吡咯俘精酸酐的图像光存储特性

对一种新型可用于可擦重写光存储的有机光致变色材料——吡咯俘精酸酐，测定了它的光致变色双稳态吸收光谱，呈色态的吸收峰在635nm，无色态的吸收峰在385nm。利用其双稳态特性，在吡咯俘精酸酐／PMMA薄膜上实现了图像光存储。所存储的图像对比度高，用普通相机在自然光下即可直接读出。在膜上存储的图像在室温下暗处保存6个月未见消退，估计此条件下保存期可以年计。     

有机光致变色材料的最新成就与机遇

综述了近年来在有机光致变色领域所取得的成就,主要包括螺恶嗪类化合物、吡喃类化合物、俘精酸酐及其衍生物、新型二芳基乙烯和质子转移体系共五大类光致变色体系。     

In situ Observation of the Photochromism in the Langmuir Monolayer of a Non—typical Amphiphilic Spiropyran Derivative at the Air／Water Interface

In situ photochromic process in the monolayer of aphotochromic spiropyran derivative without long alkyl chain,was investigated.The photochromism at the air/water interface under differnet surface pressures was studied by surface pressure-area isotherms,surface pressure-time curves,area-time curves and Brewster angle microscopy.Both forms of the compound were found to form monolayers at the air/water interface althouhg it does not have long alkyl chain.A large area expansion in the monolayer corresponding to a zreo^th order reaction was found at the initial stage of the UV light irradiation.A series of dynamic investigations revealed that at high pressure after phase transition in the monolayer,the surface pressure changes greatly umder alternative irradiation of UV and visible light.An obvious morphological change accompanying with the photochromism was observed in situ.