Elimination of fictitious penetrating rays from PO and hybridization with AFIM

Physical optics (PO) is an approximation method for high‐frequency scattering and diffraction problems. But PO fields are inaccurate in the shadow region where the source is screened by the scatter. Two key factors of the error for PO are (i) edge diffraction coefficients and (ii) existence of fictitious penetrating rays. The correction with respect to the former has been extensively investigated by many authors using various ray techniques such as GTD, UTD, and UAT. On the other hand, the latter was identified recently by the authors. This paper proposes novel PO‐based calculation procedures termed PO‐AF and PTD‐AF, where PO and Aperture Field Integration Method (AFIM) are merged with the help of special elementary diffraction coefficients. These can uniformly cover the whole angular region and only the error factor (ii) is removed in PO‐AF while both (i) and (ii) are removed in PTD‐AF. The theoretical backgrounds of PO currents are discussed in terms of field equivalence theorem and visualization of EM waves. Next, new methods are proposed and their validity is numerically demonstrated for 2D scattering problems of a strip, a corner reflector, and a cylinder of circular arc. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(2): 1–10, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20037     

Performance of solvothermally prepared Ga2O3-Al2O3 catalysts for SCR of NO with methane

The solvothermal reaction of mixtures of aluminum isopropoxide (AIP) and gallium acetylacetonate (Ga(acac)₃) directly yielded the mixed oxides of γ-Ga₂O₃-Al₂O₃. In the solvothermal synthesis, the crystal structure of mixed oxides was controlled by the initial formation of γ-Ga₂O₃ nuclei. The mixed oxides prepared in diethylenetriamine have extremely high activities for selective catalytic reduction (SCR) of NO with methane as a reducing agent. With increasing crystallite size of the spinel structure, the catalytic activity increased. The ratio of the amount of methane consumed by combustion to total methane conversion was proportional to the density of acid sites on the surface of the mixed oxides. The mixed oxide catalysts prepared in diethylenetriamine had lower densities of acid sites and showed a higher methane-efficiency for CH₄-SCR than those prepared in other solvents. These catalysts maintained their high activity even when the reaction was carried out under the severe conditions (i.e., high space velocity and low NO concentration).     

Distortion correction of NOAA image by statistical method

Remote sensing technique by satellite has been well-developed in recent years. In this paper two kinds of statistical correction methods are proposed to clarify observation data by NOAA with atmospheric scattering. The first method is the deletion of the path radiance effect by the least squares method. The second uses a smoothing filter. These methods are applied to the original remote sensing data collected on 26 July 1987.     

BIDIRECTIONAL TRANSMISSION OF ADDRESSED AUDIO SIGNAL THROUGH GI MULTIMODE OPTICAL FIBRES

This paper describes two types of bidirectional addressed audio signal transmission systems where the square-wave frequency modulation (SWFM) and intensity modulation (IM) are used to obtain the optical SWFM signals generated from LEDs at 850 nm. The first one is an addressed audio signal transmission network of tree structure. The sender and auxiliary receiver in the centre are connected to four terminals, each consisting of a receiver and an auxiliary sender, through pairs of optical fibres and an optical splitter used as an optical signal distributor. The second one is a new type of full-duplex one-to-one communication system. The sender and auxiliary receiver in one terminal are connected to the receiver and auxiliary sender in the other terminal through an optical fibre and a pair of directional couplers. Although LEDs in the second system deliver optical SWFM signals at the same wavelength of 850 nm at the same time, the communications are satisfactory because there is no interference from one LED to the other. In both the first and second experimental systems, the audio signal, address, and SWFM carrier occupy 10 Hz to 20 kHz, 65 kHz to 710 kHz, and 6 MHz, respectively. The SNR and distortion were 62 dB and 0.4 per cent, respectively.     

Condensation of organic binary mixtures flowing horizontally in a horizontal tube bundle

Both heat and mass transfer in the gas phase and heat transfer in the liquid phase are examined experimentally for film condensation of organic binary mixtures such as ethanol-water and methanol-water. Experimental results on the average heat flux, vapor-liquid interface temperature and liquid-phase Nusselt number are compared with analytical solutions based on stagnant film theory and heat-transfer relationships for film condensation from a pure vapor. Experimental heat transfer results agree well with the analytical solutions, except that the experimental liquid-phase Nusselt numbers under conditions of low mass fraction of water are considerably higher than predicted by the analytical solutions. This high value of the liquid-phase Nusselt number is considered to be caused by dropwise condensation in the liquid phase. However, its effect on the tube bundle is not so remarkable compared with that in gravity-controlled condensation on a vertical surface. This is considered to be caused by the condensate inundation effect. © 1997 Scripta Technica, Inc. Heat Trans Jpn Res, 25(6): 342–361, 1996     

Resolution of Epoxydienes by Reversed-Phase Chiral HPLC and its Application to Stereochemistry Assignment of Mulberry Looper Sex Pheromone

Resolution of insect pheromonal cis-epoxydiene racemates derived from (Z,Z,Z)-3,6,9-trienes was examined with a reversed-phase chiral HPLC column. The results showed that a Chiralcel OJ-R column was suitable for separating the enantiomers having a C₁₇–C₂₃ unsaturated straight chain except for 9,10-epoxydienes with a C₂₁–C₂₃ chain. To determine the absolute configuration of the separated enantiomers, each of the optically active epoxydienes was hydrogenated over Pd-BaSO₄ and its behavior was examined on this chiral column by cochromatography with the corresponding chiral epoxy compound having a saturated chain, which was prepared via a Sharpless epoxidation reaction. This analysis showed that the dextrorotatory C₁₇–C₂₃ 3,4- and 6,7-epoxydienes and C₁₇–C₂₀ 9,10-epoxydienes with shorter R _ts possess (3S,4R)-, (6S,7R)-, and (9R,10S) configurations, respectively, and the levorotatory enantiomers with longer R _ts possess the opposite configuration. An abdominal tip extract of the mulberry looper, Hemerophila artilineata Butler (Lepidoptera: Geometridae: Ennominae), included (9S,10R)-(Z,Z)-cis-9,10-epoxy-3,6-octadecadiene as a main sex pheromone component. The synthetic (9S,10R)-9,10-epoxydiene, rather than its antipode, elicited strong antennal and behavioral responses from the male moths in electrophysiological and field tests.     

