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Photoelectric detectors for the measurement of photolysis frequencies of different trace gases in the atmosphere are described. They exhibit uniform response characteristics over one hemisphere (2 sr) and wavelength characteristics closely matched to those of the photolysis frequencies J O1D, J NO2, and J NO3, respectively. Absolute calibration of the J O1D detector was performed by chemical actinometry with an accuracy of ±16 percent. Simultaneous measurements of J NO2 and J O1D are presented.  相似文献   
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Considering food web energetics and elemental cycling together allows the testing of hypotheses about the coevolution of biological systems and their physical environment. We investigated the energy flow and the distribution of 25 elements in the Steina River.¶We constructed an annual energy flow network and estimated the emergy ("embodied energy" that includes all the energy involved in a process) contributions of resources sustaining the system. Furthermore, we measured the concentration of various macronutrients, essential elements, and heavy metals in the physical environment and trophic compartments. Finally, we examined the hypothesis of a positive relationship between the "rarity" of an element and its tendency to bioaccumulate. To do so, we used transformity, the relative energy input required to sustain a compartment's net production or the concentration differential of an element between the living community and the physical environment.¶The resulting energy flow network is one of the most complete available for streams. In the Steina, over 99% of the energy input is transported through the system without being processed. Dissolved inorganic matter and sunlight are the largest inputs, but uptake efficiency is much higher for dissolved and particulate organic matter. Transformities of trophic compartments and elements span 6 to 7 orders of magnitude.¶The tendency to bioaccumulate was as predicted for most elements, with macronutrients showing no accumulation and heavy elements accumulating in high-transformity compartments. However, Na and K were found at highest concentrations in consumers, and Pb, Ga, and Cd in algae. Improved estimates may become possible as more knowledge is available on ecosystem flows. We suggest further ways of testing hypotheses about strategies of element processing.  相似文献   
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We are investigating the hypothesis that Compact High-Velocity Clouds (CHVCs) are the left-over building blocks of Local Group galaxies. To this end, we are searching for their embedded stellar populations using FORS at the VLT. The search is done with single-star photometry in V and I bands, which is sensitive to both, young and old, stellar populations. Five CHVCs of our sample have been observed so far down to I=24. We pointed the VLT towards the highest HI column density regions, as determined in Effelsberg radio data. In an alternate approach, we searched 2MASS public data towards those 5 CHVCs down to K=16. While the VLT data probe the central regions out to distance moduli of about 27, the 2MASS data are sensitive to a population of red giant stars to distance moduli of about 20. The 2MASS data, on the other hand, cover a much wider field of view than the VLT data (radius of 1 degree versus FORS field of 6.8 arcmin). We did not find a stellar population intrinsic to the CHVCs in either data. In this paper, we illustrate our search methods. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
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  总被引:1,自引:2,他引:1  
In this article, the recently proposed approach known as ‘risk targeting’ for the development of national seismic design maps is investigated for mainland France. Risk targeting leads to ground-motion maps that, if used for design purposes, would lead to a uniform level of risk nationally. The Eurocode 8 design loads currently in force for France are used as the basis of this study. Because risk targeting requires various choices on, for example, the level of acceptable risk to be made a priori and these choices are not solely engineering decisions but involve input from decision makers we undertake sensitivity tests to study their influence. It is found that, in contrast to applications of this methodology for US cities, risk targeting does not lead to large modifications with respect to the national seismic hazard map nor to changes in the relative ranking of cities with respect to their design ground motions. This is because the hazard curves for French cities are almost parallel. In addition, we find that using a target annual collapse probability of about 10?5 for seismically designed buildings and a probability of collapse when subjected to the design PGA of 10?5 leads to reasonable results. This is again in contrast to US studies that have adopted much higher values for both these probabilities.  相似文献   
