Thermal conductivity measurements of road construction materials in frozen and unfrozen state

A series of thermal conductivity measurements for various materials was performed in a large climate chamber. The size of the chamber allowed the preparation of relatively large samples in a controlled thermal environment. Three types of thermal sensors were used: (1) two needle probes; (2) a grid of temperature sensors, evenly distributed inside the sample; (3) two additional thermal probes, which were simplified versions of an instrument originally developed for measuring thermal properties of the ice/dust mixture expected to exist at the surface of a comet nucleus. They consist of a series of individual temperature sensors integrated into a glass fibre rod. Each of these sensors can be operated in an active (heated) or passive (only temperature sensing) mode. The following sample materials were used: fine-grained reddish sand, coarse-grained moist sand, gravels with various grain size distributions from < 1 cm up to about 6 cm, and for comparison and calibration pure water (with convection suppressed by adding agar-agar), compact ice, and compact granite. Of particular interest are the measurements with composite samples, like stones embedded in an agar-agar matrix. We describe the evaluation methods and present the results of the thermal conductivity measurements.     

A reconstruction of the palaeohydrological conditions of a flood‐plain: a multi‐proxy study from the Grabia River valley mire,central Poland

This study investigated the Grabia River valley mire in central Poland to reconstruct its palaeoenvironmental conditions from the Younger Dryas to the present. We analysed sedimentological, biological and geochemical data from the palaeo‐oxbow lake and valley mire to identify the principal hydrological trends, especially episodes of high water level. During the Lateglacial and Holocene, the Grabia River had a meandering channel, and its hydraulic parameters and the channel dimensions changed in response to climatic oscillations and vegetation development. We identified phases of high flood intensity and high groundwater level that correlate with regional and supraregional climatic events. The frequency and timing of palaeohydroclimatic oscillations show strong similarities to records from other sites in Poland and the rest of Europe. We show that various analytical methods, namely, pollen, plant macrofossils, Cladocera, Chironomidae, sedimentological, geochemical and radiocarbon data, can be effective tools for reconstructing past hydroclimatic changes in palaeo‐oxbow lakes and investigating the effects of past climate changes on river environments. The high sensitivity of the biota, especially Cladocera, to changes in water level permits the reconstruction of palaeoecological changes, especially flood episodes that occurred in the river valley. In particular, the increase in the proportion of sediment‐associated Cladocera and pelagic taxa was closely correlated with floods. Through comparisons with the palaeobiological data, geochemical data allowed the identification of humid phases within the fen associated with a rising groundwater table, direct fluvial activity (floods) and alluvial deposition. We also discuss the limitations of palaeohydrological reconstructions based on these proxies, especially on fossil aquatic invertebrates.     

Characterization of fluid inclusions from mineralized pegmatites of the Damara Belt,Namibia: insight into late-stage fluid evolution and implications for mineralization

Mineralogy and Petrology - Mineralized NYF and LCT pegmatites occur throughout the northeast-trending Neoproterozoic Damara Belt, Namibia. Mineralization in the pegmatites varies geographically,...     

Hyperspectral imaging of sedimentary bacterial pigments: a 1700-year history of meromixis from varved Lake Jaczno,northeast Poland

Hypoxia in freshwater systems is currently spreading globally and putting water quality, biodiversity and other ecosystem services at risk. Such adverse effects are of particular concern in permanently stratified meromictic lakes. Yet little is known about when and how meromixis and hypoxia became established (or vanished) prior to anthropogenic impacts, or how human activities such as deforestation, erosion and nutrient cycling affected the mixing regimes of lakes. We used calibrated hyperspectral imaging (HSI) data in the visible and near infrared range from a fresh, varved sediment core taken in Lake Jaczno, NE Poland, to map sedimentary pigments at very high resolution (sub-varve scale) over the past 1700 years. HSI-inferred bacteriopheophytin a (bphe a, produced by anoxygenic phototrophic bacteria) serves as a proxy for meromixis, whereas HSI-inferred green pigments (chlorophyll a and diagenetic products) can be used as estimators of aquatic productivity. Meromixis was established and vanished long before significant human disturbance in the catchment was observed in the late eleventh century AD. Under pre-anthropogenic conditions, however, meromixis was interrupted frequently, and the lake mixing regime flickered between dimixis and meromixis. During two periods with intense deforestation and soil erosion in the catchment, characterised by sedimentary facies rich in clay and charcoal (AD 1070–1255 and AD 1670–1710), the lake was mostly dimictic and better oxygenated than in periods with relative stability and a presumably closed forest around the lake, i.e. without human disturbances. After ca. AD 1960, meromixis became established quasi-permanently as a result of eutrophication. The persistent meromixis of the last ~60 years is unusual with respect to the record of the last 1700 years.     

