A model for the viscosity of rhyolite as a function of H2O-content and pressure: A calibration based on centrifuge piston cylinder experiments

The Newtonian viscosity of synthetic rhyolitic liquids with 0.15-5.24 wt% dissolved water was determined in the interval between 580 and 1640 °C and pressures of 1 atm and 5-25 kbar. Measurements were performed by combining static and accelerated (up to 1000g) falling sphere experiments on water-bearing samples, with high temperature concentric cylinder experiments on 0.15 wt% H₂O melts. These methods allowed viscosity determinations between 10² and 10⁷ Pa s, and cover the complete range of naturally occurring magmatic temperatures, pressures, and H₂O-contents for rhyolites.Our viscosity data, combined with those from previous studies, were modeled by an expression based on the empirical Vogel-Fulcher-Tammann equation, which describes viscosities and derivative properties (glass transition temperature T_g, fragility m, and activation volume of viscous flow Va) of silicic liquids as a function of P-T-X_(H2O). The fitted expressions do not account for composition-dependent parameters other than X_(H2O) and reproduce the entire viscosity database for silicic liquids to within 3.0% average relative error on log η (i.e. std. error of estimate of 0.26 log units).The results yield the expected strong decrease of viscosity with temperature and water content, but show variable pressure dependencies. Viscosity results to be strongly affected by pressure at low pressures; an effect amplified at low temperatures and water contents. Fragility, as a measure for the deviation from Arrhenian behavior, decreases with H₂O-content but is insensitive to pressure. Activation volumes are always largely negative (e.g., less than −10 cm³/mol) and increase strongly with H₂O-content. Variations in melt structure that may account for the observed property variations are discussed.     

δO of carbonate, quartz and phosphate from belemnite guards: implications for the isotopic record of old fossils and the isotopic composition of ancient seawater

Belemnite guards of Cretaceous and Jurassic age were found to contain varying amounts of quartz deposited both on the external surface and inside the rostrum. The oxygen isotopic composition of coexisting carbonate, quartz and phosphate from the same rostrum was measured according to well-established techniques. None of these compounds showed isotopic values in equilibrium with one another. Assuming δ¹⁸O values of the diagenetic water within the range of meteoric waters, the δ¹⁸O(SiO₂) yield temperatures in agreement with the apparent secondary origin of this phase. The δ¹⁸O(CO₃²⁻) range, with a certain continuity, between −10.8 and +0.97 PDB-1 with most of the intermediate values being within the range of the carbonate isotopic values of Mesozoic fossils. The most positive isotopic results obtained from phosphate are close to +23/+24‰ (V-SMOW). They can hardly be related to a secondary origin of the phosphate, or to the presence of diagenetic effects, since these results are among the most positive ever measured on phosphate. As far as we know there is no widespread diagenetic process determining an ¹⁸O enrichment of phosphate. The very low concentration of phosphate did not allow the determination of its mineralogical composition. All the available δ¹⁸O(PO₄³⁻) values from belemnite and non-belemnite fossils of marine origin of Tertiary and Mesozoic age are reported along with the newly measured belemnites. The following conclusions may be drawn from the data reported: (1) the pristine oxygen isotope composition of fossil marine organisms (either carbonate or phosphate) may easily undergo fairly large changes because of oxygen isotope exchange processes with diagenetic water; this process is apparent even in the case of geologically recent fossils; (2) the δ¹⁸O(PO₄³⁻) of belemnite rostra seems to be, at least in the case of the most positive results, in isotopic equilibrium with environmental water because of the similarity between the results from Cretaceous belemnites and the results from Cretaceous and Lower Tertiary pelecypods and fish teeth; 3) if so, the only feasible interpretation that can be suggested for the ¹⁸O enriched data is the possibility of a relatively large variation of the oxygen isotopic composition of ocean paleowater from Jurassic to recent time.     

An empirical equation for tunnel inflow assessment: application to sedimentary rock masses

Groundwater inflow assessment is essential for the design of tunnel drainage systems, as well as for assessment of the environmental impact of the associated drainage. Analytical and empirical methods used in current engineering practice do not adequately account for the effect of the jointed-rock-mass anisotropy and heterogeneity. The impact of geo-structural anisotropy of fractured rocks on tunnel inflows is addressed and the limitations of analytical solutions assuming isotropic hydraulic conductivity are discussed. In particular, the study develops an empirical correction to the analytical formula frequently used to predict groundwater tunnel inflow. In order to obtain this, a discrete network flow modelling study was carried out. Numerical simulation results provided a dataset useful for the calibration of some empirical coefficient to correct the well-known Goodman’s equation. This correction accounts for geo-structural parameters of the rock masses such as joint orientation, aperture, spacing and persistence. The obtained empirical equation was then applied to a medium-depth open tunnel in Bergamo District, northern Italy. The results, compared with the monitoring data, showed that the traditional analytical equations give the highest overestimation where the hydraulic conductivity shows great anisotropy. On the other hand, the empirical relation allows a better estimation of the tunnel inflow.     

Distrubution of Dissolved and Particulate Iron, copper and Manganese in the Shelf waters of the Ross sea (Antarctica)

Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies.
Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients.
In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred.
The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter.     