Novel Components of the Sex Pheromones Produced by Emerald Moths: Identification,Synthesis, and Field Evaluation

The subfamily Geometrinae (Lepidoptera: Geometridae) includes many species called emerald moths. Based on our recent finding of novel polyenyl compounds, including a double bond at the 12-position from two geometrine species, Hemithea tritonaria and Thalassodes immissaria intaminata, (6Z,9Z,12Z)-6,9,12-trienes and (3Z,6Z,9Z,12Z)-3,6,9,12-tetraenes with a C₁₇–C₂₀ straight chain were synthesized and analyzed by GC-MS. The 6,9,12-trienes, which were prepared by a double Wittig reaction between two alkanals and an ylide derived from (Z)-1,6-diiodo-3-hexene, characteristically produced fragment ions at m/z 79, 150, and M–98. The 3,6,9,12-tetraenes, which were prepared by a coupling between (Z)-3-alkenal and an ylide derived from (3Z,6Z)-1-iodo-3,6-nonadiene, showed fragment ions at m/z 79, 148, and M–96. These diagnostic ions were useful to distinguish these compounds from other known polyenyl pheromones, such as 4,6,9- and 6,9,11-trienes and 1,3,6,9-tetraenes. With reference to the GC-MS data, pheromone extracts of other species in Geometrinae inhabiting the Iriomote Islands were analyzed, and the 6,9,12-trienes were identified in the pheromone gland extracts of Pamphlebia rubrolimbraria rubrolimbraria and Maxates versicauda microptera. Furthermore, a field evaluation of the synthetic polyenes in a mixed forest of Tokyo revealed the following new male attractants for emerald moths: Idiochlora ussuriaria by a C₁₇ 6,9,12-triene and Jodis lactearia by a C₂₀ 3,6,9,12-tetraene, indicating the characteristic chemical structures of Geometrinae pheromones. On the other hand, through reexamination of the pheromone extract of H. tritonaria, (3E,6E)-α-farnesene was identified as an electrophysiologically active component in addition to the C₁₇ 6,9,12-triene. The binary mixture attracted more males than the single component lure baited with the triene in the Iriomote Islands.     

Ice clouds and Asian dust studied with lidar measurements of particle extinction-to-backscatter ratio, particle depolarization, and water-vapor mixing ratio over Tsukuba

The tropospheric particle extinction-to-backscatter ratio, the depolarization ratio, and the water-vapor mixing ratio were measured by use of a Raman lidar and a polarization lidar during the Asian dust seasons in 2001 and 2002 in Tsukuba, Japan. The apparent (not corrected for multiple-scattering effects) extinction-to-backscatter ratios (Sp) showed a dependence on the relative humidity with respect to ice (RHice) obtained from the lidar-derived water-vapor mixing ratio and radiosonde-derived temperature; they were mostly higher than 30 sr in dry air (RHice < 50%), whereas they were mostly lower than 30 sr in ice-supersaturated air (RHice > or = 100%), where the apparent extinction coefficients were larger than 0.036 km(-1). Both regions showed mean particle depolarization ratios of 20%-22%. Comparisons with theoretical calculations and the previous experiments suggest that the observed dependence of Sp on RHice is attributed to the difference in the predominant particles: nonspherical aerosols (mainly the Asian dust) in dry air and cloud particles in ice-supersaturated air.     

LIPID CLASSES, FATTY ACID COMPOSITIONS AND TRIACYLGLYCEROL MOLECULAR SPECIES FROM ADZUKI BEANS (VIGNA ANGULARIS)

The lipids extracted from adzuki beans grown in Japan were classified by thin-layer chromatography (TLC) into eight fractions. Molecular species and fatty acid distributions of triacylglycerols (TAGs) isolated from the total lipids in the beans were determined from a combination of argentation-TLC and gas chromatography. The major lipid components were phospholipids (PL; 63.5%) and TAG (21.2%), while hydrocarbons (5.1%), steryl esters (7.5%), free fatty acids (0.9%), diacylglycerols (1.3%) and monoacylglycerols (0.5%) were also present in minor proportions. Both major samples had high amounts of total unsaturated fatty acids, representing 62.1% for TAG and 65.9% for PL. Seventeen different molecular species were detected. The major TAG components were SMD (5.0%), S₂T (19.3%), SD₂ (13.8%), SMT (9.3%), MD₂ (4.5%), SDT (7.0%), D₃ (8.8%) and ST₂ (15.9%), where S, M, D and T denote a saturated fatty acid, a monoene, a diene and a triene, respectively.

PRACTICAL APPLICATIONS

This article describes the characteristics of lipid components, fatty acid compositions as well as the profiles of triacylglycerol (TAG) molecular species of adzuki beans. α-Linolenic (18:3 n -3) acid was detected as 24.8, 21.2 and 15.2% in the TAG, total lipids and phospholipids, respectively. The oil from legumes, except the profitable fatty acid content, could be a potential source of tocopherols. The data obtained in this study would be useful to both consumers and producers for manufacturing traditional adzuki confectionaries ( wagashi ) in Japan and elsewhere.