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1.
Manesh K.M. Gopalan A.I. Kwang-Pill Lee Santhosh P. Kap-Duk Song Duk-Dong Lee 《Nanotechnology, IEEE Transactions on》2007,6(5):513-518
A nanofibrous sensor for ammonia gas is fabricated by electrospinning the composite of poly(diphenylamine) (PDPA) with poly(methyl methacrylate) (PMMA) onto the patterned interdigit electrode. The composite electrospun membrane shows interconnected fibrous morphology. Functional groups in PDPA and the high active surface area of the fibrous membrane make the device detect a lower concentration of ammonia with a good reproducibility. The sensing capability of the device is studied by monitoring the changes in resistance of the membrane with different concentrations of ammonia. The changes in resistance of the membrane shows linearity with the concentration of ammonia in the limit of 10 and 300 ppm. UV-visible spectroscopy reveals the mechanism of sensing ammonia by the membrane. 相似文献
2.
Liouville numbers were the first class of real numbers which were proven to be transcendental. It is easy to construct non-normal Liouville numbers. Kano (1993) and Bugeaud (2002) have proved, using analytic techniques, that there are normal Liouville numbers. Here, for a given base k ≥ 2, we give a new construction of a Liouville number which is normal to the base k. This construction is combinatorial, and is based on de Bruijn sequences. 相似文献
3.
One limitation to the use of high-strength/high-modulus rigid-rod polymer fibres like poly-(p-phenylene benzobisthiazole) (PBZT) and poly-(p-phenylene benzobisoxazole) (PBZO) in composite structures is their low compressive strength. Various theories have been developed to predict compressive strength of rigid-rod fibres. In this study the critical buckling stress for rigid-rod fibres with stiff external coatings has been theoretically modelled assuming that the failure mode in compression is the microbuckling of the fibrils in shear. Our model predicts that significant improvement in fibre compressive strength will occur only when relatively thick coatings, with thickness to diameter (t/D) ratios in excess of > 0.05, are used. Experimentally measured compressive strength of aluminium coated PBZT fibres shows values in good agreement to the theory at t/D ratios of 0.006 and below. Factors related to the selection of suitable coating materials and problems associated with establishing coating performance are identified.Nomenclature
P
axial compressive load
-
P
f
axial compressive load on the fibre
-
P
c
axial compressive load on the coating
-
P
cr
i
critical buckling load in the ith case
- cr
critical buckling stress
- co
compressive strength of the uncoated fibre
- c
compressive strength of the coated fibre
- v(x)
lateral deflection of a buckled fibril or coating
-
V
m
amplitude of the lateral deflection in the mth mode
-
m
number of half-sine waves in the deflection mode
-
x
coordinate distance along axial direction
-
y
coordinate distance along radial direction
-
coordinate distance along circumferential direction
-
l
length of the buckling unit
-
N
number of fibrils in the fibre
-
D
fibre diameter
-
d
fibril diameter
-
t
coating thickness
-
I
f
moment of inertia of the fibril
-
A
f
cross-sectional area of the fibril
-
E
f
tensile modulus of the fibre
-
E
c
tensile modulus of the coating material
-
E
tensile modulus of the coated fibre
-
G
torsional shear modulus of the fibre
- vc
Poisson's ratio of the coating material
- f
density of the fibre
- c
density of the coating material
-
density of the coated fibre
- U
f
strain-energy change in the fibre
- U
c
strain-energy change in the coating
- T
f
external work done on the fibre
- T
c
external work done on the coating
-
d/D
-
t/D 相似文献
4.
Mohanapriya Marimuthu Santhosh Rajendran Reshma Radhakrishnan Kalpana Rengarajan Shahzada Khurram Shafiq Ahmad Abdelaty Edrees Sayed Muhammad Shafiq 《计算机、材料和连续体(英文)》2023,74(3):4729-4745
Continuous improvements in very-large-scale integration (VLSI) technology and design software have significantly broadened the scope of digital signal processing (DSP) applications. The use of application-specific integrated circuits (ASICs) and programmable digital signal processors for many DSP applications have changed, even though new system implementations based on reconfigurable computing are becoming more complex. Adaptable platforms that combine hardware and software programmability efficiency are rapidly maturing with discrete wavelet transformation (DWT) and sophisticated computerized design techniques, which are much needed in today’s modern world. New research and commercial efforts to sustain power optimization, cost savings, and improved runtime effectiveness have been initiated as initial reconfigurable technologies have emerged. Hence, in this paper, it is proposed that the DWT method can be implemented on a field-programmable gate array in a digital architecture (FPGA-DA). We examined the effects of quantization on DWT performance in classification problems to demonstrate its reliability concerning fixed-point math implementations. The Advanced Encryption Standard (AES) algorithm for DWT learning used in this architecture is less responsive to resampling errors than the previously proposed solution in the literature using the artificial neural networks (ANN) method. By reducing hardware area by 57%, the proposed system has a higher throughput rate of 88.72%, reliability analysis of 95.5% compared to the other standard methods. 相似文献
5.
