Characteristics of amorphous kerogens fractionated from terrigenous sedimentary rocks

A preliminary attempt to fractionate amorphous kerogens from terrigenous bulk kerogen by a benzene-water two phase partition method under acidic condition was made. Microscopic observation revealed that amorphous kerogens and structured kerogens were fractionated effectively by this method. Characteristics of the amorphous and structured kerogens fractionated by this method were examined by some chemical analyses and compared with those of the bulk kerogen and humic acid isolated from the same rock sample (Haizume Formation, Pleistocene, Japan). The elemental and infrared (IR) analyses showed that the amorphous kerogen fraction had the highest atomic$\text{H}\text{C}$ ratio and the lowest atomic $\text{N}\text{C}$ ratio and was the richest in aliphatic structures and carbonyl and carboxyl functional groups. Quantities of fatty acids from the saponification products of each geopolymer were in agreement with the results of elemental and IR analyses. Distribution of the fatty acids was suggestive that more animal lipids participate in the formation of amorphous kerogens because of the abundance of relatively lower molecular weight fatty acids (such as C₁₆ and C₁₈ acids) in saponification products of amorphous kerogens. On the other hand, although the amorphous kerogen fraction tends to be rich in aliphatic structures compared with bulk kerogen of the same rock samples, van Krevelen plots of elemental compositions of kerogens from the core samples (Nishiyama Oil Field, Tertiary, Japan) reveal that the amorphous kerogen fraction is not necessarily characterized by markedly high atomic $\text{H}\text{C}$ ratio. This was attributed to the oxic environment of deposition and the abundance of biodegraded terrestrial amorphous organic matter in the amorphous kerogen fraction used in this work.     

Oxygen isotopic and chemical zoning of melilite crystals in a type A Ca‐Al‐rich inclusion of Efremovka CV3 chondrite

Abstract– Different oxygen isotopic reservoirs have been recognized in the early solar system. Fluffy type A Ca‐Al‐rich inclusions (CAIs) are believed to be direct condensates from a solar nebular gas, and therefore, have acquired oxygen from the solar nebula. Oxygen isotopic and chemical compositions of melilite crystals in a type A CAI from Efremovka CV3 chondrite were measured to reveal the temporal variation in oxygen isotopic composition of surrounding nebular gas during CAI formation. The CAI is constructed of two domains, each of which has a core‐mantle structure. Reversely zoned melilite crystals were observed in both domains. Melilite crystals in one domain have a homogeneous ¹⁶O‐poor composition on the carbonaceous chondrite anhydrous mineral (CCAM) line of δ¹⁸O = 5–10‰, which suggests that the domain was formed in a ¹⁶O‐poor oxygen isotope reservoir of the solar nebula. In contrast, melilite crystals in the other domain have continuous variations in oxygen isotopic composition from ¹⁶O‐rich (δ¹⁸O = ?40‰) to ¹⁶O‐poor (δ¹⁸O = 0‰) along the CCAM line. The oxygen isotopic composition tends to be more ¹⁶O‐rich toward the domain rim, which suggests that the domain was formed in a variable oxygen isotope reservoir of the solar nebula. Each domain of the type A CAI has grown in distinct oxygen isotope reservoir of the solar nebula. After the domain formation, domains were accumulated together in the solar nebula to form a type A CAI.     

Roles of methane and carbon dioxide in geological processes on Mars

We discuss in this paper possible roles of methane and carbon dioxide in geological processes on Mars. These volatiles in the martian crust may migrate upward from their sources either directly or via various traps (structural, sedimentary, ground ice, gas hydrates). They are then likely emitted to the atmosphere by seepage or through diverse vent structures. Though gas hydrates have never been directly detected on Mars, theoretical studies favor their presence in the crust and polar caps; they could have played an important role as significant gas reservoirs in the subsurface. The martian gas hydrates would possibly be a binary system of methane and carbon dioxide occupying clathrate cavities. Landforms such as mud volcanoes with well-known linkage to gas venting are extensively distributed on Earth, and methane is the primary gas involved. Thus, identification of these landforms on Mars could suggest that methane and possibly carbon dioxide have contributed to geological processes of the planet. For example, we present a newly identified field in Chryse Planitia where features closely resembling terrestrial mud volcanoes occur widely, though with no observable activity. We also present results of a preliminary search for possible recent or present-day, methane-emission zones in the regions over which enrichments of atmospheric methane have been reported.     

