全文获取类型
收费全文 | 7289篇 |
免费 | 477篇 |
国内免费 | 3篇 |
学科分类
工业技术 | 7769篇 |
出版年
2024年 | 17篇 |
2023年 | 80篇 |
2022年 | 110篇 |
2021年 | 232篇 |
2020年 | 196篇 |
2019年 | 214篇 |
2018年 | 318篇 |
2017年 | 347篇 |
2016年 | 327篇 |
2015年 | 240篇 |
2014年 | 322篇 |
2013年 | 707篇 |
2012年 | 471篇 |
2011年 | 522篇 |
2010年 | 405篇 |
2009年 | 380篇 |
2008年 | 390篇 |
2007年 | 368篇 |
2006年 | 311篇 |
2005年 | 177篇 |
2004年 | 167篇 |
2003年 | 174篇 |
2002年 | 158篇 |
2001年 | 133篇 |
2000年 | 112篇 |
1999年 | 96篇 |
1998年 | 165篇 |
1997年 | 104篇 |
1996年 | 91篇 |
1995年 | 79篇 |
1994年 | 54篇 |
1993年 | 39篇 |
1992年 | 30篇 |
1991年 | 20篇 |
1990年 | 18篇 |
1989年 | 16篇 |
1988年 | 19篇 |
1987年 | 7篇 |
1986年 | 13篇 |
1985年 | 18篇 |
1984年 | 22篇 |
1983年 | 23篇 |
1982年 | 15篇 |
1981年 | 8篇 |
1980年 | 10篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1973年 | 4篇 |
排序方式: 共有7769条查询结果,搜索用时 0 毫秒
1.
Glass columns (length 50 cm, i.d. 4 cm) containing 900 g of uranium ore waste were subjected to a three-step process: (1) acid drainage generation, (2) neutralization and precipitation treatment and, again, (3) acid drainage generation. In the first acid generation step, lasting about one year, different variables (pyrite addition, inoculation and irrigation solution) were tested by measuring effluent pH, redox potential, total iron and sulphate. Conditions of acid generation were satisfactorily reproduced, reaching stable pH values around 2.0 that were determined mainly by pyrite addition and the type of irrigation solution used (distilled water or ferrous sulphate). The neutralization and precipitation treatment consisted of alternating irrigations of a neutralizing solution (CaO saturated plus NaOH) and a precipitating solution (ferric sulphate saturated). This treatment caused accumulation of basic iron sulphate and iron oxide precipitates according to SEM studies. After this treatment, the barrier effect created by the reaction products was checked, using irrigation solutions similar to the first step. The effluents collected showed higher pH and lower redox potential, total iron and sulphate values than those observed before the treatment, evidencing inhibition of acid drainage generation. 相似文献
2.
3.
Here we are presenting the case of a 70-years-old woman who has hepatic cirrhosis anti-HCV and insulin-dependent diabetes mellitus, without relevant epidemiologic ascendants or previous transfusions and HBV, HIV negatives. On admission to our hospital she showed signs of autoimmune hemolytic anaemia (AHA) which was confirmed by positive direct Coombs test and an improvement in blood test after corticoid treatment. Having discarded other possible causes such as drugs infectious diseases or essential mixed cryoglobulinemia (CME), we put forward the possible association between AHA and infection by HCV, where AHA was an extrahepatic immunological manifestation of HCV. This fact has never been brought to light in previous medical literature. 相似文献
4.
RM Martín‐Aranda E Ortega‐Cantero ML Rojas‐Cervantes MA Vicente‐Rodríguez MA Baares‐Muoz 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(2):234-238
α,β‐Unsaturated nitriles have been synthesized by Knoevenagel condensation of a carbonylic compound with malononitrile, assisted by sonochemical irradiation. Two alkaline‐promoted clays (Li+‐ and Cs+‐exchanged saponites) have been employed as catalysts. The influence of the carbonylic compound (benzaldehyde or cyclohexanone) and the use of a solvent on the catalytic activity have been studied. Remarkable increase in the conversion values has been found when the reaction is activated by ultrasound, as compared with the thermal activation. In this green, solvent‐free procedure, α,β‐unsaturated nitriles have been produced in very high yields (97%) when the Cs+‐saponite is used as catalyst. Copyright © 2004 Society of Chemical Industry 相似文献
5.
An evaluation of the Spanish CSIC performance in Biotechnology, as compared with those of the French CNRS and the Italian
CNR, has been carried out to determine the balance between the generation of scientific knowledge and the transfer of technology.
This study shows a high scientific productivity mostly in journals with moderate impact factor, a low generation of patents
and an insufficient transfer of knowledge to the Spanish companies. Other indicators confirm the existence of competitive
human resources in biotechnological research producing scientific knowledge of interest for the development of patents and
that cooperates successfully at European level. 相似文献
6.
7.
The effects of cooking temperature, time and temperature of brine-salting, and temperature of ripening on the behavior of Enterobacteriaceae in Manchego cheese were studied. Fifty lots of cheese from raw ewe's milk manufactured and ripened under different conditions were investigated throughout a 60-day ripening period. Differences in pH values due to temperature-dependent whey retention accounted for the effect of cooking temperature on coliform and fecal coliform counts. Temperature of brine-salting had no effect on Enterobacteriaceae counts, but a significant effect of salting time on Enterobacteriaceae and fecal coliform counts was detected. Ripening temperature was the manufacturing variable with greatest influence (P<.01) on Enterobacteriaceae and coliform counts during the whole curing period. 相似文献
8.
A method based on cluster analysis techniques is proposed in order to obtain representative local wind patterns. Modeling renewable energy systems, in an accurate way which strongly depends on wind loads, requires reliable data to analyze their response and evaluate their performance. Otherwise poor agreement with the models may be obtained. In a case study for La Paz, Baja California Sur, Mexico, four different wind patterns were obtained from a one-year data set recorded at 10-min intervals. 相似文献
9.
Jos A.D. Muoz Antn Alvarez Jorge Ancheyta Miguel A. Rodríguez Gustavo Marroquín 《Catalysis Today》2005,109(1-4):214-218
The present paper focuses on the study of process alternatives for heat integration of a heavy crude oil hydrotreatment plant. Experimental information obtained from a pilot scale, kinetics and reactor modeling tools, and a commercial process simulator were employed to develop mass and energy balances. Four study cases, which employ a combination of quenching and heat exchangers, were identified and evaluated. The results indicated that the case with two quenches with hydrogen and three heat exchangers is the best process heat integration (PHI) option from an energetic point of view. 相似文献
10.
Preparation and characterisation of vanadium catalysts supported over alumina-pillared clays 总被引:1,自引:0,他引:1
M. A. Vicente C. Belver R. Trujillano M. A. Baares-Muoz V. Rives S. A. Korili A. Gil L. M. Gandía J. -F. Lambert 《Catalysis Today》2003,78(1-4):181-190
Supported vanadium-containing catalysts were prepared by impregnation of Al-pillared clays with NaVO3 precursor aqueous solutions. A montmorillonite and a saponite, both natural as well as previously pillared with Al13-Keggin polycations, were used as supports, being impregnated with solutions of the precursor by means of the incipient wetness technique. The layered structure of the supports is maintained after impregnation, and even after calcination of the impregnated solids at 500 °C, although with a significant worsening of the textural properties of the solids, in particular, a loss of specific surface area. Three crystalline vanadium-containing phases were identified in the impregnated solids, namely, NaV3O8, AlVO4 and V2O5 (shcherbinaite). The reduction of these phases to V3+ species was observed as wide processes in the 450–750 °C range, all of them centred at ca. 600 °C. 相似文献