铸造Al-Cu合金凝固参数与枝晶间距的关系

本文介绍了用自行设计的铝合金凝固参数测试装置,研究了铸造铝铜合金凝固参数和铸件的宏观晶粒组织、枝晶结构、化学成分不均匀性的关系。根据实验结果,建立了一次枝晶间距和二次枝晶间距和冷却速度的数学表达式:d_1=135.8V~-0.59,d_2=169.5V~-0.379。     

Ti_3Al基金属间化合物的研究进展

对Ti3 Al基金属间化合物的研究情况及其合金组织、力学性能、影响因素作了概述 ,并重点介绍了其熔炼技术和铸造特性。最后 ,展望Ti3 Al基金属间化合物在航空航天领域的发展前景     

Ti-47Al-1.2Ce合金显微组织及富稀土相的形貌

采用水冷铜坩埚真空感应熔炼炉制备了Ti-47Al-1.2Ce合金.通过XRD,SEM,EMPA和TEM等测试方法,研究了Ce对TiAl基合金显微组织的影响以及富稀土相的形貌.实验结果表明,铸态Ti-47Al-1.2Ce合金由等轴晶组成,富稀土相主要以椭球形存在于晶内和以网状存在于晶界;稀土元素的加入,可以减小TiAl相的单胞体积,细化合金晶粒尺寸和层片间距.     

Ti-22Al-25Nb合金ISM熔炼过程中的成分控制

采用X荧光光谱(XRF)分析水冷铜坩埚真空感应炉熔炼(ISM)加入和不加入稀土Y的Ti-22Al-25Nb合金铸锭成分,分析结果表明,在保证获得成分均匀的合金铸锭的情况下,Al的挥发烧损在28.94%～33.88%之间;加入at为0.5%～1%Y,Y的挥发烧损在w为17.20%～34.26%;采取提高熔化温度降低保温时间的措施可以降低Al的挥发烧损.     

Recent developments in engineering γ—TiAl intermetallics

γ-TiAl based alloys are rapidly being developed for elevated temperature applications,due to their high strength,light mass and good oxidation resistance.However,th disadvantages of TiAl based alloys are low ductility and toughness at room temperature,and poor workability.Grain refinement is one of the most effective ways for improving room temperature tensile properties and hot workability of ordered TiAl based alloys.At present,the majority of research works have focused on alloy modifications through compositional controls,alloying additions,thermo-mechanical processing and production techniques.This article discusses the research status of TiAl based alloys in the aras of microstructure,alloying,processing and applications.     

小龙虾肉脯的工艺优化

本文以质构、色差、感官评分为指标,研究糖盐比、TG酶添加量、烤制温度、烤制时间对小龙虾肉脯品质的影响。在此基础上,以感官评分和硬度为响应值,采用响应面设计优化工艺条件,得到的最佳工艺参数为：100 g小龙虾肉,糖盐比7.5∶2.5（10.0 g）、TG酶添加量2.00 U/g、烤制温度145℃、烤制时间9 min,此工艺加工而成的小龙虾肉脯产品片形整齐,厚薄均匀,色泽淡红清亮,咸甜适宜,有较好的弹性,硬度、咀嚼性适中,感官评分为89.00分,硬度为540.45 N,试验结果值与理论预测值误差分别是0.84%、0.46%,模型拟合度好,试验结果可靠。     

氢对锆基块体非晶合金热膨胀系数和有效原子作用势的影响

利用电弧熔炼及铜模快速铸造的方法制备Zr41.2Ti13.8Cu12.5Ni10Be22.5块状非晶合金,通过电化学方法向块状非晶中充入氢,结果表明,氢提高玻璃转变温度下的线膨胀系数,降低晶化开始温度处的线膨胀系数,延缓玻璃转变前结构弛豫现象的发生,另外,充氢能够增加块体非晶合金材料的原子平均最近邻距离和有效作用势深度。     

新型牙科铸钛专用包埋料的研制

研究了自制磷酸盐包埋料焙烧温度与膨胀率及膨胀系数之间,焙烧温度、固化时间与抗拉强度之间的关系,以及室温条件下一次包埋时包埋料与纯钛的界面反应情况.结果表明:包埋料的最大凝固膨胀率为0.1%,800℃的热膨胀率为0.46%,总膨胀率为0.56%,完全可以满足实际义齿铸造的要求.焙烧后抗拉强度在0.3～0.35MPa之间,正常固化24h后,包埋料的抗拉强度为2.35MPa,已经能够满足铸造过程的需要.Zr、P元素在纯钛中的扩散很小,可以忽略不计.金属元素Mg的扩散深度约为6μm,Al的扩散深度约为20μm,Si的扩散深度约为15μm,可以通过表面处理来保证铸件质量.     

Effects of minor yttrium addition on hot deformability of lamellar Ti-45Al-SNb alloy

The effects of 0.3%（molar fraction, the same below） yttrium addition on hot deformability of lamellar Ti-45Al-5Nb alloy were investigated by simulated isothermal forging tests. The ingots with the nominal compositions of Ti-45Al-5Nb and Ti-45Al-5Nb-0.3Y were prepared by induction skull melting. Simulated isothermal forging tests were conducted on Gleeble 1500D thermo-simulation machine using a 6 mm in diameter and 10 mm in length compressive specimen at the deformation temperatures of 1 100, 1 150, 1 200 ℃ and strain rates of 1.0, 0.1, 0.01 s^-1. The results show that yttrium addition remarkably improves hot deformability of Ti-45Al-5Nb alloy. An appropriate hot deformation processing parameter of Ti-45Al-5Nb-0.3Y alloy is determined as 1 200 ℃, 0.01 s^-1. The flow stresses are decreased by yttrium addition under the same compressive conditions. The activation energies of deformation Q are calculated as 448.6 and 399.5 kJ/mol for Y-free and Y-containing alloys, respectively. The deformed microstructure observation under 1 200 ℃, 0.01 s^-1 condition indicates that Ti-45Al-5Nb-0.3Y alloy shows more dynamic recrystallization. The improvement of hot deformability of Ti-45Al-5Nb-0.3Y alloy induced by yttrium addition should be attributed to that the smaller the original lamellar colonies, the lower the deformation resistance and activation energy of deformation are, and the more the dynamic recrystallization is.     

高温钛合金及TiAl金属间化合物的精密铸造技术及应用前景

本文对高温钛合金及TiAl金属间化合物的发展趋势进行了概述,介绍了钛合金及TiAl金属间化合物水冷铜坩埚真空感应熔炼(ISM)熔模精密铸造技术的研究现状.最后,介绍了高温钛合金及TiAl金属间化合物在航空航天领域与民用领域中的应用和发展前景.