Lunar gravity field determination using SELENE same-beam differential VLBI tracking data

A lunar gravity field model up to degree and order 100 in spherical harmonics, named SGM100i, has been determined from SELENE and historical tracking data, with an emphasis on using same-beam S-band differential VLBI data obtained in the SELENE mission between January 2008 and February 2009. Orbit consistency throughout the entire mission period of SELENE as determined from orbit overlaps for the two sub-satellites of SELENE involved in the VLBI tracking improved consistently from several hundreds of metres to several tens of metres by including differential VLBI data. Through orbits that are better determined, the gravity field model is also improved by including these data. Orbit determination performance for the new model shows improvements over earlier 100th degree and order models, especially for edge-on orbits over the deep far side. Lunar Prospector orbit determination shows an improvement of orbit consistency from 1-day predictions for 2-day arcs of 6 m in a total sense, with most improvement in the along and cross-track directions. Data fit for the types and satellites involved is also improved. Formal errors for the lower degrees are smaller, and the new model also shows increased correlations with topography over the far side. The estimated value for the lunar GM for this model equals 4902.80080±0.0009 km³/s² (10 sigma). The lunar degree 2 potential Love number k ₂ was also estimated, and has a value of 0.0255 ± 0.0016 (10 sigma as well).     

Rip current spacing

Mass, momentum and energy conservation laws, including the radiation stress, are used to derive an equation of the eigenvalues of rip current spacing.A coastal region with linear bottom slope is divided into two parts: Offshore region and surfzone separated by the breaker line. Wave set-up, wave energy and mean current are assumed to be composed of basic state, which is a function of the distance from the coast to offshore only, and of superposed two-dimensional perturbations.In the case of normal incidence of waves, basic steady current system vanishes and perturbations are found to be of cellular shape. According to the boundary conditions at the coast, stream function of perturbed motion in the surfzone can be represented by the confluent hypergeometric function, while in the offshore zone it is approximated by the modified Bessel function.Interpolation of the stream functions in the surf and offshore regions enables us to obtain a characteristic relation which gives the eigenvalues of nondimensional alongshore spacing of rip current system as a function of a parameter determined by the bottom friction coefficient, width of the surfzone and breaker height.     

Rain‐induced deep‐seated catastrophic rockslides controlled by a thrust fault and river incision in an accretionary complex in the Shimanto Belt,Japan

To clarify the geological causes of rockslides induced by rainstorms in accretionary complexes, the geology and geomorphology of two large rockslides (volumes > 10⁶ m³) induced by the heavy rainfall of Typhoon Talas in the Shimanto Belt, Kii Mountains, Japan in 2011 are investigated. Our analysis reveals that thrusts with brittle crush zones controlled the occurrence of the rockslides. The properties and distribution of thrusts were poorly constrained before this study. Flooding during the rainstorm removed surface materials along rivers, allowing thorough geological mapping to be performed. Gravitationally deformed slopes were studied using GIS analysis of 1 m digital elevation models (DEMs) and fieldwork, and X‐ray diffraction (XRD) analysis, permeability, and direct shear tests were used to characterize the mineralogy and geotechnical properties of fault gouge. The Kawarabi thrust has a brittle crush zone up to 6 m thick and acts as the sliding surface for both landslides. The thrust dips 34° downslope and is cut by high‐angle faults and joints along one or both sides of each landslide body. Prior to failure, the upper part of the slope contained small scarps, suggesting that the slopes were already gravitationally deformed. The slope instability can be attributed to long‐term river erosion, which has undercut the slope and exposed the thrust at the base of the slope. The groundwater level, monitored in boreholes, suggests that the Kawarabi thrust is a barrier to groundwater flow. The weak and impermeable nature of the thrust played an essential role in the generation of gravitational slope deformation and catastrophic failure during periods of increased rainfall. Thrusts are a common feature of accretionary complexes, including in the Shimanto Belt, and the mechanism of slope failure stated above can be typical of rockslides in accretionary complexes and provide new insights into landslide disaster mitigation.     

Asymptotic giant branch stars in the Phoenix dwarf galaxy

JHK _s near-infrared photometry of stars in the Phoenix dwarf galaxy is presented and discussed. Combining these data with the optical photometry of Massey et al. allows a rather clean separation of field stars from Phoenix members. The discovery of a Mira variable ( P = 425 d), which is almost certainly a carbon star, leads to an estimate of the distance modulus of 23.10 ± 0.18 that is consistent with other estimates and indicates the existence of a significant population of age ∼2 Gyr. The two carbon stars of Da Costa have   M _bol=−3.8  and are consistent with belonging to a population of similar age; some other possible members of such a population are identified. A Da Costa non-carbon star is  Δ K _s∼ 0.3  mag brighter than these two carbon stars. It may be an asymptotic giant branch star of the dominant old population. The nature of other stars lying close to it in the   K _s, ( J − K _s)  diagram needs studying.