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An overview is presented on possible mechanisms that control the leaching behaviour of the oxyanion forming elements As, Cr, Mo, Sb, Se, V and W in cementituous systems and alkaline solid wastes, such as municipal solid waste incinerator bottom ash, fly ash and air pollution control residues, coal fly ash and metallurgical slags. Although the leachability of these elements generally depends on their redox state, speciation measurements are not common. Therefore, experimental observations available in the literature are combined with a summary of the thermal behaviour of these elements to assess possible redox states in freshly produced alkaline wastes, given their origin at high temperature. Possible redox reactions occurring at room temperature, on the other hand, are reviewed because these may alter the initial redox state in alkaline wastes and their leachates. In many cases, precipitation of oxyanions as a pure metalate cannot provide a satisfactory explanation for their leaching behaviour. It is therefore highly likely that adsorption and solid solution formation with common minerals in alkaline waste and cement reduce the leachate concentration of oxyanions below pure-phase solubility. 相似文献
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Large-scale ancient landslides of the area of more than 5 km2 and volume exceeding 200 × 106 m3 are characteristic features of the valleys incised in the northern periphery of the Crimean Mountains (Ukraine). The largely
affected area is located in the outermost cuesta range of the Crimean Mountains which consists of rigid Sarmatian limestones
overlying weak Middle Miocene and Upper Palaeogene deposits. A giant landslide arose in the Alma water gap as a reflection
of several coincident preparatory factors such as suitable bedrock stratification, smectite-rich bedrock exposed to swelling
activity, presence of faults parallel to the valley trend, and river capture event which preceded the landslide event. The
occurrence of such ancient megaslides is particularly interesting in the area which is characterized by low precipitation
(<500 mm/year) and weak contemporary seismicity. It probably reflects a more dynamic environment in humid phases of the Holocene;
however, seismic triggering along the Mesozoic suture zone cannot be rejected. Compressional features such as gravitational
folds in the central and distal parts of the landslide, which probably correlate with the whole landslide genesis or its significant
reactivation, arose, according to the radiocarbon dating, during the Holocene climatic optimum in the Atlantic period. The
slope deformation has been relatively quiescent since that time, except minor historic reactivization which took place in
the frontal part of the landslide. We suppose that the studied landslide could be classified as a transitional type of slope
deformation with some signs of spreading and translational block slides. 相似文献
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Tom Horlick-Jones 《GeoJournal》1995,37(3):329-334
Cities like London, New York and Los Angeles possess complex urban environments that, despite their technological sophistication, present their citizens with a multiplicity of risks. This paper presents a discussion of the effects of physical and social trends on the creation of risk and vulnerability to hazard in such cities. The interplay between physical hazards and perceived risks in late modern, or Risk, urban societies is considered, and the impact of this process on adjustment to hazard. 相似文献
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Mark E Bailey and Tom Ray give an overview of the National Astronomy Meeting in Dublin, where record numbers of astronomers went to talk, listen and network. 相似文献
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We used multivariate statistical techniques to analyse the distributions of surface sediment chironomid assemblages with respect to surface-water temperature, and an additional set of 27 environmental variables, in 30 freshwater lakes of northern Fennoscandia. Our study transect spans boreal coniferous forest to subarctic tundra and includes a steep temperature gradient. Canonical correspondence analysis (CCA) with forward selection and associated Monte Carlo permutation tests revealed that there were statistically significant (P<0.05) relationships between chironomid distributions and two environmental variables, namely lakewater temperature and maximum lake depth. A constrained CCA with temperature as the only predictor variable suggested that the relationship between lakewater temperature and chironomid composition was sufficiently robust for developing a weighted-averaging (WA) based quantitative inference model that will allow palaeotemperature reconstructions using subfossil chironomid remains preserved in lake sediments. 相似文献
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