Polymeric carbon nanocomposites from multiwalled carbon nanotubes functionalized with segmented polyurethane

Multiwalled carbon nanotubes (MWNT) were functionalized with segmented polyurethanes (PU) by the “grafting to” approach. Raman and X‐ray photoelectron spectroscopy (XPS) spectra show that the sidewalls of MWNTs have been functionalized with acid treatment, and the amount of COOH increases with increasing acid treatment time. FTIR and X‐ray diffraction (XRD) spectra confirm that PU is covalently attached to the sidewalls of MWNTs by esterification reaction. Similar to the parent PU, the functionalized carbon nanotube samples are soluble in highly polar solvents, such as dimethyl sulfoxide (DMSO) and N,N‐dimethylformamide (DMF). The functionalized acid amount and the grafted PU amount were determined by thermogravimetric analyses (TGA). Comparative studies, based on SEM images between the PU‐functionalized and chemically defunctionalized MWNT samples, also reveal the covalent coating character. Dynamic mechanical analysis (DMA) of nanocomposite films prepared from PU and PU‐functionalized MWNTs show enhanced mechanical properties and increased soft segment T_g. Tensile properties indicate that PU‐functionalized MWNTs are effective reinforcing fillers for the polyurethane matrix. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Accurate rotor flux orientation technique for indirect rotor flux oriented control of induction motor drives

Abstract

In this paper, a novel detuning index is first proposed for indicating the proper timing required to correct the rotor time constant of indirect rotor flux oriented controlled single‐cage induction motor drives. This index can faithfully reflect the influence of rotor resistance changes as well as rotor flux changes. It also reduces greatly the number of rotor time constant estimations in practical applications. The theoretical basis of the index and the physical meaning are described in the paper in detail. Based on the proposed index, an on‐line rotor time constant estimator is also proposed to make corrections. Only existing available quantities of the closed loop controller are used for calculating the estimated rotor time constant accurately. Both simulation and experimental results verify the effectiveness of the proposed rotor flux orientation technique. It is seen that the proposed rotor flux orientation technique is suitable for practical applications.     

A two-user approximation-based transmit beamforming for physical-layer multicasting in mobile cellular downlink systems

Multicast has been known as an efficient transmission technique for group-oriented applications such as multi-party video conferencing, video streaming for paid users, online gaming, and social networking. In this paper, we investigate physical-layer multicasting in mobile cellular downlink systems, where the antennas at base station are employed to transmit common signals to multiple users simultaneously. A central design problem of downlink physical-layer multicasting is the search for the optimal beamforming vector that maximizes the multicast rate. Traditionally, the problem has been formulated as a quadratically constrained quadratic programming problem and shown to be NP-hard in general. In this paper, starting from examining the Karush–Kuhn–Tucker stationary conditions, a new method based on two-user approximation is proposed for the search for the optimal beamforming vector. The method is able to achieve a much higher multicast rate than the existing methods and provides an attractive trade-off between performance and complexity, especially for the case of using a large number of antennas. Using a large number of antennas at base station, also known as the large-scale multiple-input and multiple-output technique, has been regarded widely as one of the most promising technologies to increase system capacity, coverage, and user throughput for future generations of mobile cellular systems.     

A new color image space HRU related to the CIEL*a*b* color space

The color image space with one kind of merit color image scales (WIP) is derived using the psychophysical method of magnitude estimation method, usually used in visual assessment of color appearance, which can be used to describe the color image meanings of colors of works of art in parallel with those of people. The results show that a new color image space HRU is developed, and the relativity between this space and the CIEL*a*b* color space is also discussed. And, a good relationship between the HRU color image space and the CIEL*a*b* color space can be found. This may be of great advantage to the new color image space HRU in predicting the color image for single color based on the color space CIEL*a*b*. © 2009 Wiley Periodicals, Inc. Col Res Appl, 34, 452–457, 2009     

Synthesis and characterization of four‐arm star‐shaped polymers and copolymers

Four‐arm star‐shaped polymers and copolymers were obtained by transition metal‐catalyzed atom‐transfer radical polymerization (ATRP). The polymers were characterized by FTIR and ¹H‐NMR spectroscopy. Gel permeation chromatography results indicated the formation of polystyrene and polystyrene‐block‐poly(methyl methacrylate) (PS‐b‐PMMA) arms with controlled molecular weights. In dilute solution, the linear polymers had higher inherent viscosities than star‐shaped ones. Thermogravimetric analysis showed a similar degradation mechanism for linear and star‐shaped polymers. Differential scanning calorimetry indicated the successful formation of diblock star‐shaped copolymers. Copyright © 2006 Society of Chemical Industry     

