新型功能碳材料的高压截获

高性能功能材料在诸多领域具有广泛的应用前景,是人们一直关注的研究热点。高压可以有效地改变物质的原子间距和成键方式,是获得新型功能材料的重要途径。在碳材料的高压研究中,许多有趣的功能碳材料,如光学透明碳、高强度弹性碳和超硬非晶碳等,已经通过不同的碳前驱体合成。本文简要介绍了作者近年来在低维碳基纳米复合材料高压研究中取得的进展,基于设计的不同低维碳前驱体,高压下截获了具有超硬特性、新型压致共价聚合及发光增强的碳材料。     

肉苁蓉挥发性化学成分分析

报道了用同时蒸馏—萃取法提取肉苁蓉挥发性物质，测得肉苁蓉挥发油的含量为3．5％；利用GC／MS法分离确认出24种化学成分；用峰面积归一化法得出各化学成分在挥发油中的相对百分含量，其中主要成分为丁香酚，占总挥发油的83．60％；又用单离子法分离出丁香酚，并用IR，EI-MS法对其进行分析确认。     

水泥聚苯模壳格构式混凝土墙体的抗侧性能试验及分析

论文介绍6片不同高宽比的水泥聚苯模壳格构式混凝土墙体在轴压力和水平往复侧推力作用下的试验,分析这种墙体的抗侧强度、刚度和延性等力学性能.试验表明,高宽比大于1的墙体破坏时表现为墙体跟部的单一水平裂缝,其他部位完好;高宽比3∶4的墙体破坏时存在多条通过格构梁柱的斜向裂缝,墙体裂缝分布密集,变形能力好.     

Valorization of Rice Straw via Hydrotropic Lignin Extraction and Its Characterization

Rice straw hydrotropic lignin was extracted from p-Toluene sulfonic acid (p-TsOH) fractionation with a different combined delignification factor (CDF). Hydrotropic lignin characterization was systematically investigated, and alkaline lignin was also studied for the contrast. Results showed that the hydrotropic rice straw lignin particle was in nanometer scopes. Compared with alkaline lignin, the hydrotropic lignin had greater molecular weight. NMR analysis showed that β-aryl ether linkage was well preserved at low severities, and the unsaturation in the side chain of hydrotropic lignin was high. H units and G units were preferentially degraded and subsequently condensed at high severity. High severity also resulted in the cleavage of part β-aryl ether linkage. ³¹P-NMR showed the decrease in aliphatic hydroxyl groups and the increasing carboxyl group content at high severity. The maximum weight loss temperature of the hydrotropic lignin was in the range of 330–350 °C, higher than the alkaline lignin, and the glass conversion temperature (T_g) of the hydrotropic lignin was in the range of 107–125 °C, lower than that of the alkaline lignin. The hydrotropic lignin has high β-aryl ether linkage content, high activity, nanoscale particle size, and low T_g, which is beneficial for its further valorization.     

Adaptive dynamic surface neural network control for nonstrict-feedback uncertain nonlinear systems with constraints

This paper presents an adaptive dynamic surface neural network control for a class of nonstrict-feedback uncertain nonlinear systems subjected to input saturation, dead zone and output constraint. The problem of input saturation is solved by designing an anti-windup compensator, and the issue of output constraint is addressed by introducing tan-type Barrier Lyapunov function. Furthermore, based on adaptive backstepping technique, a series of novel stabilizing functions are derived. First-order sliding mode differentiator is introduced into backstepping design to obtain the first-order derivative of virtual control. The real control input is obtained using dead-zone inverse method. It is proved that the proposed control scheme can achieve finite time convergence of the output tracking error into a small neighbor of the origin and guarantee all the closed-loop signals are bounded. Simulation results demonstrate the effectiveness of the proposed control scheme.     

A novel chaotic attractor

In this letter, a novel chaotic attractor is reported. Some basic dynamical properties, such as Lyapunov exponents, fractal dimension, Poincare mapping, the continuous spectrum and chaotic behavior of this new transverse butterfly attractor are studied. Meanwhile, the forming mechanism of its compound structure obtained by merging together two simple attractors after performing one mirror operation has been investigated by detailed numerical as well as theoretical analysis. Furthermore, the complex chaotic dynamical behavior of the system has been also proofed by experimental simulation of a designed electronic oscillator based on EWB.     

Hyperchaos synchronization of fractional-order arbitrary dimensional dynamical systems via modified sliding mode control

This paper considers the design of adaptive sliding mode control approach for synchronization of a class of fractional-order arbitrary dimensional hyperchaotic systems with unknown bounded disturbances. This approach is based on the principle of sliding mode control and adaptive compensation term for solving the problem of synchronization of the unknown parameters in fractional-order nonlinear systems. In particular, a novel fractional-order five dimensional hyperchaotic system has been introduced as a representative example. Furthermore, global stability and asymptotic synchronization between the outputs of master and slave systems can be achieved based on the modified Lyapunov functional and fractional stability condition. Simulation results are provided in detail to illustrate the performance of the proposed approach.     

A new chaotic attractor

In a previous article [Chaos, Solitons and Fractals, 13 (2002) 1037], the authors have analyzed the multifractal Lyapunov spectrum. Here we continue that study by considering perturbations of the potential and the dynamics to obtain variational expressions for the entropies and Lyapunov spectra. The spirit and the framework of this note is to obtain, beyond hyperbolicity, variational results, some of which are new and some other which have already been derived but under stronger conditions.