希土胺羧酸配合物的研究——Ⅲ.吡啶-2,6-二甲酸钕配合物{[Nd(HDPA)(DPA)(H2O)2]·4H2O}n合成及其晶体结构

关于吡啶-2,6-二甲酸希土配合物晶体结构有Na₃[Ln(DPA)₃]·yNaClO₄·xH₂O类型的报道^[1]。本文合成了{[Nd(HDPA)(DPA)(H₂O)₂]·4H₂O}_n。配合物单晶并测定了其结构。     

Adaptive dynamic surface neural network control for nonstrict-feedback uncertain nonlinear systems with constraints

This paper presents an adaptive dynamic surface neural network control for a class of nonstrict-feedback uncertain nonlinear systems subjected to input saturation, dead zone and output constraint. The problem of input saturation is solved by designing an anti-windup compensator, and the issue of output constraint is addressed by introducing tan-type Barrier Lyapunov function. Furthermore, based on adaptive backstepping technique, a series of novel stabilizing functions are derived. First-order sliding mode differentiator is introduced into backstepping design to obtain the first-order derivative of virtual control. The real control input is obtained using dead-zone inverse method. It is proved that the proposed control scheme can achieve finite time convergence of the output tracking error into a small neighbor of the origin and guarantee all the closed-loop signals are bounded. Simulation results demonstrate the effectiveness of the proposed control scheme.     

新型结构超宽带LiNbO3电光调制器的优化设计

采用有限元软件对新型结构的铌酸锂电光调制器进行了优化设计.分析表明,采用脊波导和T型电极相结合的方式,能在保持高的特征阻抗的同时有效的实现相速匹配和有效降低电极损耗,从而较好的提高器件性能,是一种比较有潜力的调制器.利用优化结果,给出一种带宽达153 GHz,半波电压为8.55 V,特征阻抗为44 Ω的调制器的设计例子.     

Normalized Lempel-Ziv complexity and its application in bio-sequence analysis

In this article, we propose a new method to measure DNA similarity based on a normalized Lempel-Ziv complexity scheme. The new method can weaken the effect of sequence length on complexity measurement and save computation time. Firstly, a DNA sequence is transformed into three (0,1)-sequences based on a scheme, which considers “A” and “non-A” , “G” and “non-G”, “C” and “non-C” bases respectively. Then, the normalized Lempel-Ziv complexity of the three (0,1)-sequences constitute a 3D vector. Finally, by the 3D vector, one may characterize DNA sequences and compute similarity matrix for them. The examination of similarities of two sets of DNA sequences illustrates the utility of the method in local and global similarity analysis.     

Electrochemical determination of acetaminophen using a glassy carbon electrode modified with a hybrid material consisting of graphene aerogel and octadecylamine-functionalized carbon quantum dots

The study reports on the synthesis of a graphene aerogel@octadecylamine-functionalized carbon quantum dots (GA@O-CQDs). The graphene oxide aqueous dispersion, O-CQDs aqueous dispersion and toluene were strongly mixed to make a toluene-in-water Pickering emulsion. The graphene oxide sheets in the aqueous phase are reduced by hydrazine hydrate, diffuse into the toluene droplets, and self-assemble into graphene oxide microgels. This is followed by freeze-drying and thermal annealing to obtain the GA@O-CQDs hybrid that has a three-dimensional structure of several microns. It was dispersed in ethanol and deposited on a glassy carbon electrode. The modified electrode was applied to differential pulse voltammetric determination of acetaminophen, best at a peak potential of 0.15 V (vs. Ag/AgCl). Figures of the merit include a wide linear response range (0.001–10 μM) and a 0.38 nM of the detection limit (S/N?=?3). The assay has been applied to the determination of acetaminophen in tablets.

Open image in new window

Graphical abstract Schematic presentation of the synthesis of graphene aerogel@octadecylamine-functionalized carbon quantum dots. The synthesis achieves to the intimate chemical and electrical contact between graphene and carbon quantum dots. An electrode modified with the hybrid exhibits ultra high sensitivity for detection of acetaminophen.

     

Delay-dependent stochastic stability criteria for Markovian jumping neural networks with mode-dependent time-varying delays and partially known transition rates

In this paper, the problem of stochastic stability criterion of Markovian jumping neural networks with mode-dependent time-varying delays and partially known transition rates is considered. Some new delay-dependent stability criteria are derived by choosing a new class of Lyapunov functional. The obtained criteria are less conservative because free-weighting matrices method and a convex optimization approach are considered. Finally, a numerical example is given to illustrate the effectiveness of the proposed method.     

邻羧基苯基重氮氨基偶氮苯与锌显色反应的研究及其应用

在硼砂-氢氧化钠(pH＝10.4)介质中，邻羧基苯基重氮氨基偶氮苯与锌发生灵敏的显色反应，生成一种稳定的橙红色配合物，该配合物的最大吸收峰为525nm，表观摩尔吸光系数为2.1×105L·mol-1·cm-1，锌在0～10μg/25ml之间符合比耳定律。方法具有较好选择性，巳用于食品包装材料锌污染的直接检测，结果与原子吸收法一致。     

New asymptotic stability criteria for neural networks with time-varying delay

The problem of delay-dependent asymptotic stability criteria for neural networks with time-varying delay is investigated. A new class of Lyapunov functional is constructed to derive some new delay-dependent stability criteria.The obtained criterion are less conservative because free-weighting matrices method and a convex optimization approach are considered. Finally, numerical examples are given to demonstrate the effectiveness of the proposed method.