一种白铜管坯的近终形连铸

采用水平连铸工艺制备了空心BFe10-1-1白铜管坯，并对铸态管坯的表面质量、凝固组织及力学性能进行分析。结果表明，采用合适的工艺参数，可以利用水平连铸的方法制备出表面光滑，凝固组织致密的近终形BFe10-1-1白铜管坯；管坯的力学性能随着温度升高而下降，室温时管坯具有良好的塑性。     

旋转电磁场对BFe10-1-1合金管坯组织及力学性能的影响

研究旋转电磁场对水平连铸空心BFe10-1-1合金管坯凝固组织和力学性能的影响,并对其机理进行初步的探讨。结果表明：在工频旋转电磁场的搅拌作用下,BFe10-1-1合金管坯的凝固组织显著细化,由粗大的柱状晶完全转化为均匀细小的等轴晶,同时抑制了Ni元素的枝晶偏析;施加电磁场后管坯的力学性能得到明显改善,当励磁电流为80 A时,管坯抗拉强度提高了15.3%,屈服强度提高了10.9%,伸长率提高了58.6%。     

Influence of rare earth elements on corrosion resistance of BFe10-1-1 alloys in flowing marine water

The corrosion behavior of BFe10-1-1 alloy with different rare earth (RE) contents in simulated flowing marine water was investi-gated by X-ray diffractometer and scanning electron microscope (SEM). It was demonstrated that the corrosion rate of BFe10-1-1 alloy with the same chemical compositions in faster flow velocity of marine water was higher than that in a lower flow velocity of marine water. Fixing the flow velocity, BFe10-1-1 alloy had the best flushing corrosion resistance when the RE content was 0.04wt.%. The consequence of such good corrosion resistance was attributed to the formation of compact protective film on alloy surface containing RE phase such as CeNi5- The RE-contained film combines with other corrosion products firmly, which was difficult to fall off from the alloy surface in the flowing marine water. Additionally, SEM analysis confirmed that pitting mechanism, which would be transformed to spalling mechanism gradually with further increasing RE content, was the prevalent mechanism when the alloy contained 0.04wt.%RE.     

稀土对纯铜和BFe10-1-1合金再结晶温度的影响

在纯铜和BFe10-1-1铁白铜中添加不同比例的稀土元素,经熔铸、轧制和热处理试验,通过对试样进行组织与力学性能分析,研究了稀土对其再结晶温度的影响.结果显示,随着稀土含量的增加,在相同退火条件下纯铜和BFe10-1-1铁白铜的再结晶程度均明显降低,表明其再结晶温度均有所提高.第二相粒子对位错的钉扎作用是再结晶温度提高的根本原因.     

稀土精炼紫杂铜的实验研究

采用自行研制的三种Cu-RE精炼剂对紫杂铜进行了精炼试验,采用等离子体发射光谱、能谱分析、金相分析和X射线衍射分析等方法,分析和研究了添加稀土对紫杂铜精炼效果及其对组织的影响.试验结果表明,在紫杂铜中加入适量的稀土精炼剂,精炼和脱氧效果良好,可明显减少O、Pb、Bi、Sn、Al等杂质元素;添加适量稀土元素,还可使紫杂铜铸造组织的枝晶细化,组织更加均匀.