Lithological and geochemical record of anthropogenic changes in recent sediments of a small and shallow lake (Lake Pusty Staw,northern Poland)

The article presents the results of lithological and geochemical investigations of recent sediments of Lake Pusty Staw. The analysed sediments document about 300 years of the history of this lake. Historical materials indicate that significant changes in the catchment of the lake took place from the beginning of the 18th century (deforestation and afforestation) followed by 19th century tourist development, and 20th century industrialisation. The sediments were dated using the ²¹⁰Pb and ¹³⁷Cs method and core lithology. These made it possible to establish a reliable chronology to the year 1730. The calculated sedimentation rates ranged between 0.17 and 0.83 cm year^–1. There was a period of intensified erosion caused by land clearance between 1734 and 1810, which resulted in an acceleration in sedimentation rate (0.36 cm year^–1) and a change of lithological type of sediment from detritus gyttja to clayey gyttja. On the basis of Cu, Zn, Cd and Pb content in the sediments, it was determined that the beginning of pollution of the lake dates back to the 19th century and was caused probably by the existence of a health resort. A systematic increase in pollution occurred in the 20th century as a result of industrial plants. Normalised with respect to Al, the content of heavy metals in polluted sediments was from several to twenty times higher than in sediments of the preindustrial period, and a comparison of historical materials with changes of sediments in most cases made it possible to identify the direct causes of the increase in pollution.     

Impact of microtopography on the geochemistry of soils within archaeological sites in SE Poland

The geochemical record of human impact within three archaeological sites in SE Poland was analysed. The total levels of Cd, Cu, Pb, Zn and P were defined. The content of the studied elements was found to be higher than the determined geochemical background. In all cases, significantly higher concentrations (2–3 times) of trace metals were found in sediments filling small depressions and foot-slope locations. These concentrations were often higher than in the profiles within the archaeological objects. The vertical distributions of elements were also different from soil profiles located on flat surfaces. The study thus confirms that microtopography and soil erosion may impact (diversify) the initial horizontal and vertical variation of geochemistry of soils within archaeological sites caused by human activity. This should be taken into account when using geochemical prospecting in archaeological studies in areas with varied topography.     

Seismicity before and after the two great Sumatra earthquakes of 2004 and 2005

The Harvard CMT catalogue contains 481 shallow earthquakes that occurred between 1 January 1977 and 30 November 2005 within a broad region defined by the geographical latitude from 3°S to 14°N and by the longitude from 91°E to 102°E. There are 230 events that occurred before the great earthquake of 26 December 2004. Their surface distribution is not uniform and the source area of the 2004 great event appears as an area of seismic quiescence with a radius of about 100 km. There are 186 events that occurred between the two great earthquakes of 26 December 2004 and 28 March 2005. Practically all of them are located to the northwest from the great earthquake of 2005, that in turn was followed by 63 events, mostly located to the southeast. The cumulative seismic moment from earthquakes before the occurrence of the great event of 2004 increased rather regularly with time, with sudden increase about twenty years and two years before the occurrence of the great event. The seismic moment of earthquakes between the two great events increased rapidly during the first ten-fifteen days, then flattened out and increased slowly with time. After the great event of 2005 the seismic moment shows quiet increase during some 115 days, then sudden jump, followed by very small activity till the end of our observations. From the spatial distribution of seismic moment of earthquakes that occurred before the great event of 2004 it follows that its largest release appeared to the southeast from the great event, around the rupture area of the great earthquake of 2005. The largest release of seismic moment from earthquakes between the two great events is observed in the vicinity of the 2004 event and further up to the north. The seismic moment from earthquakes that occurred after the great event of 2005 was mostly released in its vicinity and further down to the south.     

Non-woven polypropylene fabric modified with carbon nanotubes and decorated with nanoakaganeite for arsenite removal

Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L^?1, at pH 6.5 and with a sorbent dose of 5 g L^?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g^?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g^?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.