A study of global vs. local properties for maleic anhydride modified polypropylene nanocomposites

Nanoindentation of organomodified clay filled maleated polypropylene (MAPP) was investigated. The study aims to identify the relative increase in local stiffness in comparison to the increase in mechanical properties of the bulk in polypropylene-based nanocomposites. Such a study allows one to assess confined material property in addition to increased filler volume at the local scale. A mixture of highly intercalated and well exfoliated clay structures, when dispersed in MAPP matrix, was observed under transmission electron microscopy. The degree of exfoliation was found to increase with clay loading, which was attributed to the higher viscosity and mechanical shear forces during melt compounding. Instrumented indentation was performed on (1) clay aggregate supported by MAPP matrix, (2) clay-matrix boundary, and (3) the MAPP matrix. The clay aggregated region generally showed higher stiffness as compared to the matrix. And, the relative increase in indentation stiffness is substantially higher than the relative increase in tensile and compressive stiffnesses for clay reinforced systems. Polymer chain confinement and topological constraint appeared to be operative to enhance local stiffness in the clay aggregated region. Good correlation was, however, obtained between the change in macroscopic stiffness and the change in highly local indentation stiffness as a result of clay reinforcement.     

Synthesis of AlPO4 Molecular Sieves with AFI and AEL Structures by Dry-Gel Conversion Method and Catalytic Application of Their SAPO Counterparts on Isopropylation of Biphenyl

AlPO₄-5 and AlPO₄-11 were synthesized by dry-gel conversion (DGC) method. Steam-assisted conversion (SAC) and vapor-phase transport (VPT) techniques were applied for this purpose. The synthesis was successful in presence of a certain minimum amount of external bulk water, without which the crystallization failed. Crystallization by VPT method was slower than corresponding SAC and HTS method. SAPO analogs of the samples, SAPO-5 and SAPO-11 were also synthesized by DGC method. Samples made by DGC methods had higher yield than the conventional hydrothermal synthesis (HTS); otherwise the samples showed similar characteristics as that made by HTS. XRD, SEM and N₂-adsorption results showed high crystallinity and purity of the samples made by DGC, and ²⁷Al MAS NMR spectra indicated the tetrahedral framework nature of Al. SAPO-5 and SAPO-11 were tested for their catalytic activity in isopropylation of biphenyl, and in terms of conversion and selectivity, SAPO-5 was found to be suitable for this application.     

Solving singular control problems using uniform trigonometrization method

This study investigates the application of a recently developed construct, the uniform trigonometrization method (UTM), to the singular control problems in chemical engineering. The UTM involves minimal modifications to the original problem, thereby generating near-singular control solutions that can be used for conceptual design and serve as an alternate to direct techniques like nested and simultaneous approaches. Eight classical singular control problems with known analytical solutions and three complex singular control problems from chemical engineering domain are solved in this study. The results obtained using the UTM for these problems are found to match well with the literature and are of higher resolution as compared to the results obtained using a direct pseudospectral-based solver. The ability of the UTM to handle complex chemical engineering problems with both singular controls and state path constraints has also been demonstrated in this study.     

Developing Faculty ICT Competencies Inside and Outside the Library

Despite all the financial resources that are directed to support and acquire learning technologies, the results have been generally disappointing. Faculty are eager to use technology but lack the technical skills, ability, and experience. Library staff includes a talent tool rich in Information and Communication Technologies (ICT)/WEB 2.0 technical expertise and experience. In terms of content sourcing and procurement, library technical services and selection staff have broad knowledge of the marketplace for online information and content as well as experience in licensing access. They have a firm grasp of the transaction process, workflows, pricing, and licensing negotiations. Content development and sourcing inevitably involves access management, online storage, copyright, and licensing—things at which libraries are good. ICT deployment is changing teaching and learning on campuses, and the roles of those involved in teaching and learning are also changing. Whether formally through mandated library services, or informally through back channels, library staff are supporting faculty new technology use as well as faculty teaching materials content sourcing and procurement.     

Optimizing spatiotemporal sensors placement for nutrient monitoring: a stochastic optimization framework

Nutrient monitoring is very important for the area of food–energy–water nexus. The sensor network for nutrient monitoring requires dynamic sensing where the positions of the sensors change with time. In this work, we have proposed a methodology to optimize a dynamic sensor network which can address the spatiotemporal aspect of nutrient movement in a watershed. This is a first paper in the series where an algorithmic and methodological framework for spatiotemporal sensor placement problem is proposed. Dynamic sensing is widely used in wireless sensors, and the current approaches to solving this problem are data intensive. This is the first time we are introducing a stochastic optimization approach to dynamic sensing which is efficient. This framework is based on a novel stochastic optimization algorithm called Better Optimization of Nonlinear Uncertain Systems (BONUS). A small case study of the dynamic sensor placement problem is presented to illustrate the approach. In the second paper of this series, we will present a detailed case study of nutrient monitoring in a watershed.     

