Reconstructing historical seismicity from lake sediments (Lake Laffrey, Western Alps, France)

Sediment archives from a mountain lake are used as indicators of seismotectonic activity in the Grenoble area (French western Alps, 45°N). Sedimentological analysis (texture and grain-size characteristics) exhibits several layers resulting from instantaneous deposits in Lake Laffrey: six debris flow events up to 8 cm thick can be attributed to slope failure along the western flank of the basin. Dating with ²¹⁰Pb and ¹³⁷Cs gamma counting techniques and the reconnaissance of historical events, provide a constrained age-depth model. Over the last 250 years, five of such debris flow deposits could be related to historical earthquakes of MSK intensities greater than VI over an area of <60 km. One debris flow deposit triggered at the beginning of the last century can be related to an historical landslide possibly triggered by the artificial regulation of the lake level.     

Iron (III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy

The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions (m_Fe ∼ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH < 2.5), Fe is hexa-coordinated with 6 oxygens of H₂O- and/or OH-groups in the first coordination sphere of the metal, at an Fe-O distance of 2.00 ± 0.01 Å. With increasing pH (2.7 < pH < 13), these groups are rapidly replaced by bridging hydroxyls (-OH-) or oxygens (-O-), and polymerized Fe hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ∼3.47 ± 0.03 Å). The Fe-Fe coordination numbers (N_edge = 1-2; N_corner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3.At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05-m Si solutions (pH ∼ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe_edge ∼ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (∼12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe₂Si_1-2 and Fe₃Si_2-3 at pH < 3; (2) structures composed of Fe-Fe dimers and trimers sharing one or two edges of FeO₆-octahedra; and (3) silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ∼ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ∼20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell (R_Fe-O = 1.84 Å). This new finding implies that Fe may partially substitute for Si in the tetrahedral network of the silica polymers in Si-rich solutions.The results of this study demonstrate that aqueous silica can significantly inhibit iron polymerization and solid-phase formation, and thus increase the stability and mobility of Fe(III) in natural waters. The silica “poisoning” of the free corner sites of iron-hydroxide colloids should reduce the adsorption and incorporation of trace elements by these colloids in Si-rich natural waters.     

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).     

Experimental abiotic alteration of igneous and manufactured glasses

Pits in ocean basalt glass are often attributed to the activity of microorganisms, however, neither the mechanism of formation of pits in glass nor the involvement of microorganisms have been confirmed by experimentation. Experimental abiotic corrosion of basalt glass with 1% hydrofluoric acid (HF), a proxy for more slowly acting organic acids, produces pits that are similar in size, shape, and distribution to pits found in basalt glass collected from the ocean floor and basalt glass incubated with microorganisms. This pit formation by HF etching was demonstrated by comparing secondary electron images taken before and after the acid treatment. The formation of pits by abiotic corrosion of basalt glass is an alternate hypothesis for the origin of these features, and the interpretation of these features as biomarkers may require a resolution of these alternative hypotheses.     

Geochronology of granulites from the south Itabuna-Salvador-Curaçá Block,São Francisco Craton (Brazil): Nd isotopes and U–Pb zircon ages

This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.     

Identification of Gleissberg Cycles and a Rising Trend in a 315-Year-Long Series of Sunspot Numbers

We show in this short note that the method of singular spectrum analysis (SSA) is able to clearly extract a strong, clean, and clear component from the longest available sunspot (International Sunspot Number, ISN) time series (1700?–?2015) that cannot be an artifact of the method and that can be safely identified as the Gleissberg cycle. This is not a small component, as it accounts for 13% of the total variance of the total original signal. Almost three and a half clear Gleissberg cycles are identified in the sunspot number series. Four extended solar minima (XSM) are determined by SSA, the latest around 2000 (Cycle 23/24 minimum). Several authors have argued in favor of a double-peaked structure for the Gleissberg cycle, with one peak between 55 and 59 years and another between 88 and 97 years. We find no evidence of the former: solar activity contains an important component that has undergone clear oscillations of \(\approx90\) years over the past three centuries, with some small but systematic longer-term evolution of “instantaneous” period and amplitude. Half of the variance of solar activity on these time scales can be satisfactorily reproduced as the sum of a monotonous multi-secular increase, a \(\approx90\)-year Gleissberg cycle, and a double-peaked (\(\approx10.0\) and 11.0 years) Schwabe cycle (the sum amounts to 46% of the total variance of the signal). The Gleissberg-cycle component definitely needs to be addressed when attempting to build dynamo models of solar activity. The first SSA component offers evidence of an increasing long-term trend in sunspot numbers, which is compatible with the existence of the modern grand maximum.     

