Polarization imaging for 3D inspection of highly reflective metallic objects

In the field of industrial vision, the 3D inspection of highly reflective metallic objects is still a delicate task. The specular reflections prevent the use of a 3D laser scanner, whereas the phase shifting-based 3D systems are more adapted to inspect surfaces with low curvature. This paper deals with a new automated 3D inspection system based on polarization analysis. Studying the state of polarization of the reflected light is very useful for obtaining information on the normals of the surface. An extension of the shape from polarization method from dielectric to metallic surfaces is demonstrated. Then, an improved relaxation algorithm is provided in order to reconstruct the shape from the normal field given by the polarization analysis. Finally, applications to shape defect detection are discussed and the efficiency of the system in discriminating defects on highly reflective metallic objects made by stamping and polishing is presented. The text was submitted by the authors in English.     

Effect of structure on glass transition temperature of amine crosslinked epoxies

About 40 epoxide-amine network polymers with glass transition temperatures ranging from 0 to 232°C were investigated, about one-third being reported for the first time. The glass transition temperature T_gl of the corresponding linear copolymers was first calculated by use of an additivity law whose physical validity was carefully checked. Then the contribution of crosslink mers was determined, and various physical and empirical approaches of the effect of crosslinking on T_g were compared. The results gave evidence in favor of the DiMarzio approach. A predictive relationship based on these considerations is proposed.     

Courants caractéristiques et analyse de SEREigen currents and RCS analysis

In this Note, we return to the theory of characteristic modes which was introduced 30 years ago for electromagnetic scattering problems. A simple mathematical framework is proposed and complete definitions are given. The potential interest of this theory in terms of Radar Cross Section (RCS) analysis is then discussed, especially in the low frequency case. Finally, a 3-D example is presented to illustrate the efficiency of this decomposition. To cite this article: Y. Morel et al., C. R. Mecanique 332 (2004).     

An investigation of the 2D attractive Hubbard model

We present an investigation of the 2D attractive Hubbard model, considered as an effective model relevant to superconductivity in strongly interacting electron systems. We use both hybrid Monte-Carlo simulations and existing hopping parameter expansions to explore the low temperature domain. The increase of the static S-wave pair correlation with decreasing temperature, which depends weakly on the band filling in the explored temperature range, is analyzed in terms of an expected Kosterlitz-Thouless superconducting transition. Using both our data and previously published results, we show that the evidence for this transition is weak: If it exists, its temperature is very low. The number of unpaired electrons remains nearly constant with temperature at fixed attractive potential strength. In contrast, the static magnetic susceptibility decreases fast with temperature, and cannot be related only to pair formation. We introduce a method by which the Padé approximants of the existing series for the susceptibility give sensible results down to rather low temperature region, as shown by comparison with our numerical data. Received: 30 October 1996 / Revised: 23 October 1997 / Accepted: 29 January 1998     

Irreversible and reversible phase transitions of alkyl monolayers. Gas chromatographic evidence of polar solvent influence on the adsorbing properties of the layer

Summary Further to Gilpin's observations in liquid chromatography of the irreversible transformation of alkyl grafts, following the replacement of an organic mobile phase by an aqueous one, we describe some gas chromatographic experiments which lead to similar (log V_s, I/T) plots, as a consequence of the same solvent release process.We use paraffin films on siliceous supports or hydroxylated liquid substrates or C₂₂-alkyl bonded silica. These experiments demonstrate that this irreversible transition and the melting-like reversible transition are completely different phenomena. They confirm the existence of at least three kinds of monomeric alkyl films.     

Pd-H from Pd/C and triethylamine: Implications in palladium catalysed reactions involving amines

The palladium hydride-iminium complex generated from Pd/C and triethylamine catalyses the isomerisation of allylic alcohols into carbonyl compounds, and Pd/C catalyses the conjugate reduction of activated double bonds using triethylamine as the source of the two newly incorporated hydrogen atoms via the same complex.     

Reductive complexation of cycloheptatrienes by iron pentacarbonyl and catalytic sodium borohydride

Fe(CO)5 and a catalytic amount of sodium borohydride react with cycloheptatrienes in protic solvents to yield the corresponding tricarbonyl(eta 4-1,3-diene)iron complexes in a one-pot procedure, which has been found to be particularly efficient for the synthesis of the useful tricarbonyl(cyclo-heptadiene)iron complex.     

Interfacial tension and fluorine evolution on a carbon anode

During electrolysis of molten KF-2HF, strongly adherent fluorine bubbles are generated at the surface of carbon anode. The current was passing even if the horizontal anode was fully covered with gas film. The formation and growth of gas bubbles were studied by transient electrochemical techniques. It was observed that the fluorine bubbles do not have the spherical cap shape predicted by the classical theory. The curvature radius of the interface profile is not constant, the edge of the bubble being flat with a contact angle close to zero. The results are interpreted in the frame of a model which takes into account the predominant role of the interfacial properties.     

Role of elemental fluorine in nuclear field

The preparation of fluorine gas by Henri Moissan by electrolysis of molten fluorides can be considered as one of the most important discoveries during the last centuries. Indeed, in addition to its use in many industrial fields (microelectronic, surface cleaning, pharmacology, medicine, …), fluorine gas is strongly involved in nuclear field for the preparation of UF₆. The latter allows the natural uranium enrichment via the gaseous diffusion process. Due to the increase of the energy demand in industrialised and emergent countries, the production of UF₆ and consequently of F₂ should increase drastically during the next decades. The aim of this paper is to summarise the evolution of the process to produce fluorine from its discovery to the present process. Few aspects on the researches done for a better understanding of the fluorine evolution reaction are presented. The use of fluorine in the nuclear field is also discussed.