γ-Al2O3 supported vanadium oxides were modified by tungsten and molybdenum oxides in order to improve dispersion and selectivity towards olefins in propane oxidative dehydrogenation (ODH). Both vanadium–tungsten and vanadium–molybdenum catalysts were obtained by adsorption of mixed isopolyanions (VW5O195−, V2W4O194−, VMo5O195− and V2Mo4O194−) from aqueous solutions. The isopolyanion solutions were characterized by UV-Vis and 51V NMR spectroscopy. Vanadium, vanadium–tungsten and vanadium–molybdenum precursors and catalysts were also characterized by UV-Vis (diffuse reflectance) and solid state 51V NMR spectroscopy. An improved selectivity to propene in the presence of tungsten and molybdenum in VOx/γ-Al2O3 was observed and attributed to dilution of vanadium by tungsten or molybdenum oxides on the γ-Al2O3 surface. 相似文献
Giuseppe Gradenigo (1859-1926) was an important figure in the development of Otology. Within this paper the authors consider his background and his particular contributions to the development of various aspects of audiology. 相似文献
The martensitic transformation temperatures and the types of martensitic phases have been determined in a wide concentration
range of technological interest for Cu-Al-Ni shape-memory alloys (SMAs) A stability diagram of martensitic phases as a function
of alloy concentration has been determined. It is found that when the aluminum content increases, the transformation changes
from β3 ⇒ β′3 to β3 ⇒ γ′3, with an intermediate concentration range where both martensites coexist due to a β3 ⇒ γ′3+β′3 transformation. On the other hand, an increase of nickel content stabilizes the martensite β′3, changing from a mixed β3 ⇒ γ′3 + β′3 to a single β3 ⇒ β′3 transformation. Furthermore, linear relationships between Ms and Al and Ni concentrations have been obtained for all types of martensitic phases. 相似文献
We show an interesting pairwise balanced design (PBD)-closure result for the set of lengths of constant-composition codes whose distance and size meet certain conditions. A consequence of this PBD-closure result is that the size of optimal constant-composition codes can be determined for infinite families of parameter sets from just a single example of an optimal code. As an application, the sizes of several infinite families of optimal constant-composition codes are derived. In particular, the problem of determining the size of optimal constant-composition codes having distance four and weight three is solved for all lengths sufficiently large. This problem was previously unresolved for odd lengths, except for lengths seven and eleven. 相似文献
The fibrinolytic capacity of patients with acute myocardial infarction (AMI) is known to be impaired. The primary regulatory element of the fibrinolytic system is plasminogen activator inhibitor (PAI). It has been previously observed that there are 2 peaks in the plasma PAI level of AMI patients at 4h and 16h after thrombolytic therapy with recombinant tissue plasminogen activator (rtPA). Lanoteplase/SUN9216 is a mutant tPA with a biological half-life longer than that of rtPA. Thrombolytic therapy with mutant tPA or rtPA was carried out consecutively in 21 patients with AMI (8 patients as the mutant tPA group, and 13 patients as the rtPA group). The recanalization time of the mutant tPA group was significantly faster than that of the rtPA group (16.1 +/- 3.9 min vs 39.6 +/- 4.8 min, p<0.01). The PAI activity at 4h after the initiation of thrombolysis was significantly lower in the mutant tPA group than in the rtPA group (8.74 +/- 5.46IU/L vs 26.74 +/- 3.35 IU/L, p<0.01). There was a one mild peak in serial plasma PAI activity levels 24h after the initiation of thrombolysis. The results suggest that thrombolytic therapy with mutant tPA reduced the impairment of fibrinolytic capacity. The mutant tPA gives faster recanalization and lower PAI activity after successful thrombolysis, compared with rtPA. 相似文献
Solid C60 is a semiconductor with very special properties which are sensitive to its preparation conditions. Very little is known about the forbidden gap states and about the recombination centers in this material. An attempt is made in this paper to deduce information on the latter from the temperature dependences of the photoconductivity and the corresponding light intensity exponent that were measured on C60 films. This attempt combines a comparison of the experimental results with numerical simulation of a simple model. It is concluded that oxygen centers play a major role in the electronic structure of solid C60 These centers are acceptor-like, they act as compensators to the shallow donors and they result in recombination centers which lie 0.3 eV below the conduction band edge. It is further concluded that the oxygen suppresses the well-known phase transition that occurs around 260°C by prohibiting the expansion of the lattice upon the increase of temperature. 相似文献
Predicting remaining useful life (RUL) is crucial for system maintenance. Condition monitoring makes not only degradation data available for RUL estimation but also categorized health status data for health state identification. However, RUL prediction has been treated as an independent process in most cases even though potential relevance exists with health status detection process. In this paper, we propose a convolution neural network based multi-task learning method to reflect the relatedness of RUL estimation with health status detection process. The proposed method applied to the C-MAPSS dataset for aero-engine unit prognostics supported superior performances to existing baseline models.