排序方式: 共有15条查询结果,搜索用时 218 毫秒
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以碳糊电极(CPE)为基底,采用电聚合方法制备出聚溴甲酚绿修饰碳糊电极(PBG/CPE),运用循环伏安法(CV)对修饰电极进行表征,通过扫描电子显微镜(SEM)对聚合膜的表面形貌进行观察分析。利用PBG/CPE研究了多巴胺(DA)的电化学行为,并对最佳实验条件进行了探讨。研究结果表明:DA在PBG/CPE上于0.32V和0.24V处分别出现一对可逆氧化还原峰,PBG/CPE对DA有显著的催化作用,该催化过程受吸附控制。DA催化氧化还原峰电流与其浓度在1.0×10-5~2.0×10-4mol/L范围内呈现良好的线性关系,检出限为1.0×10-6mol/L。 相似文献
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Electrical Properties of La-Doped Al2O3 Films on Si (100) Substrates as a High-Dielectric-Constant Gate Material 下载免费PDF全文
Amorphous La-doped Al2O3 (La: Al2O3) thin films are deposited on n-type (100) Si substrates by rf magnetron co-sputterlng. The composition of the deposited films is measured by energy dispersive x-ray spectroscopy: Capacitance-voltage measurement shows that the dielectric constant k of La-doped Al2O3 films ranges from 8.5 to 11.6 with the increasing La content, and the highest k value of 11.6 is obtained for the 20.14% La content film. In the structure of the Al/La:Al2O3/Si metal oxide semiconductor, the dominant conduction stems from the space- charge-limited current at different temperatures. In addition, the wavelength dependence of the transmittance is studied by ultraviolet spectroscopy and the band gap of all the deposited films is above 5.5eV. The results demonstrate that La-doped Al2O3 can meet the requirement of next-generation gate materials. 相似文献
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Three-dimensional SiO2 photonic crystals (PhCs) are fabricated on quartz substrates by the vertical deposition method. Scanning electron microscopy measurement reveals that the samples exhibit an ordered close-packed arrangement of SiO2 spheres. It is found that the position of the [111] photonie band gap (PBG) shifts to a long wavelength (red shift) with increasing sphere size. Gap broadening effects are observed due to the presence of defects in the samples. Moreover, the optical properties of the PBG are very sensitive to the annealing temperature. Our results indicate that the optical properties of the PBG can be easily tuned in the visible region by appropriate experimental parameters, which will be useful for practical applications of PhC optical devices. 相似文献
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ZnO nanospheres are synthesized by a two-step self-assembly method. X-ray diffraction pattern and Raman scattering spectra measurements show that all the samples present a typical wurtzite structure. A regular sphere shape is inspected by field emission scanning electron microscope and transmission electron microscope for the samples. It is shown that the as-synthesized ZnO nanosphere is composed of numbers of primary particles with size of around 1Ohm. A possible growth mechanism for the two-step self-assembly ZnO nanosphere is proposed. After applying the ZnO nanospheres to dye-sensitized solar cells (DSSCs), a 117% increase of the overall light to electricity conversion efficiency η is observed compared with that of the ZnO nanopartieles based DSSCs. Associated with the UV-vis results, light scattering is assigned to the great improvement of η. 相似文献
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在竞争关系的生态模型基础上,通过引入周期性参数形成一个竞争的二维周期系统.对此非自治生态系统,利用比较定理探讨了系统的持续存在性;由Brouwer不动点定理及稳定性理论证明了其周期解的唯一存在性;最后,讨论了相应的最优控制问题,并给出了问题的最优收获策略Eopt(t). 相似文献
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改性纳米TiO2降解水中微量次甲基蓝的动力学研究 总被引:3,自引:0,他引:3
改性纳米TiO2降解水中微量次甲基蓝的动力学研究;光催化氧化;动力学;表观一级反应 相似文献
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在多孔硅衬底上用射频溅射法沉积了非晶的SiC:Tb薄膜. 对样品在N2中进行了不同温度的退火处理. 用傅里叶红外变换谱分析了样品的结构.用荧光光谱仪测试了样品的光致发光,在紫外、可见光区域观测到了强的发光峰.发现随着衬底加热温度和样品退火温度的变化,发光峰有明显的强度变化和微弱的蓝移现象.分析了产生这种现象的机理,得出了紫外区域的发光峰是由于氧缺乏中心引起的,而可见区的发光是由于Tb离子产生的.
关键词:
碳化硅
光致发光
氧缺乏中心
多孔硅 相似文献