The nitrogen dioxide (NO2) sensing capability of polypyrrole (PPy) was enhanced dramatically after functionalized with iron(III)phthalocyanine-4,4′,4″,4-tetrasulfonic acid monosodium salt (FePcTSA). The incorporated phthalocyanine was confirmed by different characterization techniques such as UV–vis spectroscopy, FTIR, GFAAS, EDAX, etc. The resistance of the functionalized PPy decreased spontaneously during exposure to NO2 gas at room temperature. This material exhibited excellent stability, reversibility, and reproducibility. The lowest response time (t50) thus obtained is 47 s with a highest response factor (ΔR/R0 × 100) of 50.25. 相似文献
6.
M. Santhosh Kumar J. Prez-Ramírez M.N. Debbagh B. Smarsly U. Bentrup A. Brückner 《Applied catalysis. B, Environmental》2006,62(3-4):244-254
Fe-silicalite and Fe-SBA-15 with similar iron content have been characterized by N2 adsorption, small angle X-ray scattering (SAXS), wide-angle X-ray scattering (WAXS), scanning electron microscopy (SEM), high-resolution transmission electron micrographs (HRTEM), UV–vis–DRS and EPR, and tested in direct N2O decomposition, N2O reduction by CO and N2O-mediated propane oxidative dehydrogenation. Both catalysts contain almost exclusively isolated Fe3+ sites of similar concentration and structure, which are, however, stabilized in markedly different pore geometries (intersecting channels of ca. 0.55 nm diameter in Fe-silicalite versus parallel linear pores of ca. 7.5 nm diameter in Fe-SBA-15). This aspect is of vital importance in order to exclusively ascribe different catalytic performances to the environment where the iron species are stabilized. Fe-silicalite revealed to be much more active than Fe-SBA-15 in all reactions studied. This clearly illustrates that the confinement of the iron species in pores of suitable geometry (structure and size) is essential to originate their remarkable catalytic properties. The large pores in ordered mesoporous materials apparently do not generate the required intimate contact between potentially active Fe sites and reactant molecules. 相似文献
7.
The electrical and optical properties of silver indium selenide thin films prepared by co-evaporation have been studied. X-ray diffraction indicates that the as prepared films were polycrystalline in nature. The lattice parameters were calculated to be a=0.6137 and b=1.1816 nm. Composition was determined from energy dispersive analysis of X-ray. Silver indium selenide thin films were also prepared by bulk evaporation of powdered sample for comparative study. They have an optical band gap (Eg) of 1.25 eV and it is a direct allowed transition. Refractive index (n) and extinction coefficient (k) were calculated from absorption and reflection spectra. Steady-state photoconductivity was measured from 300 to 400 K. Carrier lifetime was calculated from transient photoconductivity measurements at room temperature at different intensities of illumination. 相似文献
8.
9.
P. JideshAuthor Vitae Santhosh George Author Vitae 《Computers & Electrical Engineering》2012,38(5):1262-1277
In this paper a shock coupled fourth-order diffusion filter is proposed for image enhancement. This filter converges at a faster rate while preserving and enhancing edges, ramps and textures present in the images. The proposed filter diffuses with varying magnitudes in the directions normal to the level-curve and along it. The magnitude of the directional diffusion is controlled by a diffusion function, meant to provide a good response in the direction along the level-curves, than across them. The proposed filter can still preserve the planar approximation of the image, thereby avoiding the discrepancy caused due to the staircase effect, as in the second-order counterparts. The anisotropic property of the filter is thoroughly studied, analyzed and demonstrated with perspective and quantitative results. The performance of the proposed filter is compared with the state-of-the-art methods for image enhancement. The quantitative and perspective measures provided endorse the capability of the method to enhance various kinds of images. 相似文献
10.
Copper sulphide (CuS) nanomaterials with interesting morphology were synthesised using copper nitrate trihydrate, thiourea and water as a solvent by a simple hydrothermal route. A systematic investigation was carried out to investigate the effect of reaction time (5, 16 and 24?h) at 150°C on the morphology of the materials. Without the use of any template or additives, shape controlled synthesis of CuS nanocrystallites were achieved. The possible mechanism for the formation of the various nanostructures of CuS in this system is discussed. The prepared materials were characterised by X-ray diffraction, field emission scanning electron microscopy (FE-SEM) and DRS-UV–Vis absorption analysis. The UV–Vis spectrum shows that it is the promising material which can absorb in the visible region and hence could be used for photocatalytic applications. In addition, the electrochemical characteristic of the synthesised material was investigated by cyclic voltammetric analysis, which shows that CuS could be used for electrocatalytic applications. 相似文献