Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

The pathway of mercury in contaminated waters determined by association with organic carbon (Tagus Estuary,Portugal)

Reactive dissolved Hg (Hg_R), non-reactive dissolved Hg (Hg_NR), particulate Hg (Hg_P), dissolved organic C (DOC), particulate organic C (POC), salinity and other interpretative parameters were determined in water samples collected in the North Channel and in adjacent areas of the Tagus estuary (Portugal). Higher concentrations of both dissolved and particulate Hg in the North Channel indicate a pollution source and raise the possibility of Hg escaping to adjacent areas by tidal action. This transport was confirmed by the increase of Hg_R with salinity and Hg_NR with DOC, along a longitudinal axis paralleling the North Channel. Apparently, Hg leaving this channel is progressively complexed by inorganic and organic ligands. Near the mouth of the estuary, values decreased reflecting dilution with seawater. Moreover the Hg_P:POC ratio also increased seaward, suggesting mixing with Hg enriched particles that escaped the North Channel, or incorporation of dissolved Hg species in river-derived particles. These results suggest that the pathway of anthropogenic Hg in contaminated waters may be identified by their enrichment in organic matter, both in the dissolved and particulate fraction.     

Different cardiac response to copper in limpets from metal polluted and clean shores of Hong Kong

The gastropod limpet, Cellana grata, is common on moderately exposed to exposed Hong Kong rocky shores. On the basis of the existing literature on trace metal contamination in Hong Kong, four sites were identified, representative of highly polluted (Aberdeen and Lei Yue Mun) and clean (Cape d'Aguilar and Clear Water Bay) conditions. Limpets from the two polluted sites showed similar, but significantly higher body concentrations of copper than limpets from the two clean sites, which were also similar. Non-invasive measurements of cardiac activity of limpets from the four sites showed between site differences in baseline heart rates under standard seawater, irrespective of pollution level. When acutely exposed to water borne copper (2 h, 0.5+/-0.06 SD ppm), however, limpets from clean sites showed a significantly higher increase in inter-beating time (bradycardia) than those from polluted sites. These results highlight the potential use of cardiac activity to assess the exposure of natural populations of limpets to trace metal pollution.     

Evaluation of gas production rates in some comets

Emission fluxes of CN, C₂ and C₃ carbon-bearing molecular species observed in the coma of comets Bennett (1969i 1970II), West (1975n 1976VI), P Halley (1982i), Hartley-Good (19851) and Bradfield (1987s) are analysed in the framework of Haser model. CN, C₂ and C₃ production rates are determined using recently derived fluorescence efficiencies. The dependence of CN, C₂ and C₃ production rates on the heliocentric distance and the possible correlations among these radicals is studied and briefly discussed.     

Gravitational mass of magnetostatic field

Maxwell's displacement current equation is interpreted in the light of recent work to show that static magnetic field in free space should have a colocated and contemporaneous mass that is neither embodied in, nor can be anticipated from, the mass-energy relation. Thus magnetostatic field in the universe represents an invisible mass. Some consequences are discussed.     

A verification of some methods to determine the fluxes of momentum,sensible heat,and water vapour using standard deviation and structure parameter of scalar meteorological quantities

A set of micro-meteorological data collected over a horizontal, uniform terrain (the plain of La Crau, France) in June 1987 is analysed. Conditions were predominantly sunny and arid, while due to the Mistral the wind speed could exceed 10 m/s. Verification of several methods to evaluate surface fluxes of heat, momentum and water vapour from the standard deviation of temperature, wind and specific humidity is presented. Also, a similar approach using the structure parameter of temperature is considered. These methods are all based on Monin-Obukhov (M-O) similarity theory. It is found that the standard deviation of temperature, vertical and horizontal wind speed as well as the structure parameter for temperature behave according to M-O similarity. It is shown that the sensible heat flux and friction velocity can be determined from a fast response thermometer and a cup anemometer. Also, it appears that the analytic solution of the set of governing equations as derived by the first author yields good results. M-O theory does not appear to work for the standard deviation of specific humidity. This may be due to the relative importance of large eddies.     

Regional development in the United States during the 1980s: population redistribution and economic restructuring

The reduction of the rate of growth of the Brazilian population from 3% in the 1960s to 2% by 1993 resulted from a significant reduction of fertility. According to the 1986 national maternal-child health and family planning survey (PNSMIPF) results, 43.3% of women were using some type of contraception: 65.6% of married or cohabiting women. Women relied most on sterilization (17.2%), followed by oral contraceptives (OCs) (17%), the rhythm method (2.8%), the condom (1.1%), and others (5.2%). Only in the south was OC use more prevalent (28.5%) than sterilization (12.2%). The proportion of sterilization reached 27.8% in the north/center-east urban regions. In urban areas sterilization averaged 18.7% vs. 12.7% in rural areas. 26.9% of currently married women in the age range of 15-44 years had been sterilized. A 1990 international estimation indicated that the proportion of sterilization amounted to 36.9% in China, 30.95 in India, 29.7% in Brazil, 47.6% in South Korea, 30.4% in Thailand, and 36.5% in the Dominican Republic. The 1986 PNSMIPF survey also indicated that sterilized women were better informed than other women about contraception. 75% of the former had used OCs, 5% had used the diaphragm, 3% the IUD, 30% the condom, and 35% coitus interruptus at one time or other. The sterilized women had an average of 1.7 more children than those who were using other methods of contraception. 48.6% of women were sterilized before the age of 30, when they had had an average of 3.6 children. 66.6% of the sterilized women who had given birth before the age of 20 had 4 or more live births as compared to 5.9% of sterilized women aged 30 with the same number of children. 47% of women without any schooling were using some kind of contraception vs. 77% of those who had completed secondary school. A multivariate analysis also showed that the age of the mother, the number of live births, the educational status of the mother, and family income were positively correlated with sterilization.     

Protoplanetary core formation by rain-out of minerals

Models of giant gaseous protoplanets calculated by DeCampli and Cameron (1979) indicate that iron and probably other minerals in the interior of a planet would be in the liquid state during part of the protoplanet evolution. Liquid drops in a protoplanet would grow by coalescence much as cloud drops in the Earth's atmosphere grow to rain drops. We have modeled this process by using the stochastic collection equation (Slattery, 1978) for various initial conditions. In all of the cases considered, the growth time (to centimeter-sized droplets) is much shorter than the time, as estimated by detailed evolutionary calculations, that the drops are in the liquid state. Brownian collection is effective in quickly coalescing tiny liquid droplets to an average radius of about 0.005 cm with very few drops remaining with radii less than 0.001 cm. For radii larger than 0.005 cm gravitational collection is dominant. Since the particles are rapidly swept from interstellar grain sizes to much larger sizes, the opacity in the cloud layer is expected to drop sharply following melting of the grains.