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量子点(QD)作为一种新型的半导体纳米发光材料,由于其独特的光学性质,如发光颜色可调、尺寸可调、激发光谱宽和发射光谱窄等优点,自被发现以来一直备受关注。相比于单量子点而言,核/壳量子点更为优异的光学性能使其成为光伏器件应用中的理想材料,例如在量子点敏化太阳能电池中,Ⅰ型核/壳量子点太阳能电池器件表现出更高的稳定性和转换效率。然而,界面电荷转移和电荷复合过程如何影响器件性能一直是大家关注的焦点,相关方面认知的匮乏阻碍了量子点光伏器件的进一步发展。为了对电荷转移(CT)和复合过程有更加清晰的认识,通过利用飞秒时间分辨瞬态吸收(TA)光谱和量子化学计算相结合的方法,对Ⅰ型CdSe/ZnS核/壳量子点和三种量子点-电子受体分子(如1-氯蒽醌(1-CAQ)、蒽醌(AQ)和甲基紫(MV2+))复合物的载流子动力学进行了全面而细致的研究。通过光谱分析表明,QD-MV2+复合物发生了最快的电子转移(ET)和俄歇复合(AR)过程,并且ET速率与AR速率呈正相关关系。此外,根据Marcus ET理论和密度泛函理论计算,证明了电子受体的带隙和给受体之间的能级差作为... 相似文献
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Laser-induced fluorescence experimental spectroscopy and theoretical calculations of uranium monoxide 下载免费PDF全文
Xi-Lin Bai 《中国物理 B》2022,31(5):53301-053301
As a model molecule of actinide chemistry, UO molecule plays an important role in understanding the electronic structure and chemical bonding of actinide-containing species. We report a study of the laser-induced fluorescence spectra of the U16O and U18O using two-dimensional spectroscopy. Several rotationally resolved excitation spectra were investigated. Accurate molecular rotational constants and equilibrium internuclear distances were reported. Low-lying electronic states information was extracted from high resolution dispersed fluorescence spectra and analyzed by the ligand field theory model. The configuration of the ground state was determined as U2+(5f37s)O2-. The branching ratios, and the vibrational harmonic and anharmonic parameters were also obtained. Radiative lifetimes were determined by recording the time-resolved fluorescence spectroscopy. Transition dipole moments were calculated using the branching ratios and the radiative lifetimes. These findings were elucidated by using quantum-chemical calculations, and the chemical bonding was also analyzed. The findings presented in this work will enrich our understanding of actinide-containing molecules. 相似文献
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对有、无缝合复合材料层合板的拉伸疲劳性能进行了试验研究,考察了0^\circ
缝合对复合材料光滑板拉伸疲劳损伤扩展规律的影响. 通过有限元素法分析了有、无缝合复
合材料层合板的应力状态分布情况,对缝合复合材料层合板的拉伸疲劳损伤及其扩展机理进
行了分析. 研究表明,缝合改变了复合材料层合板拉伸疲劳损伤起始与扩展的机理,针脚
附近的面内正应力\sigma_{x}与层间剪应力的集中对层合板拉伸疲劳损伤的
发生与扩展有着重要的作用,自由边界处的层间集中应力对缝合板的疲劳性能也有影响. 自
由边界处的层间集中应力是导致无缝合层合板疲劳损伤及其扩展的主要原因. 相似文献
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