Intercolony variability of skeletal oxygen and carbon isotope signatures of cultured Porites corals: Temperature-controlled experiments

The skeletal oxygen isotope ratio of Porites corals is the most frequently used proxy of past seawater temperature and composition for tropical and subtropical oceans. However, field calibration of the proxy signals is often difficult owing to the dual dependence of skeletal oxygen isotope ratio on temperature and the oxygen isotope composition of water. We conducted tank experiments in which we grew Porites spp. colonies for 142 d in thermostated seawater at five temperature settings between 21°C and 29°C under moderate light intensity of 250 μmol m⁻² s⁻¹ with a 12:12 light:dark photoperiod. A skeletal isotope microprofiling technique applied along the major growth axis of each colony revealed that the oxygen isotope ratios of newly deposited skeleton in most colonies remained almost constant during tank incubation, thus providing an ideal situation for precise calibration of oxygen isotope ratio proxy signals. However, the oxygen isotope ratios displayed an unusually large intercolony variability (∼1‰) at each temperature setting although the mean slope (∼0.15‰ °C⁻¹) obtained for the temperature-skeletal oxygen isotope ratio relationship was close to previous results. The intercolony variations in the oxygen isotope ratios were apparently caused by kinetic isotope effects related to variations in the skeletal growth rate rather than by species-specific variability or genetic differences within species. No correlation was found between skeletal carbon isotope ratios and temperature. The carbon isotope ratios showed significantly inverse correlation with linear growth rates, suggesting a kinetic isotope control at low growth rates. Observed intercolony variability in skeletal carbon isotope ratios (∼5‰) can be partly attributed to growth-rate-related kinetic isotope effects.     

Lunar photometric properties at wavelengths 0.5-1.6 μm acquired by SELENE Spectral Profiler and their dependency on local albedo and latitudinal zones

The lunar photometric function, which describes the dependency of the observed radiance on the observation geometry, is used for photometric correction of lunar visible/near-infrared data. A precise photometric correction parameter set is crucial for many applications including mineral identification and reflectance map mosaics. We present, for the first time, spectrally continuous photometric correction parameters for both sides of the Moon for wavelengths in the range 0.5-1.6 μm and solar phase angles between 5° and 85°, derived from Kaguya (SELENE) Spectral Profiler (SP) data. Since the measured radiance also depends on the surface albedo, we developed a statistical method for selecting areas with relatively uniform albedos from a nearly 7000-orbit SP data set. Using the selected data set, we obtained empirical photometric correction parameter sets for three albedo groups (high, medium, and low). We did this because the photometric function depends on the albedo, especially at phase angles below about 20° for which the shadow hiding opposition effect is appreciable. We determined the parameters in 160 bands and discovered a small variation in the opposition effect due to the albedo variation of mafic mineral absorption. The consistency of the photometric correction was checked by comparing observations made at different times of the same area on the lunar surface. Variations in the spectra obtained were lower than 2%, except for the large phase angle data in mare. Lastly, we developed a correction method for low solar elevation data, which is required for high latitude regions. By investigating low solar elevation data, we introduced an additional correction method. We used the new photometric correction to generate a 1° mesh global lunar reflectance map cube in a wavelength range of 0.5-1.6 μm. Surprisingly, these maps reveal that high latitude (?75°) regions in both the north and south have much lower spectral continuum slopes (color ratio r_1547.7nm/r_752.8nm ? 1.8) than the low and medium latitude regions, which implies lower degrees of space weathering.     

Lermontovskoe Tungsten Skarn Deposit: the Oldest Mineralization in the Sikhote-Alin Orogen, Far East Russia

Abstract. Lermontovskoe tungsten skarn deposit in central Sikhote-Alin is concluded to have formed at 132 Ma in the Early Cretaceous, based on K-Ar age data for muscovite concentrates from high-grade scheelite ore and greisenized granite. Late Paleozoic limestone in Jurassic - early Early Cretaceous accretionary complexes was replaced during hydrothermal activity related to the Lermontovskoe granodiorite stock of reduced type. The ores, characterized by Mo-poor scheelite and Fe^3+- poor mineral assemblages, indicate that this deposit is a reduced-type tungsten skarn (Sato, 1980, 1982), in accordance with the reduced nature of the granodiorite stock.
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism.     

