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1.
A novel series of temperature‐sensitive poly[(N‐isopropylacrylamide)‐co‐(ethyl methacrylate)] (p(NIPAM‐co‐EMA)) microgels was prepared by the surfactant‐free radical polymerization of N‐isopropylacrylamide (NIPAM) with ethyl methacrylate (EMA). The shape, size dispersity and volume‐phase transition behavior of the microgels were investigated by transmission electron microscopy (TEM), ultraviolet–visible (UV–Vis) spectroscopy, dynamic light scattering (DLS) and differential scanning calorimetry (DSC). The transmission electron micrographs and DLS results showed that microgels with narrow distributions were prepared. It was shown from UV–Vis, DLS and DSC measurements that the volume‐phase transition temperature (VPTT) of the p(NIPAM‐co‐EMA) microgels decreased with increasing incorporation of EMA, but the temperature‐sensitivity was impaired when more EMA was incorporated, causing the volume‐phase transition of the microgels to become more continuous. It is noteworthy that incorporation of moderate amounts of EMA could not only lower the VPTT but also enhance the temperature‐sensitivity of the microgels. The reason for this phenomenon could be attributed to changes in the complicated interactions between the various molecules. Copyright © 2004 Society of Chemical Industry 相似文献
2.
1. Introduction Seismic physical modeling technology is an important method for the research on seismic exploration theory and methods. In seismic physical experiments, the earth, mantle or field site are scaled down to physical models according to the similarity principle, and then the seismic field and its variation are observed in the laboratory for the research work on the theories and methods of the earth structure, earthquake forecasting, energy and mineral resource exploration, and engi… 相似文献
3.
Mou Weimin; Biocca Frank; Owen Charles B.; Tang Arthur; Xiao Fan; Lim Lynette 《Canadian Metallurgical Quarterly》2004,10(4):238
In 3 experiments, the authors investigated spatial updating in augmented reality environments. Participants learned locations of virtual objects on the physical floor. They were turned to appropriate facing directions while blindfolded before making pointing judgments (e.g., "Imagine you are facing X. Point to Y"). Experiments manipulated the angular difference between the learning heading and the imagined heading and between the actual heading and the imagined heading. The effect of actual-imagined on pointing latency was observed for naive users but not for users with brief training or instructions concerning the fact that objects can move with body movements. The results indicated that naive users used an environment-stabilized reference frame to access information arrays, but with experience and instruction the nature of the representation changed from an environment stabilized to a body stabilized reference frame. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
4.
The public information signs ( The term public information signs will be abbreviated to public signs in the following text.)in the urban areas not only offer convenience for people to move around, but also reflect the level of development and progress of those areas. It is essential to the creative development and uplifting of the New Costal Area (thereafter, NCA) to have a good understanding of its present situation with regard to its public signs, to discuss the related issues in the development, to work out a system that is up to international standard and develop its own standards in the course of implementing the national strategies on standardizing public signs. 相似文献
5.
沉积环境与多元统计综合分析法 总被引:1,自引:0,他引:1
本文首先根据地震资料提取了十二种地震参数,然后通过对LH油田TZ地区沙三上段下部地层进行沉积环境分析,确定了可能存在的沉积相类型,并用有序样品聚类的方法对过井和井旁地震测线按沉积相个数进行分割,由此而建立了该区各类沉积相的判别函数。通过这些判别函数,用逐步判别分析的方法,对该区其它地震测线的参数进行判别分类,最后搞清了研究区目的层的沉积相展布。通过分析和计算证明,这一方法对有地震资料的盆地或地区进行沉积相的划分,是行之有效的 相似文献
6.
本文阐述了氧化锆增韧陶瓷(ZTC)的相变增韧机理,并探讨了热处理工艺对ZTC的相变及显微组织的影响规律。 相似文献
7.
本文研究了浸胶工艺对Nomex蜂窝性能的影响,分析探讨了提高Nomex蜂窝性能及外观质量的途径。研究结果表明:采取新的浸胶工艺制作的Nomex蜂窝,各项性能全面达到法国宇航材料标准。 相似文献
8.
Jihao Wang Yufen Han Zhiyang Xu Xiaozhen Yang Seeram Ramakrishna Yong Liu 《大分子材料与工程》2021,306(4):2000724
Polymer systems have typical multiscale characteristics, both in space and time. The mesoscopic properties of polymers are difficult to describe through traditional experimental approaches. Dissipative particle dynamics (DPD) is a simulation method used for solving mesoscale problems of complex fluids and soft matter. The mesoscopic properties of polymer systems, such as conformation, dynamics, and transport properties, have been studied extensively using DPD. This paper briefly summarizes the application of DPD to research involving microchannel flow, electrospinning, free-radical polymerization, polymer self-assembly processes, polymer electrolyte fuel cells, and biomedical materials. The main features and possible development avenues of DPD are described as well. 相似文献
9.
10.
Xiaozhen Yang 《Polymer》2004,45(12):4241-4248
The conformational distribution change of amorphous poly(lactic acid) (PLA) induced by deformation has been studied using Raman spectroscopy. Spectroscopic features associated with the rotational isomeric states (ttt, ttg′, tg′t, tg′g′) have been established experimentally and supported by normal coordinate analysis. Deformation induced a significant increase in the most favorable tg′t conformation. Based on the relative intensities of Raman-active skeletal modes, a quantitative method has been developed that can be used to elucidate structural changes in a variety of deformed polymer samples. For biaxially oriented PLA films, the overall tg′t conformation increased from the 76% in undeformed sample to a value as high as 92%. The change in conformational distribution in the amorphous phase follows a different trend (76-88%) as compared to the increase in sample crystallinity (0-43%). A large change in amorphous chain conformation occurred at relatively low draw ratios. In contrast, the large change in the degree of crystallinity occurred at higher draw ratios. 相似文献