Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.     

The dynamics of the northwestern border of the Carpathians

The border area between the Bohemian Massif and the Carpathians arc is covered by dense networks of repeated levellings as well as horizontal (triangulation, trilateration) measurements. The results were adjusted in separate vertical or horizontal networks respectively. Derived rates of vertical and horizontal movements are presented. The properties of these movements are discussed as a background to the tectonic development of the area under study.     

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.     

Induction Sounding of the Earth’s Mantle at a New Russian Geophysical Observatory

Deep magnetotelluric (MT) sounding data were collected and processed in the western part of the East European Craton (EEC). The MT sounding results correspond well with impedances obtained by magnetovariation (MV) sounding on the new geophysical observatory situated not far from the western border of Russia. Inversion based on combined data of both induction soundings let us evaluate geoelectrical structure of the Earth’s crust and upper and mid-mantle at depths up to 2000 km, taking into account the harmonics of 11-year variations. Results obtained by different authors and methods are compared with similar investigations on the EEC such as international projects CEMES in Central Europe and BEAR in Fennoscandia.     

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.     

Methane fluxes in the southeastern Baltic Sea

New data from surveys of gas-bearing mud areas in the Gdansk Deep (southeastern Baltic Sea) were collected during four research cruises in 2009–2011. These revealed the presence of seven large pockmarks apart from the three already known, and enabled significant improvement of the existing digital map of gassy mud distribution. Based on geochemical sediment analyses, calculated diffusive methane fluxes from the upper (0–5?cm) seabed layer into near-bottom waters were highest—3.3?mmol/(m²?day)—in pockmark mud, contrasting strongly with the minimum value of 0.004?mmol/(m²?day) observed in typical, background mud. However, fluxes of less than 0.1?mmol/(m²?day) were observed in all sediment types, including pockmarks. In a newer attempt to roughly estimate budgets at a more regional scale, diffusive methane venting amounts to 280?×?10⁶?mmol/day for southeastern Baltic Sea muddy sediments. Elongated pockforms in the southern Gotland Deep, known since the end of the 1980s as pockmarks, had methane concentrations that were similar to those of gassy mud from the Gdansk Basin, and there was no geo-acoustic evidence of considerably increased gas levels.     

Robotic optical telescopes global network MASTER II. Equipment, structure, algorithms

Presented paper describes the basic principles and features of the implementation of a robotic network of optical telescopes MASTER, designed to study the prompt (simultaneous with gamma radiation) optical emission of gamma-ray bursts and to perform the sky survey to detect unknown objects and transient phenomena. With joint efforts of Sternberg astronomical institute, High altitude astronomical station of the Pulkovo observatory, Ural state university, Irkutsk state university, Blagoveshchensk pedagogical university, the robotic telescopes MASTER?II near Kislovodsk, Yekaterinburg, Irkutsk and Blagoveshchensk were installed and tested. The network spread over the longitudes is greater than 6?h. A further expansion of the network is considered.     

极地冰层回转钻进切削热量测试装置的研制

极地冰盖深部“暖冰”层钻进时,由于冰层的温度较高,接近甚至达到冰的压力熔点,回转钻进时产生的切削热量极易使冰屑融化,导致机械钻速慢、取心率低、卡钻事故频发。钻压、转速、切削具结构等参数均对切削热量有一定的影响,有必要设计一套实验装置对切削热量进行测试,从而为设计切削具结构、优化钻进参数组合提供理论依据。以XY-1型岩心钻机钻进系统为平台,利用无线信号传输原理设计了冰层回转钻进切削热量测试实验台。初步测试结果表明,该实验装置能够准确测量钻压、扭矩、切削温度等参数,可用来进行相关的实验研究。     

Prolonged Dry Episodes over North America: New Tendencies Emerging During the Last 40 Years

A disproportionate increase in precipitation coming from intense rain events, in the situation of general warming (thus, an extension of the vegetation period with intensive transpiration) and an insignificant change in total precipitation could lead to an increase in the frequency of potentially serious type of extreme events: prolonged periods without precipitation (even when the mean seasonal rainfall totals increase). This paper investigates whether this development is already occurring during the past several decades over North America south of 55°N, for the same period when changes in frequency of intense precipitation events are being observed. Lengthy strings of “dry” days without sizeable (>1.0 mm) precipitation were assessed only during the warm season (defined as a period when mean daily temperature is above the 5℃ threshold) when water is intensively used for transpiration and prolonged periods without sizable rainfall represent a hazard for terrestrial ecosystem's health and agriculture. During the past four decades, the mean duration of prolonged dry episodes (20 days or longer in southeastern Canada, 1 month or longer in the Eastern United States and along the Gulf Coast of Mexico and 2 months or longer in the Southwestern United States and Northern Mexico) has significantly increased. As a consequence, the return period of 1 month long dry episodes over the Eastern U.S. has been reduced more than twofold from 15 to 6~7 years. The longer average duration of dry episodes has occurred during a relatively wet period around most of the continent south of 55°N but is not observed over the Northwestern U.S. and adjacent regions of Southern Canada. 