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Thermodynamic assessments were made to optimize thermodynamic models and parameter fits to selected experimental and first principles hypothetical predicted phase data within the Na–Al–Ti–H system. This enabled thermodynamic modeling of Ti solubility within the sodium alanates: NaAlH4 and Na3AlH6, and the relative stability of Ti-bearing phases. The modeling provides insights into the role of Ti originating from Ti-based activating agents commonly referred to as ‘catalysts’ in promoting reversibility of the Na–Al–H dehydrogenation and rehydrogenation reactions under moderate temperature and pressure conditions relevant to H storage applications. Preliminary assessments were made to evaluate H solubility in bcc-Ti and hcp-Ti, and stability of the hydride δ-TiH2. To model possible Ti dissolution in NaAlH4 and α-Na3AlH6, sub-lattice models were applied. A repulsive interaction is predicted by first principles calculations when Ti is dissolved in NaAlH4 or α-Na3AlH6, which becomes stronger with increasing temperature. Although Ti is virtually insoluble in NaAlH4 or α-Na3AlH6, a small addition of TiCl3 will induce a thermodynamic driving force for formation of TiH2 and/or TiAl3. The addition of pure Ti shows a weaker effect than TiCl3 and leads to formation of TiH2 only. Based on a combined interpretation of present thermodynamic modeling and prior experimental observations, the TiAl3 and TiH2 phases are ascribed to have a catalytic effect, not a thermodynamic destabilization effect, on the reversibility of the dehydrogenation/rehydrogenation reactions in the Na–Al–H system. 相似文献
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选择性激光烧结工艺(selective laser sintering,SLS)加工中所产生的翘曲变形严重影响了成型件的加工精度和SLS技术的应用与推广。本文在研究SLS成型误差的基础上,分析造成SLS成型件翘曲的主要原因与产生的机理,构建了一种新的翘曲变形的力学模型。并以此模型为基础,分析了现有SLS扫描方式存在的不足,提出一种新的间隔式激光光栅扫描方式。通过实验验证,该扫描方式可以有效地降低SLS成型件的翘曲变形,提高SLS成型件的加工精度,而且能大大提高加工速度,降低加工能耗。 相似文献
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Seed Oils of Five Black Tartary Buckwheat Cultivars with Biochemical Characterization and Antioxidant Properties 下载免费PDF全文
Zhen Zhang Caian He Ruixue Zhu Jing Shen Yueli Yu Qiang Peng Jinfeng Gao Yunlong Li Min Wang 《Journal of the American Oil Chemists' Society》2016,93(8):1127-1136
Black tartary buckwheat oils (BTBOs) were extracted from five major industrial tartary buckwheat cultivars grown under similar agronomical activities and environmental conditions. These oils were characterized for the bioactive compounds containing fatty acids, β‐carotene, lutein, α‐, β‐, δ‐ and γ‐tocopherol, and for their antioxidant properties. The total tocopherol contents that were obtained ranged from 704.66 to 1156.19 mg/kg, with γ‐tocopherol (588.98–977.91 mg/kg) as the main component. The concentration of lutein ranged from 253.14 to 429.63 mg/kg, which was almost ten times higher than that of β‐carotenoid (46.71–69.2 mg/kg), indicating that black tartary buckwheat seed oils were a good source of lutein. The predominant fatty acids were unsaturated oleic acid (C18:1) (35.27–40.61 %) and linoleic acid (C18:2) (38.25–42.90 %). Excellent values of 2,2‐diphenyl‐1‐picrylhydrazyl radical (DPPH), diammonium salt (ABTS) radical scavenging activities were obtained and the highest oxygen radical absorbance capacity (ORAC) value of 13.89 mmol Trolox equiv/g oil was detected in the variety of Chuanqiao No. 1, which was clearly separated by principal component analysis (PCA) on the basis of the highest content of tocopherols and carotenoids. Moreover, the correlation analysis showed that tocopherols and carotenoids were the major contributors to the antioxidant activities of the BTBOs. This study demonstrates that lipophilic extraction in the tartary buckwheat seed contains many interesting bioactive compounds, which are beneficial for human health. 相似文献
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食品安全已经成为世界性的话题,针对物联网在食品加工环节的应用展开研究,利用物联网的传感器对食品在加工环节的数据进行记录和监控,在服务器端把收集的数据存入数据库,并实现数据库的设计,为食品出厂的质量做出贡献。 相似文献
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垂线平均含沙量两种表述方法之比较 总被引:1,自引:0,他引:1
表达沿垂线平均含沙量的方法通常有流量法与面积法两种,但在实际运用中常发生混淆。本文讨论了两种垂线平均含沙量之间的关系,指出面积平均含沙量需要大于流量平均含沙量。含沙量及流速分布越不均匀,两者差别就越大,当悬浮指标2≤0.3时两者相差不到10%,最后还对两种垂线平均含沙量的应用作了初步搪塞。 相似文献
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Caian Qiu 《Metallurgical and Materials Transactions A》1993,24(11):2393-2409