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用so1-gel法以正硅酸乙酯、乙醇和蒸馏水为原料,以盐酸为催化剂,包埋三联吡啶钌[Ru(bpy)3C12]制备催化Belousov-Zhabotinsky(BZ)反应的非线性光催化薄膜,并利用紫外分光光度法测定了在薄膜中Ru(bpy)3Cl2的包埋量.通过投影图像的方法光激发BZ反应,在包埋Ru(bpy)3C12的薄膜上产生化学波图像.在薄膜中演化形成的图像具有相当高的图像清晰度.在图像的演化过程中,具有图像反转、边界增强、图像分割等图像处理能力,并可以通过改变BZ反应条件来调控增强某些图像处理能力. 相似文献
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First-principles study of the co-effect of carbon doping and oxygen vacancies in ZnO photocatalyst 下载免费PDF全文
Although tuning band structure of optoelectronic semiconductor-based materials by means of doping single defect is an important approach for potential photocatalysis application,C-doping or oxygen vacancy(Vo)as a single defect in ZnO still has limitations for photocatalytic activity.Meanwhile,the influence of co-existence of various defects in ZnO still lacks sufficient studies.Therefore,we investigate the photocatalytic properties of ZnOx C0.0625(x=0.9375,0.875,0.8125),confirming that the co-effect of various defects has a greater enhancement for photocatalytic activity driven by visible-light than the single defect in ZnO.To clarify the underlying mechanism of co-existence of various defects in ZnO,we perform systematically the electronic properties calculations using density functional theory.It is found that the coeffect of C-doping and Vo in ZnO can achieve a more controllable band gap than doping solely in ZnO.Moreover,the impact of the effective masses of ZnOxC0.0625(x=0.9375,0.875,0.8125)is also taken into account.In comparison with heavy Vo concentrations,the light Vo concentration(x=0.875)as the optimal component together with C-doping in ZnO,can significantly improve the visible-light absorption and benefit photocatalytic activity. 相似文献
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表面活性剂对3-甲基吡啶电氧化制取烟酸的影响 总被引:1,自引:0,他引:1
研究了在阳极液中加入不同类型和不同浓度表面活性剂对3-甲基吡啶电氧化的影响. 结果表明, 十六烷基三甲基溴化铵、脂肪醇聚氧乙烯醚硫酸钠、十二烷基苯磺酸钠、十二烷基二甲基甜菜碱和山梨醇酐单硬脂酸酯的胶团对3-甲基吡啶电氧化有明显的促进作用. 实验结果还表明, 在低浓度的硫酸为支持电解质阳极液中加入表面活性剂与不加表面活性剂相比, 3-甲基吡啶电氧化制取烟酸的选择性和电流效率明显提高. 相似文献
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Several kinds of models have already been proposed to explain the photoemission process. The exact photoemission theory of the semiconductor photocathode was not well established after decades of research. In this paper an integral equation of quantum efficiency (QE) is constructed to describe the photoemission of positive electron affinity (PEA) of the semiconductor photocathode based on the three-step photoemission model. Various factors (e.g., forbidden band gap, electron affinity, photon energy, incident angle, degree of polarization, refractive index, extinction coefficient, initial and final electron energy, relaxation time, external electric field and so on) have an impact on the QE of the PEA semiconductor photocathode, which are entirely expressed in the QE equation. In addition, a simulation code is also programmed to calculate the QE of the K2CsSb photocathode theoretically at 532 nm wavelength. By and large, the result is in line with the expected experimental value. The reasons leading to the distinction between the experimental and theoretical QE are discussed. 相似文献
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Berezinskii-Kosterlitz-Thouless Transition in a Two-Dimensional Random-Bond XY Model on a Square Lattice 下载免费PDF全文
We perform Monte Carlo simulations to study the two dimensional random-bond XY model on a square lattice. Two kinds of bond randomness with the coupling coefficient obeying the Gaussian or uniform distribution are discussed. It is shown that the two kinds of disorders lead to similar thermodynamic behaviors if their variances take the same value. This result implies that the variance can be chosen as a characteristic parameter to evaluate the strength of the randomness. In addition, the Berezinskii-Kosterlitz-Thouless transition temperature decreases as the variance increases and the transition can even be destroyed as long as the disorder is strong enough. 相似文献
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极限的概念是微积分学的基础,如何合理引入和定义这一概念对于《高等数学》的教学显得较为重要.对于一元函数的极限而言,通常可通过数列的极限问题引入直观的极限的概念,并抽象出数列极限的“ε-N”语言,进而通过空心邻域的概念导出一元函数的极限的一般概念(ε-... 相似文献
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结构钢损伤本构关系的研究 总被引:3,自引:0,他引:3
回顾了结构钢损伤模型的发展史,提出了一种新的本构模型-结构钢弹塑性各向异性损伤本构模型,该模型采用混合强化准则,考虑Bauschinger效应,屈服平台、硬化(软化)效应及损伤和损伤演化影响。算例分析结果表明本文模型能够客观地反映结构钢在循环荷载作用下的工作性能、适用于进行钢结构及构件在循环荷载作用下弹塑性反应分析。 相似文献