二苯甲酰-D-酒石酸分子印迹整体柱的制备及其色谱性能

采用紫外光谱法选择丙烯酰胺为功能单体,以二苯甲酰-D-酒石酸(D-DBTA)为模板分子,丙烯酰胺为功能单体,二甲基丙烯酸乙二醇酯为交联剂,甲苯和十二醇为混合致孔剂,用原位分子印迹技术,合成了D-DBTA分子印迹整体聚合物。在优化色谱条件的基础上,25min内基本实现了DBTA消旋体的手性分离,分离度达1.25。对色谱分离过程中的热力学进行分析,在所考察的温度范围内,色谱分离存在两种不同的热力学过程,且两者与范特霍夫方程能够很好地吻合。在这两种热力学过程的转换温度处,分离因子α达最大值。     

Band-stop optical nanofilters with split-ring resonators based on metal–insulator–metal structure

Novel band-stop filters with circular split-ring resonators based on the metal–insulator–metal(MIM) structure are presented, with their transmission properties of SPPs propagating through the filter simulated by the finite-difference timedomain(FDTD) method. The variation of the gap of the split ring can affect the transmission characteristics, i.e., the transmission spectrum of SPPs exhibiting a shift, which is useful for modulating the filter. Linear and nonlinear media are used in the resonator respectively. By varying the refractive index of the linear medium, the transmission properties can be changed obviously, and the effect caused by changing the incident intensity with a nonlinear medium is similar.Several resonant modes that are applicable can be enhanced by changing the position of the gap of the split ring. Thus, the transmission properties can be modulated by adjusting the size of the gap, varying the refractive index, and changing the incident intensity of the input light. These methods may play significant roles in applications of optical integrated circuits and nanostructural devices.     

二阶导数紫外吸收光谱测定复合氨基酸注射液中的色氨酸和苯丙氨酸的含量

复合氨基酸注射液是含有11种氨基酸及甘露醇的复方制剂。文献曾报导用二阶导数光谱测定蛋白质及天然物中的色氨酸;徐绪温等使用双波长分光光度计,用导数光谱法测定了复合氨基酸注射液中色氨酸,本文提出用二阶导数光谱直接测定色氨酸和苯丙氨酸含量的方法。实验方法 (一)仪器与试剂所用仪器为岛津UV-240型自记式紫外分光光度计OP1-1附件。氨基酸标准物均为广州侨光制药厂提供的日本进口试剂,按药典检定合格;甘露醇,分析纯。复合氨基酸注射液由广州侨光制药厂提供,为内含11种氨基酸及甘露醇的无菌水溶液,     

面向结构洞的复杂网络关键节点排序

复杂网络中的结构洞节点对于信息传播具有重要作用, 现有关键节点排序方法多数没有兼顾结构洞节点和其他类型的关键节点进行排序. 本文根据结构洞理论与关键节点排序相关研究选取了网络约束系数、介数中心性、等级度、效率、网络规模、PageRank值以及聚类系数7个度量指标, 将基于ListNet的排序学习方法引入到复杂网络的关键节点排序问题中, 融合7个度量指标, 构建了一个能够综合评价面向结构洞节点的关键节点排序方法. 采用模拟网络和实际复杂网络进行了大量实验, 人工标准试验结果表明本文排序方法能够综合考虑结构洞节点和核心节点, 关键节点排序与人工排序结果具有较高的一致性. SIR传播模型评估实验结果表明由本文选择TOP-K节点发起的传播能够在较短的传播时间内达到最大的传播范围.