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Summary UsingCraddock's method of representing the annual temperature variation by a two-term harmonic form fitted to monthly means, the harmonic coefficients of 63 stations in western Europe and around the Mediterranean Sea, as well as the 5-day normals for 24 Mediterranean stations, were computed and tabulated. In addition, some of the harmonic coefficients were charted and isoplethed, showing very distinctly the influence of continentality and topography. These charts, together withCraddock's charts for northern and northwestern Europe, provide fairly complete coverage of Europe and the Mediterranean area.This paper was prepared in the offices of the Technical Support Division of the 2d Weather Wing, United States Air Force, as a matter of routine business. The information contained herein was presented at the 5th Meeting of the Italian Society of Geophysics and Meteorology by Dr.Ingrid Weiss (Genoa: 23–25 April 1957). Since the paper is of general interest to all meteorologists of the Mediterranean area, it is published here with the permission of the originating agency as «Mémoire No. 3 du Centre International de Recherches sur la Météorologie de la Méditerranée (CIRMM)».  相似文献   
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The Southern Venn-Stavelot Massif is characterized by Ordovician and Devonian rocks very rich in manganese and aluminum, which are attacked by a low grade regional metamorphism. The assemblages 1 (phengite, paragonite, chlorite, chloritoid, garnet, quartz, hematite, rutile) and 2 (phengite, paragonite, chlorite, kaolinite (andalusite, pyrophyllite), garnet, quartz, hematite, rutile) are of basic interest for the formation of chloritoid. As the two rock types are isofaciell and quasi-identical in chemistry except for the iron oxides, there is clear evidence for the influence of on the chloritoid formation at its lower p-T stability limit. This can be shown by a discussion of the phase relations of chloritoid, garnet, kaolinite, chlorite and phengite in respect to the oxidation ratio mol 2 Fe2O3x 100/2 Fe2O3+ FeO of the host rocks. Especially chloritoid and chlorite change their chemistry in a characteristic way with rising oxidation ratio in getting richer and richer in manganese and magnesium (chloritoid) and magnesium (chlorite). A simultaneous increase in trivalent iron in these phases is supposed. At an oxidation ratio of 85–90 the stability limit of chloritoid is reached. The increasing substitution of manganese and magnesium up to this limit should have a stabilizing effect. In a rough estimate the oxygen partial pressure is supposed to be in the order of 10−10 atm at the stability limit of chloritoid assuming a temperature of metamorphism between 360–400° C. Rocks with oxidation ratios between 90 and 100 are characterized by the presence of kaolinite. If the oxidation ratio is still higher (all iron as Fe3+, parts of the manganese in the trivalent state), the rocks belong to assemblage 3 (phengite, paragonite, chlorite, viridine, (kaolinite), (garnet), quartz, hematite, braunite, rutile). Dedicated to Prof. Dr. K. Jasmund at his 60. birthday.  相似文献   
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Abstract– We report Mg‐Al and Ca‐Ti isotopic data for meteoritic nanodiamonds separated from the Allende CV3 and Murchison CM2 meteorites. The goal of this study was to search for excesses in 26Mg and 44Ca, which can be attributed to the in situ decay of radioactive and now extinct 26Al and 44Ti, respectively. Previous work on presolar SiC and graphite had shown that 26Al/27Al and 44Ti/48Ti ratios in presolar grains can be used to discriminate between different types of stellar sources. Aluminum and Ti concentrations are low in the meteoritic nanodiamonds of this study. Murchison nanodiamonds have higher Al and Ti concentrations than the Allende nanodiamonds. This can be attributed to contamination and the presence of presolar SiC in the Murchison nanodiamond samples. 26Mg/24Mg and 44Ca/40Ca ratios are close to normal in Allende nanodiamonds with upper limits on the initial 26Al/27Al and 44Ti/48Ti ratios of approximately 1 × 10?3. These ratios are factors of 10–1000 and, respectively, 1–1000 lower than those of presolar SiC and graphite grains from supernovae. The 26Al/27Al and 44Ti/48Ti data for nanodiamonds are compatible with an asymptotic giant branch star or solar system origin, but not with a supernova origin of a major fraction of meteoritic nanodiamonds. The latter possibility cannot be excluded, though, as the diamond separates may contain significant amounts of contaminating Al and Ti, which would lower the inferred 26Al/27Al and 44Ti/48Ti ratios considerably.  相似文献   
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