A NEW TYPE OF ISOTHERM FOR ZINC LIQUID-SOLID PARTITIONING ON δ-MnO_2,γ-MnOOH AND MANGANIIE IN SEAWATER

This article deals with the interaction of zinc with δ-MnO2,γ-MnOOH and manganite existing in natural water systems. The mechanism of the reaction has been studied in detail. From the fact that the "ratio of ion exchange (%)-pH" graph is an "S shaped" curve, it is possible to deduce that the chemical reaction is of the nature of cation exchange. And since the pH range of ion exchange = 4, it is possible to further deduce that the reaction can be explained by the mechanism of monovalence cation exchange.The main result of this article is the discovery of a new type of isotherm which has not been mentioned in previous literature here and abroad. This isotherm cannot be represented by any presently available adsorption isotherm equations in marine chemistry. The characteristics of this new type of isotherm are as follows: the isotherm has two "knees" and three "plateaus", the heights of these three "plateaus" are in the ratio 1:2:3. In order to explain theoretically our new isotherm, this article suggest     

海水中镉（Ⅱ）与水合氧化钛无机离子交换反应的研究

海洋化学研究的一个主要内容是海水中元素的迁移和变化规律的探索。已经发现，这是与海水中的水合氧化物、粘土矿物和若干有机物之间的离子交换作用密切相关的。在本文中无机离子交换剂是水合氧化钛，金属元素为镉，作为这一方面系统研究工作(在这系列工作中，     

海水中锌在δ-MnO2、水锰矿、γ-MnOOH上分配的分级离子交换等温线崇

海水中微量金属与固体粒子相互作用的研究，是目前海洋化学中的重要课题，它对了解微量金属在海洋巾的含量、分布和变化规律具有重大意义。目前一般认为，海水中悬浮物包括水合氧化物、粘土矿物和有机质三大类。据报道，在海水悬浮物中，水合氧化物的吸附量最大。海水中的水合氧化锰主要以δ-MnO2、水锰矿、γ-MnOOH三种形式。     

海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。     

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater

In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode.     

面向疾病的空间聚集性与影响因素分析方法

疾病的发生与自然环境、社会环境和人群特点密切相关,其发生与流行通常具有一定的空间分布特征。针对目前在疾病空间聚集特征与影响因素的已有研究中,缺少两者关联关系的探讨,以及空间尺度多集中于省、市和县域,因此,本研究提出一种面向疾病空间聚集性与影响因素分析的方法。以武汉市的历史肺结核数据为例,进行基于乡镇尺度的肺结核发病率数据及影响因素数据的处理与整合,基于空间自相关方法分析2011年、2013年和2015年肺结核空间聚集情况;并运用地理探测器探测肺结核发病率空间分布的影响因素及交互作用,探究肺结核空间聚集的成因。结果表明：肺结核热点聚集乡镇主要分布在新洲区、江夏区和蔡甸区,冷点聚集乡镇主要分布在洪山区;植被指数、人口密度、人均GDP及五类兴趣点密度（医疗保健类、生活服务类、餐饮类、住宅类和农林牧渔类）为肺结核发病率空间分布的主要影响因素,其交互作用对肺结核发病率影响显著增强。研究成果可为武汉市肺结核防治提供科学参考。     

南黄海胶体有机碳和溶解有机碳的分布

利用切向超滤技术对胶体有机碳（ＣＯＣ）进行了有效分离,利用紫外／过硫酸钾法分别测定南黄海溶解有机碳（ＤＯＣ）和ＣＯＣ的浓度。测定结果：南黄海表层水ＤＯＣ的平均含量为３４０．０μｍｏｌ／Ｌ;ＣＯＣ的浓度变化为３０．２～１２５．０μｍｏｌ／Ｌ,在ＤＯＣ中所占的比例平均为３０．９％,最高可达５６．６％,结果表明,ＣＯＣ在有机碳的生物地球化学循环中起着重要作用;真溶解态有机碳（ＵＯＣ）和ＣＯＣ之间的非相关性揭示了ＣＯＣ来源的复杂性。     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c