Spatiotemporal changes in cadmium contamination in the Seine estuary (France)

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.     

Early Permian extensional shearing of an Ordovician granite: The Saint-Eutrope “C/S-like” orthogneiss (Montagne Noire,French Massif Central)

Dating the magmatic events in the Montagne Noire gneiss dome is a key point to arbitrate between the different interpretations of the Late Carboniferous–Early Permian tectonics in this southern part of the Variscan belt. The Saint-Eutrope orthogneiss crops out along the northern flank of the dome. We show that the protolith of this orthogneiss is an Ordovician granite dated at 455 ± 2 Ma (LA-ICP-MS U-Pb dating on zircon). This age is identical to that previously obtained on the augen orthogneiss of the southern flank, strongly suggesting that both orthogneiss occurrences have the same Ordovician protolith. The Saint-Eutrope orthogneiss experienced intense shearing along the Espinouse extensional detachment at ca. 295 Ma (LA-ICP-MS U-Pb-Th on monazite), an age close to that determined previously on mica by the ³⁹Ar-⁴⁰Ar method and contemporaneous with the emplacement age of the syntectonic Montalet granite farther to the west. This normal sense shearing reworked previous fabrics related to Variscan thrusting that can be still observed in the augen orthogneiss of the southern flank, and is responsible for the spectacular “C/S-like” pattern of the Saint-Eutrope orthogneiss. This work also shows that care is needed when dealing with C/S-type structures, since they can develop not only in syntectonic intrusions, but also in orthogneisses affected by an intense secondary deformation, at decreasing temperature.     

Intra-oceanic settings of the western Mexico Late Jurassic-Early Cretaceous arc sequences. Implications for the Pacific-Tethys geodynamic relationships during the Cretaceous

Abstract

The Guerrero suspect terrane composed of Late Jurassic-Early Cretaceous sequences, extends from Baja California up to Acapulco and is considered to be coeval with the Late Mesozoic igneous and sedimentary arc sequences of the Greater Antilles, Venezuela and Western Cordillera of Colombia. New geological, petrological and geochemical data from central and southern Mexico, led us to propose a new model for the building of the Alisitos-Teloloapan arc. This arc, partly built on the Pacific oceanic lithosphere and partly on continental fragments, could be related to the subduction of an oceanic basin - the Arperos basin - under the Paleo-Pacific plate. This subduction was dipping southwest.

At the beginning of the magmatic activity of the oceanic segment of this arc, depleted tholeiitic basalts were emitted in a submarine environnement below the CCD. While subduction was going on, the arc magmas evolved from LREE depleted tholeiites to slightly LREE enriched tholeiites and then, to calc-alkaline basalts and andesites enriched in LREE and HFSE. Concurrently, the arc sedimentary environment changed from deep oceanic to neritic with the deposition of Aptian-Albian reefal limestones, at the end of the arc building. In the continent-based segment, the arc magmas are exclusively differentiated calc-alkaline suites depleted in HREE and Y, formed of predominantly siliceous lavas and pyroclastic rocks, emitted in a sub-aerial or shallow marine environment.

Thus, taking into account this above mentioned model, the Cretaceous volcanic series, accreted to the margins of cratonal America, in Colombia, Venezuela, Greater Antilles and Mexico, could be related to the same west-south-west dipping subduction of oceanic basins, fringing the North and South American continental cratons and connected directly with the inter-American Tethys. While the subduction was proceeding, this magmatic arc drifted towards the North and South American cratons and finally, collided with the continental margins at different periods during the Cretaceous.     

Une méthode de quantification de la dégradation d'un escarpement de faille au cours des cycles climatiques du Quaternaire : la faille de Jobourg (Nord Cotentin,France)Quantification of a fault-scarp degradation through Quaternary: the Jobourg fault (North Cotentin,France)

The degradation of the Jobourg fault-scarp occurred by cryoclastic processes in a periglacial environment during a part of Quaternary time. An attempt of quantification indicates a bulk scarp erosion of about 39 m³ m^?2, while the head accumulated at the bottom of the fault scarp only represents 4.6 m³ m^?2. To cite this article: M. Font et al., C. R. Geoscience 334 (2002) 171–178.