Synthesis, structure, and antimetastatic activity of thetrans-[Pt(NC5H4C(O)NHC2H4ONO2)2Cl2] complex

Thetrans-[Pt(NC₅H₄C(O)NHC₂H₄ONO₂)₂Cl₂] complex (2) was prepared by the reaction of nicorandyl (N-nitroethoxynicotinamide), which is widely used in cardiology, with K₂PtCl₄ in water. The structure of2 was established by X-ray structural analysis. It was found that complex2 exhibits high antitumor activity, in particular, antimetastatic activity, unlike the analogous Cu^II complex with bromine atoms. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1672–1675, September, 1997.     

正交各向异性矩形板受迫振动的三维分析

从正交各向异性三维弹性动力学的控制方程出发，在求得四边简支矩形板自由振动频率和位移振型的基础上，构造了受迫振动的位移函数；利用自由振动位移振型的正交性，将控制方程的空间变量和时间变量分离，得到了广义质量、广义力和频率表示的关于时间的2阶常微分方程，从而得到了正交各向异性弹性矩形板在受迫振动下的位移场和应力场．给出了本文方法与薄板理论的算例．     

Thermal activation of complexation reaction on aerosil surface

The influence of temperature in the 20–100°C range on processes of bimolecular interaction in the aerosil-phenanthrene-trinitrobenzene system has been studied. Temperature-stimulated CTC accumulation on the surface is found. Activation energies of complex formation are estimated. Quenching of phenanthrene fluorescence by acceptor has a mixed static and dynamic character.     

正电子产生靶上初级电子束半径的最小化研究

为获得尽可能高的正电子(e⁺)产额,严格控制初级电子(e^－)束在e⁺产生靶上的束半径是至关重要的.首先分析了使e^－束半径增大的各因素和对这些因素的制约;然后以北京正负电子对撞机(BEPC)的正电子源为例,给出了束半径的实测值和计算值的比较,以具体说明这些因素的影响;最后讨论了北京正负电子对撞机二期工程(BEPC-Ⅱ)的相应优化设计研究,提出了获得靶上最小束半径的若干途径.     

Synthesis and structures of nitroxyalkyl methylphosphonates

The reactions of ethylene glycol mononitrate and glycerol 1,3-dinitrate with methylphosphonic dichloride afforded new nitroxyalkyl methylphosphonates.     

Cubane derivatives 1. Synthesis and molecular structures of the esters of 1,4-cubanedicarboxylic acid

An effective method of esterification of 1,4-cubanedicarboxylic acid with alkylsulfuric acids is proposed. The derivatives of alkanols with substantially different pK_a Valus are obtained in high yields. Molecular structures of the esters obtained are confirmed by various methods. The X-ray study showed a remarkable effect of the nature of an alkyl radical on the geometry of the cubane core.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp.668–672, April, 1994.The authors thank Dr. G. V. Lagodzinskaya for analyzing the NMR spectra and for useful discussions.     

Effect of laser erosion on the copper and zinc concentrations in the surface layer of brass

A REMMA 102 scanning electron microscope equipped with semiconductor and wave spectrometers is applied to measure the copper and zinc concentrations in the surface layers of an M161 brass sample and the same sample subjected to a focused laser radiation. The results are compared with the results obtained with an MS3101 laser mass spectrometer having a laser-plasma ion source. The laser-assisted erosion of the surface layer in the brass is shown to significantly change the copper and zinc concentrations. It is found that, when the craters produced by laser pulses on the initial surface do not overlap, the copper and zinc contents in the laser-induced plasma correspond to their contents in the sample.     

关于阶乘的Erds-Stewart猜想

摘要:设n是正整数;P_0=1,P_i(i=1,2,…)是第i个素数.本文证明了:方程 n!+1=P_k~aP_(k+1)~b,P_(k-1)0,b>0,仅有解(n,P_k,P_(k+1),a,b)=(1,1,2,1,0),(2,3,5,1,0),(3,5,7,0,1),(4,5,7,2,0),(5,7,11,0,2).上述结果证实了Erds和Stewart提出的一个猜想.     

晶态-非晶态复合锂离子导体的电学性质

本文研究了晶态LiCl-非晶态Li₂O·3B₂O₃复合锂离子导体的电学性质。实验发现这种晶态-非晶态新型复合离子导体的电学性质变化具有新的现象,即在宏观电导率σ_m-组成曲线上出现了电导率增加的“双峰”效应。相应地,在表观活化能E_m-组成曲线和介电常数ε_m-组成曲线上出现了“双谷”。本文还详细讨论了这些实验现象,得到了与理论相符合的结果。 关键词：