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1.
Rapid pyrolysis was conducted in a drop tube reactor using seven coals under various operating conditions. In addition to dense char, porous chars (network char and cenospheric char) were formed by the rapid pyrolysis under certain conditions. Porous char was mainly composed of film-like carbon and skeleton carbon. The pyrolyzed coal char particles were characterized in detail. Morphology and bulk density of porous char were quite different from the dense char formed under the same conditions, but elemental composition and BET surface area were similar to each other. CO2 gasification reactivity of porous char was lower than dense char in the later gasification stage, and this was ascribed to the low reactivity of skeleton carbon. 相似文献
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Rajender Singh Malik Sandeep Nath Tripathi Deeksha Gupta Veena Choudhary 《International Journal of Hydrogen Energy》2014
Novel composite membranes were prepared using imidazolium type aprotic ionic liquids and sulfonated poly (ether ketone) (SPEK) as polymer matrix by solution casting process. All the prepared membranes were characterized for their thermal stability, mechanical properties, ion exchange capacity, proton conductivity and leaching out of ionic liquids in presence of water. Ionic liquid based membranes were more flexible than neat SPEK membrane due to the plasticization effect of ionic liquids. The interactions and compatibility occurring among components were investigated by vibration spectroscopy (FTIR ATR) and scanning electron microscopy respectively. The thermal stability of composite membranes was higher than unmodified membranes. The ion conductivity of composite membranes under anhydrous conditions was found to be dependent on temperature, type and concentration of ionic liquid in SPEK matrix. Ion conductivities of composite membranes under anhydrous condition were found to be up to two orders (∼100 times) higher than neat SPEK membrane and it was found to be ∼5 mS/cm at 140 °C for SPEK/OTf-70. These composite membranes can be successfully operated at temperatures ranging from 40 °C to 140 °C under anhydrous conditions. 相似文献
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Kothaplamoottil Sivan Saranya Padinjareveetil Akshay K.K. Padil Vinod V. T. Pilankatta Rajendra George Bini Senan Chandra Černík Miroslav Varma Rajender S. 《Clean Technologies and Environmental Policy》2019,21(8):1549-1561
Clean Technologies and Environmental Policy - An economical and easy one-step method for the biosynthesis of highly stable molybdenum trioxide (MoO3) nanoparticles was developed using gum arabic as... 相似文献
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Rajender Prasad Tiwari Syed Zimad Husain Hashmi Raghav Sharma Saif Ahmad Khan Balaji Birajdar 《Journal of the American Ceramic Society》2019,102(8):4659-4669
Residual NiO phase is generally detected in 0.9(KNbO3)–0.1(BaNi1/2Nb1/2O3-δ) (KBNNO) synthesized using NiO as a nickel precursor by solid-state reaction. In this work, NiO phase is found to exist in the form of the residual NiO particles with a size of 100-200 nm using energy dispersive X-ray elemental mapping. These NiO residual particles are eliminated by using nickel acetate as a nickel precursor and a 100% perovskite phase KBNNO is successfully synthesized at as low as 600°C temperature. Furthermore, using the two-step sintering technique, 100% relative density is achieved in this material. The nickel acetate–based KBNNO shows a robust ferromagnetism with the saturation magnetization of 11.42 memu/g and the remanent magnetization of 3.89 memu/g which is 38 times higher than that of previously reported value in NiO-based KBNNO. Thus, a highly pure and fully dense KBNNO ceramic with superior magnetic properties is obtained using nickel acetate and by the two-step sintering method. This is a key step forward in the processing of KBNNO and is likely to have a significant impact on other physical properties of this newly invented and promising photovoltaic perovskite material. 相似文献
