAA doped with the above‐mentioned dopants were measured as a function of their concentrations. It was observed that the short lifetime intensity I₁ decreased, whereas the intermediate lifetime intensity I₂, which is related to the conductivity of the material, increased with increasing the wt % of Cr₂O₃ and cupferron as well as at low concentrations of CB. These results are discussed in terms of the conducting island model. It was found that there were distinct positive relationships between σ and I₂. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 877–883, 2002; DOI 10.1002/app.10381     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

Simulation of Natural Depletion and Miscible Gas Injection Effects on Asphaltene Stability in Petroleum Reservoir Fluids

Natural depletion of petroleum reservoirs as well as gas injection for enhance oil recovery, are unavoidable processes in the oil industry. Foremost, prediction of the problems due to these two processes is very necessary and important. So many field and experimental experiences have shown that heavy organic depositions, especially asphaltene deposition, are principal results during these processes. Results of laboratory simulation of asphaltene deposition during the natural depletion of petroleum reservoirs and also during gas injection and enhanced oil recovery (EOR) processes are reported here. This is achieved through the design of a new experimental setup for the investigation of pressure and composition effects on asphaltene deposition in petroleum fluids at high pressure and high temperature conditions. In this work, asphaltene deposition during decreasing pressure, from pressures greater than reservoir pressure to pressures below the bubble point pressure (natural depletion) and also asphaltene deposition during natural gas injection in reservoir conditions, are studied for three samples—one recombined sample and two bottomhole samples. All of the obtained results from this work conform to theoretical and other experimental works.     

Query processing optimization in broadcasting XML data in mobile communications

Todays, XML as a de facto standard is used to broadcast data over mobile wireless networks. In these networks, mobile clients send their XML queries over a wireless broadcast channel and recieve their desired XML data from the channel. However, downloading the whole XML data by a mobile device is a challenge since the mobile devices used by clients are small battery powered devices with limited resources. To meet this challenge, the XML data should be indexed in such a way that the desired XML data can be found easily and only such data can be downloaded instead of the whole XML data by the mobile clients. Several indexing methods are proposed to selectively access the XML data over an XML stream. However, the existing indexing methods cause an increase in the size of XML stream by including some extra information over the XML stream. In this paper, a new XML stream structure is proposed to disseminate the XML data over a broadcast channel by grouping and summarizing the structural information of XML nodes. By summarizing such information, the size of XML stream can be reduced and therefore, the latency of retrieving the desired XML data over a wirless broadcast channel can be reduced. The proposed XML stream structure also contains indexes in order to skip from the irrelevant parts over the XML stream. It therefore can reduce the energy consumption of mobile devices in downloading the results of XML queries. In addition, our proposed XML stream structure can process different types of XML queries and experimental results showed that it improves the performace of XML query processing over the XML data stream compared to the existing research works in terms of access and tuning times.

     

Incorporation of a Regularization Term to Control Negative Correlation in Mixture of Experts

Combining accurate neural networks (NN) in the ensemble with negative error correlation greatly improves the generalization ability. Mixture of experts (ME) is a popular combining method which employs special error function for the simultaneous training of NN experts to produce negatively correlated NN experts. Although ME can produce negatively correlated experts, it does not include a control parameter like negative correlation learning (NCL) method to adjust this parameter explicitly. In this study, an approach is proposed to introduce this advantage of NCL into the training algorithm of ME, i.e., mixture of negatively correlated experts (MNCE). In this proposed method, the capability of a control parameter for NCL is incorporated in the error function of ME, which enables its training algorithm to establish better balance in bias-variance-covariance trade-off and thus improves the generalization ability. The proposed hybrid ensemble method, MNCE, is compared with their constituent methods, ME and NCL, in solving several benchmark problems. The experimental results show that our proposed ensemble method significantly improves the performance over the original ensemble methods.     

A robust critical path in an environment with hybrid uncertainty

In this article, we consider the project critical path problem in an environment with hybrid uncertainty. In this environment, the duration of activities are considered as random fuzzy variables that have probability and fuzzy natures, simultaneously. To obtain a robust critical path with this kind of uncertainty a chance constraints programming model is used. This model is converted to a deterministic model in two stages. In the first stage, the uncertain model is converted to a model with interval parameters by alpha-cut method and distribution function concepts. In the second stage, the interval model is converted to a deterministic model by robust optimization and min-max regret criterion and ultimately a genetic algorithm with a proposed exact algorithm are applied to solve the final model. Finally, some numerical examples are given to show the efficiency of the solution procedure.     

An isogeometrical approach to structural topology optimization by optimality criteria

The Isogeometric Analysis (IA) method is applied for structural topology optimization instead of finite elements. For this purpose, a control point based Solid Isotropic Material with Penalization (SIMP) method is employed and the material density is considered as a continuous function throughout the design domain and approximated by the Non-Uniform Rational B-Spline (NURBS) basis functions. To prevent the formation of layouts with porous media, a penalization technique similar to the SIMP method is used. For optimization an optimality criteria is derived and implemented. A few examples are presented to demonstrate the performance of the method. It is shown that, dissimilar to the element based SIMP topology optimization, the resulted layouts by this method are independent of the number of the discretizing control points and checkerboard free.     

The specific enthalpy of fracture for beta Ti-15-3 alloy

Fatigue crack propagation (FCP) experiments were conducted on beta Ti-15-3 alloy under various loading conditions to examine the constancy of the specific enthalpy for fracture, advanced by the Crack Layer (CL) theory as a material parameter characteristic of its intrinsic toughness. The energy release rate and the irreversible work were determined from load-displacement curves during crack propagation. Microscopic and diffraction analyses were conducted to identify the damage mechanisms ahead of the crack tip. A damage zone whose geometry exhibited plane strain character at the initial stage of crack propagation was observed optically. The damage zone transformed into plane stress configuration when the crack reached half its critical length. Damage mechanisms involved slip lines and microcracking which is believed to ensue from intense accumulation of slip processes. The magnitude of microcracking became more weighty as the crack moved deeper into plane stress dominance. The damage preceding crack advance was quantitatively assessed as the crack resistance moment which is the volume of transformed material per unit crack extension. Application of the CL theory to the data generated under a wide range of applied stress levels gave rise to a constant value of the specific enthalpy of fracture, 20 MJ/m³. This value is in close agreement with the specific energy of slip lines computed from microstructural considerations.