Relict sand dredging for beach nourishment in the central Tyrrhenian Sea (Italy): effects on benthic assemblages

The aim of this study is to analyse the effects in space and time of relict sand-dredging activities on macrobenthic assemblages, in an area situated offshore Montalto di Castro (central Tyrrhenian Sea, Italy), and to analyse the recolonisation processes of macrobenthos in the dredged areas. The area in question is characterised by relict sand deposits (Holocenic paleo-beaches), used for beach nourishment along the Latium coast. The effects of sand extraction on benthic assemblages were investigated before, during and after three dredging operations. The sites analysed are located within the dredged areas (inside stations) and in neighbouring, not dredged, areas (outside stations). The results showed that the impact of sand extraction was confined to the dredged stations and to the areas in proximity to the dredged areas. During dredging activities, the structure of benthic assemblages within the impacted stations was characterised by low species richness and diversity. Both the direct removal of sediment and the re-suspension and consequent deposition of fine sediment affected benthic assemblages of the impacted stations. A few months after the dredgings, a recolonisation process was still observed at all the impacted stations. A gradual recolonisation process was observed at those stations affected by only one dredging, whereas a different recolonisation was observed at those stations affected by two dredgings over time. This study suggests that differences of re-colonisation processes of benthic assemblages are related to the intensity of dredging operations in terms of dredging frequency.     

The Seismotectonics of the Po Plain (Northern Italy): Tectonic Diversity in a Blind Faulting Domain

We present a systematic and updated overview of a seismotectonic model for the Po Plain (northern Italy). This flat and apparently quiet tectonic domain is, in fact, rather active as it comprises the shortened foreland and foredeep of both the Southern Alps and the Northern Apennines. Assessing its seismic hazard is crucial due to the concentration of population, industrial activities, and critical infrastructures, but it is also complicated because (a) the region is geologically very diverse, and (b) nearly all potential seismogenic faults are buried beneath a thick blanket of Pliocene–Pleistocene sediments, and thus can be investigated only indirectly. Identifying and parameterizing the potential seismogenic faults of the Po Plain requires proper consideration of their depth, geometry, kinematics, earthquake potential and location with respect to the two confronting orogens. To this end, we subdivided them into four main, homogeneous groups. Over the past 15 years we developed new strategies for coping with this diversity, resorting to different data and modeling approaches as required by each individual fault group. The most significant faults occur beneath the thrust fronts of the Ferrara-Romagna and Emilia arcs, which correspond to the most advanced and buried portions of the Northern Apennines and were the locus of the destructive May 2012 earthquake sequence. The largest known Po Plain earthquake, however, occurred on an elusive reactivated fault cutting the Alpine foreland south of Verona. Significant earthquakes are expected to be generated also by a set of transverse structures segmenting the thrust system, and by the deeper ramps of the Apennines thrusts. The new dataset is intended to be included in the next version of the Database of Individual Seismogenic Sources (DISS; http://diss.rm.ingv.it/diss/, version 3.2.0, developed and maintained by INGV) to improve completeness of potential sources for seismic hazard assessment.     

Seismic response of L��Aquila downtown from comparison between 2D synthetics spectral ratios of SH, P-SV and Rayleigh waves and observations of the 2009 earthquake sequence

This is the first part of a study on the seismic response of the L’Aquila city using 2D simulation and experimental data. We have studied two velocity-depth models with the aim of outlining the behavior of a velocity reversal in the top layer, which is associated with the stiff Brecce de L’Aquila unit (BrA). In this setting, the SMTH model is topped by a layer with about 2:1 impedance contrast with the underlying layer while the NORV model has no velocity reversal. We have simulated the propagation of SH and P-SV wavefields in the range 0–10 Hz for incidence 0°–90°. Earthquake spectral ratios of the horizontal and vertical components at six sites in L’Aquila downtown are compared to corresponding synthetics spectral ratios. The vertical component of P-SV synthetics enables us to investigate a remarkable amplification effect seen in the vertical component of the recorded strong motion. Sites AQ04 and AQ05 are best matched by synthetics from the NORV model while FAQ5 and AQ06 have a better match with synthetics spectral ratios from the SMTH model. All simulations show this behavior systematically, with horizontal and near-horizontal incident waves predicting the overall pattern of matches more clearly than vertical and near-vertical incidence. The model inferences are in agreement with new geological data reporting lateral passages in the top layer from the stiff BrA to softer sediments. Matches are good in terms of frequency of the first amplification peak and of spectral amplitude: the horizontal components have spectral ratio peaks predominantly at 0.5 Hz in the simulations and at 0.7 Hz in the data, both with amplitudes of 4, while the vertical component spectral ratios reach values of 6 at frequencies of about 1 Hz in both data and simulations. The vertical component spectral ratios are very well matched using Rayleigh waves with incidence at 90°. The NORV model without the velocity reversal predicts spectral ratio peaks for the horizontal components at frequencies up to 6 Hz. The reversal of velocity acts as a low-pass frequency filter on the horizontal components reducing the amplification effect of the sediment filled valley.