SDN‐based dynamic multipath forwarding for inter–data center networking

Equal‐cost multipath (ECMP)–based traffic engineering (TE) methods are commonly used in intra–data center (DC) networks to improve the transmission performance for east‐west traffic (ie, traffic from server to server within a DC). However, applying ECMP on inter‐DC wide area network (WAN) offers limited performance enhancement as a result of irregular network topology. Since TE can be intelligently and efficiently realized with software‐defined networking (SDN), SDN‐based multipath becomes a popular option. However, SDN suffers from scalability issue caused by limited ternary content‐addressable memory (TCAM) size. In this paper, we propose an SDN‐based TE method called dynamic flow‐entry‐saving multipath (DFSM) for inter‐DC traffic forwarding. DFSM adopts source‐destination–based multipath forwarding and latency‐aware traffic splitting to reduce the consumption of flow entries and achieve load balancing. The evaluation results indicate that DFSM saves 15% to 30% of system flow entries in practical topologies and reduces the standard deviation of path latencies from 10% to 7% than do label‐switched tunneling, and also reduces average latency by 10% to 48% by consuming 6% to 20% more flow entries than do ECMP in less‐interconnected topologies. Note that the performance gain may not always be proportional to flow entry investment, with the interconnectivity between nodes being an important factor. The evaluation also indicates that per‐flow provision consumes several times the flow entries consumed by DFSM but reduces latency by 10% at most. Besides, DFSM reduces the standard deviation of path latencies from 14% to 7% than do even traffic splitting.     

Instruction scheduling and transformation for a VLIW unified reduced instruction set computer/digital signal processor processor with shared register architecture

The popularity of multimedia applications made them a major theme in embedded systems. The key component for supporting multimedia application well is embedded processor. Thus, we have designed and implemented an embedded processor, called UniDual processor, to achieve this objective. Its key features are the integration of instructions of reduced instruction set computers (RISCs) and digital signal processors (DSPs) as well as the support of special instruction set and shared‐based clustered register architecture. However, an important issue of UniDual that remains open is how to efficiently allocate registers. In this paper, we present a scheduling and instruction transformation approach to resolve the aforementioned issue. The proposed approach schedules instructions and then transforms overlapped instructions into RISC and DSP instructions by taking communication overhead and hardware limitations into account. Compared with the greedy approach, the evaluation shows that our work is relatively effective in performance and code size reduction. Copyright © 2012 John Wiley & Sons, Ltd.     

Synthesis and properties of organosoluble polyimide/clay hybrids

A soluble polyimide prepared from 7,7′‐bis(4‐aminophenoxy)‐4,4,4′,4′‐tetramethyl‐2,2′‐spirobichroman and 4,4′‐hexafluoroisopropylidenediphthalic anhydride was mixed with organo‐modified montmorillonite or synthetic mica in N,N‐dimethylacetamide. The content of the clay minerals was 1, 2, and 4 wt %, respectively. Transparent, flexible, and tough films could be cast from the hybrid solutions. The hybrid films were characterized with wide‐angle X‐ray scattering (WAXS), transmission electron microscopy, thermomechanical analysis, thermogravimetric analysis, and differential scanning calorimetry. The WAXS results revealed that the montmorillonite was dispersed more homogeneously than the synthetic mica in the polyimide matrix. In both polyimide/clay hybrids the addition of clay caused thermal expansion coefficients to decrease, and the thermal stability was slightly enhanced. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 2067–2072, 2001     

Push selling—Multicast messages to wireless devices based on the publish/subscribe model

Push technology automates the information delivery process by not requiring users to request for the information they need. Wireless has experienced explosive growth in recent years, and “push” will be the predominant wireless service delivery paradigm of the future. A wide variety of services, alerts and messages, such as promotional content, will be delivered to consumers’ phones or PDA. However, to push information to a wireless device can be a challenge because of the problem of intermittent communication links and resource constraints on wireless devices as well as limited bandwidth. This paper explores an efficient multicasting mechanism that “pushes” pre-specified information to groups of wireless devices. The mechanism operates with limited bandwidth and also overcomes the connectivity problem. Based on the above concept, we have designed and implemented a system to multicast sales information via wireless technology. The system is message-oriented and JMS compliant.     

A numerical study of piled raft foundations

Abstract

This paper presents raft‐pile‐soil interaction for a vertically loaded flexible piled raft on layered subsoil using a two‐dimensional finite difference numerical tool. The subsoil is modeled as a linear elastic material and the raft is modeled as a beam structure under plane strain. In addition, the piles are simulated by a series of pile elements considering the pile/soil interface behavior. In the simulations, the required input parameters of soil, pile and interface are determined by back analyses of pile loading tests. Settlement, bending moment, both in pile and raft, as well as effects of raft flexibility for vertical uniform loading in the subsoil were examined. It is found that even though for vertical uniform loading, a relatively high bending moment may be induced in the piles due to lateral displacement of the stressed subsoil. For the case of a piled raft placed over a soft clay layer at ground surface the contact pressure at the raft‐soil interface is merely 4 ～ 6% of that developed in the unpiled raft. Nevertheless, the contact pressure may reach 15 ～ 25% of that of the unpiled raft if the piled raft is resting on a sand layer at the ground surface. This implies that the loading carried by the pile group could be reduced by almost 1/4 of the design load and it could eventually reduce the cost of pile group construction to a certain extent.