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1.
Single cubane-like clusters, MFe_3S_4(R_2dtc)_5 (M=Mo, R_2=—(CH_2)_4—, Bz_2; M=W, R_2=Me_2, —(CH_2)4—; dtc=dialkyldithiocarbamate) were synthesized by assembly reaction of (NH_4)_2MS_4 (M=Mo, W), FeCl_2 with R_2dtcNa (or NH_4) in DMF. The structure, IR, EPR and cyclic voltammogram are described and discussed. MoFe_3S_4(C_4H_8dtc)_5 was also obtained from the conversion of linear cluster Fe(DMF)_6[(FeCl_2)_2MoS_4] in the presence of C_4H_8dtc NH_4. Both clusters MoFe_3S_4(C_4H_8dtc)_4·2C_2H_5CN and WFe_3S_4(C_4H_8dtc)_5·2DMF crystallize in the monoclinic space group C2/c with a=12.544(2), (Mo-cluster), 12.533(4) (W-cluster); b=20.478(4), 20.121(6); c=19.582(7), 19.659(2);β=102.82(2), 102.96(3)°; and Z=4, 4. Their structures were refined to R=0.057 and 0.064 with use of 2690 and 2179 reflections (ι>3Q(I)), respectively. Many similarities in structure for Mo and W clusters indicate that both Mo and W play a very similar role in the clusters. 相似文献
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The numerical solution of Dirichlet's problem for a second-orderelliptic operator in divergence form with arbitrary nonlinearitiesin the first- and zero-order terms is considered. The mixedfinite-element method is used. Existence and uniqueness of theapproximation are proved and optimal error estimates in L2 aredemonstrated for the relevant functions. Error estimates arealso derived in Lq, 2q+ 相似文献
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SOON WOOK CHA JUNG-IL JIN M. LAGUERRE M. F. ACHARD F. HARDOUIN 《Liquid crystals》2013,40(9):1325-1337
New non-symmetric dimesogens consisting of a cholesteryl moiety and an aromatic mesogenic unit interconnected through a pentamethylene spacer have been prepared. The aromatic units consist of two phenyl rings linked by carboxy, oxycarbonyl, ethylene, ethynylene, azo or Schiff's base groups. The mesomorphic and transitional properties have been investigated by using optical microscopy, differential scanning calorimetry, helical pitch measurements, and electric field and miscibility studies. The structures of the mesophases have been studied using X-ray diffraction. Several kinds of smectic packings are observed depending on the nature of the linking group and an attempt to understand the origin of the different phase structures at a molecular level is made. 相似文献
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ABSTRACT Superporous hydrogels, hydrogels with pore sizes in the range of 100 μm and larger, were synthesized using N-isopropyl-acrylamide (NIPAM) and acrylamide (AM). The superporous hydrogels were synthesized by crosslinking polymerization of monomers in the presence of gas bubbles. The pores of superporous hydrogels were connected to each other to form open capillary channels, which provided fast response to the changes in the environmental temperature. Upon increase in temperature from 10°C to 65°C, the superporous hydrogel made from a monomer solution of NIPAM:AM = 9:1 shrank from the fully swollen state (volume of 36 cm3) to the fully collapsed state (volume of 6.5 cm3) in 72±14 sec. When the temperature was changed back to 10°C, the superporous hydrogel swelled to 36 cm3 in 78±15 sec. This deswelling-swelling cycle was repeated many times without changes in the thermo-reversible property of the superporous hydrogel. The response time of the superporous hydrogels was thousand times faster than that of conventional hydrogels. The fast response of the superporous hydrogels is due to the rapid uptake or exclusion of water molecules through the extensive capillary channels. Because superporous hydrogels still maintain the open capillary structure even after drying, the dried superporous hydrogels can also swell to the equilibrium swelling state within minutes. These fast responsive hydrogels can find many pharmaceutical and medical applications. 相似文献
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PARK Kyewon Koh 《中国科学 数学(英文版)》2011,(3):531-538
We introduce the notion of entropy generating sequence for infinite words and define its dimension when it exists. We construct an entropy generating sequence for each symbolic example constructed by Cassaigne such that the dimension of the sequence is the same as its topological entropy dimension. Hence the complexity can be measured via the dimension of an entropy generating sequence. Moreover, we construct a weakly mixing example with subexponential growth rate. 相似文献
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D. H. BOO C. G. PARK 《数学年刊B辑(英文版)》2000,(4)
1. IntroductionGiven a locally compact abelian group G and a multiplier p on G, one can associate tothem the twisted group C*-algebra C*(G, p), which is the universal object for unitary prepresentations of G. C* (Zm, p) is said to be a noncommutative torns of rank m and denotedby A.. The multiplier p determines a subgroup S. of G, called its symmetry group, andthe multiplier p is called totally skew if the symmetry group S. is trivial. And A. is calledcompletely irrational if p is totally… 相似文献
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