Petrographic and mineralogical study of hydrothermal alteration of the Rokko Granite at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line in western Japan

Field, hand specimen, and microscopic investigations alongside X-ray diffraction analyses revealed four types of hydrothermal alteration (Type-A, -B, -C, and -D) based on the mode of occurrence of altered rocks and alteration mineral assemblage at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line (ATTL) in western Japan. Type-A alteration locally occurred as gray alteration halos with sulfide minerals. Type-B and -C alterations were confined to fault gouge veins and occurred as greenish-gray veins and brown veins, respectively. Type-C alteration crosscut Type-B alteration. These alterations were associated with a number of granitic fragments including cohesive breccia and micrographic facies. Type-D alteration occurred locally in brown sediments. Different mineralogical features in the four alterations are summarized as (Type-A) illite; (Type-B) chlorite; (Type-C) limonite (Fe³⁺ hydroxides and goethite) and calcite; and (Type-D) limonite. We propose that the alterations can be broadly divided into Paleocene hydrothermal alteration (Type-A) and post-Late Miocene hydrothermal alteration (Type-B, -C, and -D): Type-A alteration occurred at approximately 200 °C during hydrothermal activity after a granitic intrusion in Late Cretaceous; Type-B, -C and -D alterations occurred under hydrothermal activity accompanying deep fluids with repeated ascents invoked by the seismicity of the ATTL after the Late Miocene. The fluids may have been the “Arima-type thermal waters” (i.e., mixtures of convective groundwater and Na-Ca-Cl-HCO₃-type fluids). Type-B alteration occurred in fractures at depths where the temperature was ≥150 °C. Type-C alteration overprinted Type-B alteration as a result of mixing of new deep fluids and descending oxidized meteoric water near the surface. Fe³⁺ hydroxides and calcite precipitated from the fluids due to the oxidation of Fe²⁺ and the degassing of CO₂, respectively, at ambient to near-boiling temperatures. When the ascending fluids gushed out from the fractures, they generated Type-D alteration at the surface under similar temperature conditions due to the oxidation of Fe²⁺.     

Lithological and physical properties of core samples from the Sagara oil field: Oil occurrence in Sagara core samples

Abstract   A drilling and coring investigation of the Sagara oil field, central Honshu, Japan, was conducted to contribute to the understanding of hydrocarbon migration processes in a forearc basin. Core samples were analyzed to determine lithology, physical properties (specifically gas permeability) and the characteristics of oil occurrence. Gas permeability values greater than approximately 10⁻¹¹ m² constitute the basic precondition for any lithology to serve as a potential fluid conduit or reservoir in the Sagara oil field. Cores recovered from the 200.6-m-deep borehole were primarily composed of alternating siltstone, sandstone and conglomerate, all of which are correlated to the late Miocene Sagara Group. Both sandstone and conglomerate can be classified into two types, carbonate-cemented and poorly to non-cemented, based on matrix material characteristics. Oil stains are generally absent in the former lithology and more common in the latter. Variations in physical properties with respect to gas permeability values are directly related to the presence and character of carbonate cement, with higher permeabilities common in poorly to non-cemented rocks. The relationships between lithology, oil-staining, cementation and permeability indicate that cementation preceded oil infiltration and that cementation processes exerted significant control on the evolution of the reservoir.     

Description and Phylogenetic Position of Dinosaur Eggshells from the Luanchuan Area of Western Henan Province, China

Here, we examine 145 dinosaur eggshells from a new fossil locality in the Qiupa Formation (Upper Cretaceous) of the Luanchuan area in western Henan Province, China. The eggshells display elongatoolithid macro- and microstructures, including ridges and nodes on the outer surface, two ultrastructural layers, and an undulatory boundary between the mammillary and continuous layers. A phylogenic analysis shows that the Luanchuan eggshells belong to the ooclade Elongatoolithidae. Within Elongatoolithidae, the thickness ratio of the mammillary layer to the entire eggshell, and the porosity of the Luanchuan eggshells are comparable to the oogenera Macroolithus and Elongatoolithus. There is no direct evidence for the taxonomic identity of the Luanchuan eggshells; however, they were likely laid by oviraptorids based on their phylogenetic position and their similarities with known oviraptorid eggs.     

Mixing of magmatic CO2 into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.     

Characteristics of canopy interception loss in Moso bamboo forests of Japan

In recent years, Moso bamboo (Phyllostachys pubescens) forests have rapidly expanded in Japan by replacing surrounding coniferous and/or broadleaved forests. To evaluate the change in water yield from forested areas because of this replacement, it is necessary to examine evapotranspiration for Moso bamboo forests. However, canopy interception loss, one of the major components of evapotranspiration in forested areas, has been observed in only two Moso bamboo forests in Japan with relatively high stem density (~7000 stems/ha). There are, in fact, many Moso bamboo forests with much lower stem density. Thus, we made precipitation (Pr), throughfall (Tf) and stemflow (Sf) observations for 1 year in a Moso bamboo forest with stem density of 3611 stems/ha and quantified canopy interception loss (Ic). Pr and Ic for the experimental period were 1636 and 166 mm, respectively, and Ic/Pr was 10%. The value was approximately the same as values for the other two Moso bamboo forests and lower than values for coniferous and broadleaved forests. On the other hand, Tf/Pr and Sf/Pr for our forest (86% and 4%, respectively) were approximately 10% of Pr larger and smaller than values for the other two Moso bamboo forests. These results suggest that the difference in stem density greatly affects precipitation partitioning (i.e. Tf/Pr and Sf/Pr) but does not greatly change Ic/Pr. Copyright © 2012 John Wiley & Sons, Ltd.