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A novel green-emitting phosphor,Eu2+-doped Ca2-x/2 Si1-x Px O4(0.25≤x≤0.30),was prepared through a conventional solidstate reaction.X-ray diffraction(XRD),photoluminescence(PL) and decay studies were employed to characterize the sample,which was assigned to P63mc space group in the hexagonal system.The effect of P-doping on the α-Ca2 SiO4 was studied and P2 O5 broken down by the raw material of(NH4)2 HPO4 played an important role in stabilizing α-Ca2 SiO4 which can only be stable at high temperature.The XRD patterns of the Ca2-x/2 Si1-x Px O4 host were found pure and optimized when the mole fraction of P2 O5 was 14.5%.The diffuse reflectance spectra of the Ca1.855 Si0.71 P0.29 O4 and Ca1.845 Si0.71 P0.29 O4 :0.01Eu2+covered the spectral region of 230-400 nm,implying that the phosphor was suitable for UV or near-UV LED excitation.The phosphor could be effectively excited in the near UV region with the maximum at 372 nm.The emission spectrum of the Ca1.845 Si0.71 P0.29 O4 :0.01Eu2+phosphor showed an asymmetrical single intensive band centered at 513 nm,which corresponded to the 4f65d1→4f7transition of Eu2+.Eu2+ions might occupy two types of Ca2+sites in the Ca1.855 Si0.71 P0.29 O4 lattice and form two corresponding emission centers,which led to the asymmetrical emission of Eu2+in Ca1.855 Si0.71 P0.29 O4.The effects of Eu2+-doped concentration in Ca1.855-x Si0.71 P0.29 O4 :xEu2+on the PL were also discussed,the optimum doping concentration of Eu2+was 1 mol.% and the critical distance of the energy transfer was also calculated by the concentration-quenching method.The non-radiative energy transfer between Eu2+seemed to be caused by the multipole-multipole interaction.The fluorescence lifetime of Eu2+was found to be 0.55711 μs.The results suggested that these phosphors might be promising candidates used for near UV light excited white LEDs. 相似文献
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提出减少时频峰值滤波分段点处阶跃误差的改进方法.经过研究时频峰值滤波在频率调制和时频平面峰值滤波时产生的离散误差以及尺度变换方式,发现分段点处阶跃误差与离散傅里叶变换的长度成反比,且与零点在尺度变换后产生的不确定值有关.提出基于定零点尺度变换的时频峰值滤波,在信号尺度变换时将零点变换到瞬时频率区间上的固定值,使各段时频峰值滤波零点偏移量一致,从而消除分段点处的阶跃误差.仿真实验和实际地震信号时频峰值滤波处理结果表明,改进的时频峰值滤波算法能够有效消减随机噪声,减少分段滤波在分段处的阶跃. 相似文献
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对乌拉特中旗鸟兰地区含石榴石花岗岩进行了同位素地质年代学和岩石地球化学研究,探讨了其形成时代和构造背景.利用锆石SHRIMP U-Pb法测得舍石榴石花岗岩岩体的年龄为(256.4±2.2)Ma,表明其形成于晚二叠世;岩石地球化学特征显示属弱过铝质Ⅰ型花岗岩,物源主要为上陆壳硬砂岩,形成于后碰撞构造环境,源区岩浆部分熔融程度较低,可能是由Ⅰ型花岗质流体与岩浆演化后期热液流体反应而分异结晶形成的.根据含石榴石花岗岩产出的大地构造位置、形成环境及侵位时代,推断研究区内华北板块北缘与西伯利亚板块南缘的碰撞缝合时间上限早于256.4 Ma. 相似文献
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Na-A zeolite was synthesized using oil shale ash (OSA), which is a solid by-product of oil shale proc- essing. The samples were characterized by various techniques, such as scanning electron microscopy, X-ray diffrac- tion and Brunaner Emmet Teller method. The batch isothermal equilibrium adsorption experiments were performed to evaluate the ability of Na-A zeolite for removal of Cu (II) from aqueous solutions. The effects of operating pa- rameters, such as concentration of copper solutions, adsorbent dosages, pH value of solutions and temperature, on the adsorption efficiency were investigated. The equilibrium adsorption data were fitted with Langmuir and Freundlich models. The maximum adsorption capacity of Na-A zeolite obtained from the Langmuir adsorption iso- therm is 156.7 mg.g-t of Cu (lI). The increase of pH level in the adsorption process suggests that the uptake of heavy metals on the zeolite follows an ion exchange mechanism. The batch kinetic data fit the pseudo-second order equation well. The thermodynamic parameters, such as changes in Gibbs free energy (AG), enthalpy (AH) and en- tropy (AS), are used to predict the nature of the adsorption process. The negative AG values at different tempera- tures confirm that the adsorption processes are spontaneous. 相似文献
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