排序方式: 共有26条查询结果,搜索用时 875 毫秒
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一维链状配位聚合物{[Cu(H2bttc)(H2O)3]·3H2O}n的非等温反应动力学和晶体结构 总被引:1,自引:0,他引:1
为研究配位聚合物{[Cu(H2bttc)(H2O)3]·3H2O}n(H2bttc=1,2,4,5-benzenetetracarboxylate)的热分解机理和非等温反应动力学进行了DSC和TG-DTG热分析。由热分析结果和FTIR光谱推测了其热分解机理;将Kissinger法、Ozawa法、积分法和微分法得到的动力学参数进行比较确定了第一个失重过程最可能的动力学模型函数。配位聚合物的X射线单晶结构分析表明它由 [Cu(H2bttc)(H2O)3]n分子链组成,并有客体水分子通过分子间氢键附着在分子链上。这一结构特点与热分析结果相一致。还有一种氢键将分子链连接起来形成二维框架,这一框架在失去配位水和结晶水后到553 K开始分解。 相似文献
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本文分析了矩阵DA的特征值,并提出了一种新的矩阵稳定性问题:D--稳定性和块D--稳定性.这里D是一个正对角阵,A是给定的矩阵.应用劳斯判据及李雅普诺夫方法等,详细地分析了此类稳定性问题,提出了一些易于验证的结果,可用于分析多变量奇异摄动系统稳定问题. 相似文献
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结构误差造成的半球谐振陀螺闭环检测误差分析 总被引:3,自引:1,他引:3
半球谐振陀螺是一种具有广阔应用前景的高精度陀螺。由于制造工艺和装配过程中的因素,其结构难免会出现误差。根据闭环检测机理,推导出结构误差的数学表达式,分析了它对测量结果的影响,这对于编制软件算法以补偿结构误差具有一定的指导意义。 相似文献
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对粘土的变流变参数模型的探讨 总被引:1,自引:0,他引:1
本文基于粘土的常流变参数模型的流变参数值离散性较大,而提出变流变参数模型.时间关系曲线.经过换算后可得应变-时间关... 相似文献
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A dimeric coordination complex Cd2(ncpo)2(phen)2(H2O)2 was constructed by a flexible dicarboxylic acid, 2-nitro-4-carboxylphenoxyacetic acid. Its crystal structure was determined by X-ray single-crystal diffraction analysis. The crystal is of monoclinic system, space group P21/n with a = 17.2616(3), b = 12.7460(2), c = 18.4041(3) A^°, β= 94.432(1)°, C42H30Cd2N6O16, Mr = 1099.52, V = 4037.09(12)A^°^3 Dc = 1.809 g/cm^3, F(000) = 2192, μ = 1.139 cm^-1 and Z = 4. The final R = 0.0218 and wR = 0.0703 for 8288 observed reflections with I 〉 2σ(I). There are two crystallographically independent but structurally very similar molecules in the unit cell of the title complex. It is noticeable that the ligand ncpo^2- displays a good flexibility, demonstrating different modes from the rigid ligands. The luminescence property has been investigated, which shows photoluminescence at 465, 490 and 574 nm upon excitation at 320 nm in the solid state at room temperature. 相似文献
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A 1-D paddle-wheel copper (II) coordination polymer constructed by 2-nitro-benzene-1,4-di(oxyacetic) acid has been synthesized by hydrothermal reaction,and its crystal structure was determined by X-ray diffraction. The crystal is of triclinic,space group P1 with a=7.7257(12),b=8.3648(13),c=11.5516(18),α=76.654(2),β=82.088(2),γ=63.636(2)o,C20H22Cu2N2O20,Mr=737.48,V=650.27(18)3,Dc=1.883 g/cm3,F(000)=374,μ=1.737 cm-1 and Z=1. The final refinement gave R=0.0345 and wR=0.0995 for 1996 observed reflections with I > 2σ(I). The coordination polymer demonstrates a 1-D microporous structure,and the channel is formed by two NBDOA2-and two Cu2+ ions. The ligand NBDOAH2 displays a good flexible characteristic. The 1-D chains are connected to a 3-D supramolecular network by hydrogen bonds. 相似文献
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壳聚糖(CS)是自然界中唯一的聚阳离子碱性多糖,具有良好的组织相容性、生物可降解性、无毒、无刺激、pH响应性等优点,因而在药物控释领域的具有潜在的应用价值。将聚阳离子壳聚糖与聚阴离子甲基丙烯酰氧乙基磷酰胆碱-甲基丙烯酸二元共聚物(poly(MPC-co-MA),PMA30)进行静电复合,制备CS-PMA30聚离子水凝胶。以考马斯亮蓝为模型药物,对CS-PMA30水凝胶的控释性能进行研究。结果表明,该CS-PMA30体系是通过静电作用形成的物理交联水凝胶,具有pH响应性,有望在药物控释、组织工程等领域得到广泛应用。 相似文献
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