An EPR study of native radiation-induced paramagnetic defects in sudoite (di–trioctahedral Al–Mg chlorite) from the alteration halo related to unconformity-type uranium deposits

Natural radiation-induced defects were identified in specimens of sudoite (Al–Mg di-trioctahedral chlorite) related to unconformity-type uranium deposits at the base of the Athabasca Group (Saskatchewan, Canada), using electron paramagnetic resonance (EPR) spectroscopy at X- and Q-band frequencies. X-band spectra indicate the presence of a main native defect, named the A_s-center, whose EPR signal is dominated by an axially distorted spectrum with apparent principal components as follows: g _// = 2,051 and g _⊥ = 2,005, and a secondary defect with apparent component g = 2,025. The study of oriented specimens shows that the main defect has its g _// component perpendicular to the (ab) plane of sudoite. The A_s-center corresponds to an electron hole located on oxygen atoms of the structure and is likely associated with Si, according to the lack of hyperfine structure. The A_s-center in sudoite has EPR parameters similar to the A-center in kaolinite and dickite, and the A_i-center in illite. The saturation behavior of EPR spectra as a function of power demonstrates that native defects of sudoite are different from those known in other clays, such as kaolinite, dickite or smectite, but are similar to those of illite. The isochronal annealing data suggest that the main defect in sudoite is stable to more than 300°C. The corresponding defects characterized in sudoite may have the potential for tracing past radionuclide migration around unconformity-type uranium deposits.     

The ECORS-Truc Vert’08 nearshore field experiment: presentation of a three-dimensional morphologic system in a macro-tidal environment during consecutive extreme storm conditions

A large multi-institutional nearshore field experiment was conducted at Truc Vert, on the Atlantic coast of France in early 2008. Truc Vert’08 was designed to measure beach change on a long, sandy stretch of coast without engineering works with emphasis on large winter waves (offshore significant wave height up to 8 m), a three-dimensional morphology, and macro-tidal conditions. Nearshore wave transformation, circulation and bathymetric changes involve coupled processes at many spatial and temporal scales thus implying the need to improve our knowledge for the full spectrum of scales to achieve a comprehensive view of the natural system. This experiment is unique when compared with existing experiments because of the simultaneous investigation of processes at different scales, both spatially (from ripples to sand banks) and temporally (from single swash events to several spring-neap tidal cycles, including a major storm event). The purpose of this paper is to provide background information on the experiment by providing detailed presentation of the instrument layout and snapshots of preliminary results.     

Origin and mechanism of Subantarctic Mode Water formation and transformation in the Southern Indian Ocean

The sources and pathways of mode waters and lower thermocline waters entering the subtropical gyre of the Indian Ocean are examined. A Lagrangian analysis is performed on an eddy-admitting simulation of the Global Ocean performed by the DRAKKAR Group (NEMO/OPA), which captures the main observed features. We trace the subducted mode water’s pathways, identify their formation regions and trace whether their source waters come from the Atlantic, Pacific or Indian sectors of the Southern Ocean. Three main sites for mode waters ventilation in the Indian sector are identified with different circulation pathways and source water masses: (a) just north of Kerguelen, where 4.2 Sv of lighter Subantarctic Mode Waters (SAMW); σ ₀ ∼ 26.5) are exported—originating in the Atlantic and Agulhas Retroflection regions; (b) SW of Australia, where 6.5 Sv of medium SAMW (σ ₀ ∼ 26.6) are ventilated—originating in the southern and denser Agulhas Retroflection region; (c) SW of Tasmania and along the South Australian coast, where 3 Sv of denser SAMW (σ ₀ ∼ 26.75) are ventilated—originating from three sources: Leeuwin Current waters, Tasman Sea (Pacific) waters and Antarctic Surface Waters. In all cases, modelled mode waters were last ventilated in the Indian Ocean just north of the deepest winter-mixed layers. For the waters subducted SW of Australia, the last ventilation site extends even further north. Waters ventilated in the deepest mixed layers north of the Subantarctic Front are then re-ventilated 5 years later southwest of Australia. The model results raise new hypotheses that revisit the classical picture of the SAMW formation and transformation, where a large homogeneous mixed layer is subducted and ‘slides’ equatorward, essentially maintaining the T/S characteristics acquired at the surface. Firstly, the last ventilation of the modelled mode waters is not in the region of the deepest mixed layers, as previously thought, but further north in regions of moderate meso-scale eddy activity. Secondly, the model shows for the first time a significant source region for Indian Ocean mode waters coming from deep winter-mixed layers along the south Australian coast. Finally, this analysis shows how the mode water characteristics are modified after subduction, due to internal eddy mixing. The simulation shows that resolved eddies have a strong impact on the mixed layer properties and that isopycnal eddy mixing also contributes to the generation of more homogeneous mode water characteristics in the interior.     

Late Quaternary kinematics of the Pallatanga strike-slip fault (Central Ecuador) from topographic measurements of displaced morphological features

The northeast-trending Pallatanga right-lateral strike-slip fault runs across the Western Cordillera connecting N50E-N70E trending normal faults in the Gulf of Guayaquil with N-S reverse faults in the Interandean Depression. Over most of its length, the fault trace has been partly obscured by erosional processes and can be inferred in the topography only at the large scale. Only the northern fault segment, which follows the upper Rio Pangor valley at elevations above 3600 m, is prominent in the morphology. Valleys and ridges cut and offset by the fault provide an outstanding record of right-lateral cumulative fault displacement. The fault geometry and kinematics of this particular fault segment can be determined from detailed topographic levellings. The fault strikes N30E and dips 75 to the NW. Depending on their size and nature, transverse morphological features such as tributaries of the Rio Pangor and intervening ridges, reveal right-lateral offsets which cluster around 27 ± 11m, 41.5 ± 4 m, 590 ± 65 m and 960 ± 70 m. The slip vector deduced from the short-term offsets shows a slight reverse component with a pitch of about 11.5 SW. The 41.5 ± 4 m displacements are assumed to be coeval with the last glacial termination, yielding a mean Holocene slip-rate of 2.9- 4.6 mm yr⁻¹. Assuming a uniform slip rate on the fault in the long term, the 27 m offset appears to correlate with an identified middle Holocene morphoclimatic event, and the long term offsets of 590 m and 960 m coincide with the glacial terminations at the beginning of the last two interglacial periods.