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Nasrollahzadeh Mahmoud Shafiei Nasrin Eslamipanah Mahtab Fakhri Parisa Jaleh Babak Orooji Yasin Varma Rajender S. 《Clean Technologies and Environmental Policy》2020,22(8):1715-1724
Clean Technologies and Environmental Policy - This work reports the fabrication of Au nanoparticles (NPs) by laser ablation of a gold metal plate immersed in water in the absence of stabilizing... 相似文献
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Jaleh Babak Gandomi Rouzbahani Mastaneh Abedi Kamaladdin Azizian Saeid Ebrahimi Hossein Nasrollahzadeh Mahmoud Varma Rajender S. 《Clean Technologies and Environmental Policy》2019,21(6):1259-1268
Clean Technologies and Environmental Policy - In this study, TiO2 nanoparticles (NPs)-based catalysts were prepared for the photocatalytic removal of toluene as a model VOC from air under UV light.... 相似文献
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Nasri Atefeh Nezafat Zahra Jaleh Babak Orooji Yasin Varma Rajender S. 《Clean Technologies and Environmental Policy》2021,23(6):1797-1806
Clean Technologies and Environmental Policy - Assorted common contaminants namely organic dyes and nitro compounds are generated by various industries and have caused alarming problems for the... 相似文献
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Hendrix JA Shimshock SJ Shutske GM Tomer JD Kapples KJ Palermo MG Corbett TJ Vargas HM Kafka S Brooks KM Laws-Ricker L Lee DK de Lannoy I Bordeleau M Rizkalla G Owolabi J Kamboj RK 《Chembiochem : a European journal of chemical biology》2002,3(10):999-1009
A new class of potent dopamine D(4) antagonists was discovered with selectivity over dopamine D(2) and the alpha-1 adrenoceptor. The lead compound was discovered by screening our compound collection. The structure-activity relationships of substituted isoindoline rings and the chirality about the hydroxymethyl side chain were explored. The isoindoline analogues showed modest differences in potency and selectivity. The S enantiomer proved to be the more potent enantiomer at the D(4) receptor. Several analogues with greater than 100-fold selectivity for D(4) over D(2) and the alpha-1 adrenoreceptor were discovered. Several selective analogues were active in vivo upon oral or intraperitoneal administration. A chiral synthesis starting from either D- or L-O-benzylserine is also described. 相似文献
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Arvind?KumarEmail author K.?K.?Sharma Rajender?Kumar Subhash?Chand Ashwani?Kumar 《Journal of Electronic Materials》2017,46(11):6422-6429
We have investigated the structural and electrical characteristics of the Ag/n-TiO2/p-Si/Al heterostructure. Thin films of pure TiO2 were deposited on p-type silicon (100) by optimized pulsed laser ablation with a KrF-excimer laser in an oxygen-controlled environment. X-ray diffraction analysis showed the formation of crystalline TiO2 film having a tetragonal texture with a strong (210) plane as the preferred direction. High purity aluminium and silver metals were deposited to obtain ohmic contacts on p-Si and n-TiO2, respectively. The current–voltage (I–V) characteristics of the fabricated heterostructure were studied by using thermionic emission diffusion mechanism over the temperature range of 80–300 K. Parameters such as barrier height and ideality factor were derived from the measured I–V data of the heterostructure. The detailed analysis of I–V measurements revealed good rectifying behavior in the inhomogeneous Ag/n-TiO2/p-Si(100)/Al heterostructure. The variations of barrier height and ideality factor with temperature and the non-linearity of the activation energy plot confirmed that barrier heights at the interface follow Gaussian distributions. The value of Richardson’s constant was found to be 6.73 × 105 Am?2 K?2, which is of the order of the theoretical value 3.2 × 105 Am?2 K?2. The capacitance–voltage (C–V) measurements of the heterostructure were investigated as a function of temperature. The frequency dependence (Mott–Schottky plot) of the C–V characteristics was also studied. These measurements indicate the occurrence of a built-in barrier and impurity concentration in TiO2 film. The optical studies were also performed using a UV–Vis spectrophotometer. The optical band gap energy of TiO2 films was found to be 3.60 eV. 相似文献