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The SO_4~(2-)concentration distributions in surface region of cement mortar immersed in sulfate solution at early stage were measured by layered sampling method combined with chemical analysis, and the diffusion coefficients of SO_4~(2-)anions in surface region of mortar into internal area were calculated by means of instantaneous plane diffusion theory. The experimental results showed that the SO_4~(2-)concentration gradually reduced when the diffusion depth increased in the surface region of mortar. Diffusion coefficient(D) was relevant with the concentration and kind of environmental sulfate solution, which reduced with immersion time at the beginning, and then rose slowly after a period of time. The calculation of initial diffusion coefficient(D_0) and starting time of deterioration(t_∞) caused by sulfate attack was further attempted based on the data of diffusion coefficient, and it was found that D_0 and t∞ were all relevant with concentrations of sulfate and different kind of sulfate as well. 相似文献
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The continuous growth of the height of the coal mine surface slag heap will make the stress size and distribution characteristics of the surrounding rock of the underground roadway under it change significantly, which will seriously lead to large deformation or damage of the roadway, and affect the safe and efficient production of the mine. Based on the geological occurrence conditions of coal strata, mining production and the actual situation of surface super-high slag pile in Wuhushan Coal Mine, a threedimensional model of surface slag pile and underground mining face in Wuhushan Coal Mine is established. The characteristic parameters of roadway surrounding rock stress peak value and location, mining influence range under different slag pile heights have been simulated and calculated, and then the influence law of different slag pile height on roadway stability is analyzed. Combined with the measured data of roadway deformation, the safety critical height of the surface slag pile is initially determined. The research results have important reference value for the safe and efficient production of similar mines. 相似文献
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制备了不同氟含量的Pt-Sn/γ-Al2O3催化剂,考察了氟含量对重整催化剂物化性质及反应性能的影响。BET,Py-IR,NH3-TPD 等测试结果表明:氟的引入对催化剂比表面积、孔体积等物化性质没有显著影响;但可明显提高催化剂酸量,氟改性的γ-Al2O3载体表面既存在L酸中心又存在B酸中心,酸量随着氟含量的增加而增大;正庚烷和石脑油的重整反应性能测试表明,随着氟含量的增加,液化气收率明显增加, C5+液体收率与芳烃收率下降,催化剂积炭速率提高,氟质量分数大于1.0%时,催化剂表现出较高的液化气(C3+C4)选择性。 相似文献
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2005年中国冶金工业环境保护论坛暨中华环境保护基金会冶金工业环境保护宣传专项基金工作年会,12月3日在北京人民大会堂隆重召开。全国政协副主席阿不来提·阿不都热西提,原全国人大常委会副委员长布赫等领导到会祝贺。首钢总公司、中国冶金建设集团公司、山西城财焦化集团公司等100多家冶金及相关产业企业的领导(代表),新华社、《人民日报》、《光明日报》、《经济日报》、中央电视台等50多家中央新闻单位记者参加了会议。 相似文献