Geomorphology Based Semi-Distributed Approach for Modelling Rainfall-Runoff Process

This study presents a geomorphology based semi-distributed methodology for prediction of runoff of a catchment. In this proposed methodology, the catchment area is divided into a number of sub-catchments using the Thiessen polygon method. The rainfall records of particular rain-gauge station are considered as uniformly distributed over the entire sub-watershed. Four different weighting factors are proposed to obtain the sub-catchment’s contribution towards runoff. The weighting factors are calculated based on the geomorphological parameters of the catchment. The geomorphological parameters of the sub-watersheds are obtained from SRTM digital elevation data. The weighted contributions from all the sub-watersheds at current and previous time steps and the previous time step discharge are used to develop an Artificial Neural Network (ANN) for predicting the discharge at the basin outlet. A lump model considering average rainfall of the catchment is also developed using ANN for evaluating the performance of the proposed distributed model. For the lump model, average rainfall is calculated using Thiessen polygon method. The historic rainfall and runoff data recorded at the Dikrong basin, a sub-catchment of the river Brahmaputra is used to evaluate the efficiency of the developed methodology. The evaluation results show that the presented model is superior to the lump model and has the potential for field application. A comparative study is also carried out to obtain the most influential combination of geomorphological parameters in predicting the catchment’s runoff.     

Evolution of fretting fatigue damage and relaxation of residual stress in shot-peened Ti-6Al-4V

The evolution of fretting fatigue damage was investigated in shot-peened Ti-6Al-4V samples, by measuring the changes in the surface residual stress, using the X-ray diffraction technique. The surface residual stress was found to relax as the number of fretting fatigue cycles increased. The relaxation behavior of the residual stress with the increasing number of fretting fatigue cycles was observed to occur in three stages. In the first 20 pct of the fretting fatigue life, a drastic relaxation was observed. In the second part (between 20 and 70 pct), a gradually increasing behavior was observed. During the last 20 to 30 pct of the fretting fatigue life, a dramatic relaxation of the residual stress was found to occur. A complete relaxation of the residual stress occurred in the fracture region. A scanning electron microscope observation of the microstructure of the damaged region was used to examine the mechanisms leading to the relaxation of the residual stress. The development of delaminations at the early stages of the accumulation of the fretting fatigue damage was observed to be the main cause of the initial relaxation. The generation of microcracks from the voids left behind by the delaminations is responsible for the additional relaxation of the residual stress. The coalescence of the microcracks generated from different delaminated regions produced yet more relaxation of residual stress and, ultimately, the final fracture of the specimen.     

Optimal design of unit hydrographs using probability distribution and genetic algorithms

A nonlinear optimization model is developed to transmute a unit hydrograph into a probability distribution function (PDF). The objective function is to minimize the sum of the square of the deviation between predicted and actual direct runoff hydrograph of a watershed. The predicted runoff hydrograph is estimated by using a PDF. In a unit hydrograph, the depth of rainfall excess must be unity and the ordinates must be positive. Incorporation of a PDF ensures that the depth of rainfall excess for the unit hydrograph is unity, and the ordinates are also positive. Unit hydrograph ordinates are in terms of intensity of rainfall excess on a discharge per unit catchment area basis, the unit area thus representing the unit rainfall excess. The proposed method does not have any constraint. The nonlinear optimization formulation is solved using binary-coded genetic algorithms. The number of variables to be estimated by optimization is the same as the number of probability distribution parameters; gamma and log-normal probability distributions are used. The existing nonlinear programming model for obtaining optimal unit hydrograph has also been solved using genetic algorithms, where the constrained nonlinear optimization problem is converted to an unconstrained problem using penalty parameter approach. The results obtained are compared with those obtained by the earlier LP model and are fairly similar.     

Fretting fatigue crack initiation behavior using process volume approach and finite element analysis

This study investigates crack initiation behavior by incorporating fretting fatigue process volume. Three critical plane based fretting fatigue crack initiation parameters are characterized by computing their averaged values over the process volume and then comparing with their counterparts obtained from the localized approach. Two approaches are used: first one involves the computation of parameter at several points over a rectangular region and then its average, and second approach computes the average state of stress/strain over a radial region from which the averaged parameter is calculated. Both approaches require pre-determination of a critical location at or around which the process volume needs to be placed. Effects of size and location of process volume on the averaged value of parameters are studied in detail. Two radii of cylindrical pad are analyzed to investigate the effect of severity of stress gradient on process volume approach. Effects of finite element mesh refinement are also investigated. Averaged value of parameter decreases with the increase of process volume size. This decrease is higher when the process volume is located in the region that is away from the contact zone. Further, a parameter based on normal stress on the critical plane shows more dependence on the size of process volume than that based on shear stress or on a combination of both shear and normal stresses. Orientation of crack initiation changes within a range that is well within the scatter band of experimental observations as the process volume size increases. Averaged value of parameter for a pad with higher stress gradient has a larger reduction with the increase of process volume size than that with a lower stress gradient. Process volume size has less effect on the averaged value of parameter with coarser finite element mesh. Finally, the localized approach provides a conservative value of fretting fatigue crack initiation parameter compared to its counterpart based on the process volume.     

Modeling and validation of composite patch repair to cracked thick and thin metallic panels

A two-dimensional finite element analysis is presented to predict crack growth behavior of cracked panels repaired with bonded composite patch. Fatigue experiments were conducted with precracked aluminum specimens of two thicknesses (1 and 6.35 mm), with and without debond, and repaired asymmetrically. Fatigue lives of thick and thin repaired panels extended four and ten times relative to unrepaired cases, respectively. The predicted fatigue crack growth rates were in agreement with experimental values at the unpatched face but not at the patched face. Thus, the present analysis provides a conservative assessment of durability and damage tolerance of repaired thin and thick panels.