Developing the ability to model acid-rock interactions and mineral dissolution during the RMA stimulation test performed at the Soultz-sous-Forêts EGS site,France

The Soultz Enhanced Geothermal System (EGS) reservoir's response to chemical stimulation is assessed by numerical simulation of coupled thermo-hydraulic-chemical processes. To assess chemical interactions between host rocks and a mixture of HCl and HF as well as its potential effects on the Soultz EGS reservoir, new modelling efforts using the FRACHEM code have been initiated. This article presents the model calibration and results. Simulations consider realistic conditions with available data sets from the EGS system at Soultz. Results indicate that the predicted amount of fracture sealing minerals dissolved by injection of a mixture of acids Regular Mud Acid (RMA) was consistent with the estimated amount from the test performed on GPK4 well at Soultz EGS site. Consequently reservoir porosity and permeability can be enhanced especially near the injection well by acidizing treatment.     

Diet breadth and mortality patterns from Laoya Cave: A primary profile of MIS 3/2 hunting strategies in the Yunnan-Guizhou Plateau,southwest China

Laoya Cave is a long-term occupation site of Late Paleolithic humans in the Yunnan-Guizhou Plateau, southwest China, where abundant lithic, bone materials were recovered. Dating by the AMS technique showed a significant depositional process during marine isotope stage (MIS) 3/2. In this study, the species spectrum was presented from the perspective of zooarchaeology and the mortality profile of large Cervidae was examined to help increase our understanding of the subsistence strategy of local people dealing with climate and environmental changes. The main part of the diet was focused on large Cervidae, and the dominance of Ungulates indicates effective management of the cave and local fauna. On the other hand, the mortality profiles of large Cervidae varied correspondingly with climate change. The evidence indicates a specialized hunting strategy that was also flexible, depending on the prevailing climate and environment.     

The Use of Invertebrates in Ground Water Monitoring: A Rising Research Field

The use of invertebrates as biomonitors of ground water quality is a relatively new approach that has come of age with the development of ground water ecology. The benefits of such an approach are illustrated by four examples of field biomonitoring from several sites in various hydrogeological settings. Contamination of the interstitial zone by heavy metals in some sectors of the Rhóne River (France) was shown by the scarcity of insect species; sewage pollution in the saturated zone of a karstic aquifer was indicated by the low relative abundances of stygobites as compared with those of stygophiles and stygoxenes; and enrichment with organic matter of an underflow was clearly demonstrated by the extremely high density of ground water invertebrates such as oligochaetes, ostracods, and isopods. Examination of the spatial changes in the composition and abundance of invertebrate assemblages was also useful in determining the direction and intensity of water fluxes between a river and its underflow, as well as in delineating the reduced or oxidized zones in a manganese-polluted aquifer. Finally, the selected case studies emphasized the variety of methodological approaches that could be developed in ground water contamination biomonitoring, as well as the complementary and sometimes new information provided by this innovative method in comparison with that obtained by conventional pollution monitoring techniques.     

Analysis of Cassini/CIRS limb spectra of Titan acquired during the nominal mission II: Aerosol extinction profiles in the 600–1420 cm spectral range

We have analyzed the continuum emission of limb spectra acquired by the Cassini/CIRS infrared spectrometer in order to derive information on haze extinction in the 3–0.02 mbar range (∼150–350 km). We focused on the 600–1420 cm⁻¹ spectral range and studied nine different limb observations acquired during the Cassini nominal mission at 55°S, 20°S, 5°N, 30°N, 40°N, 45°N, 55°N, 70°N and 80°N. By means of an inversion algorithm solving the radiative transfer equation, we derived the vertical profiles of haze extinction coefficients from 17 spectral ranges of 20-cm⁻¹ wide at each of the nine latitudes. At a given latitude, all extinction vertical profiles retrieved from various spectral intervals between 600 and 1120 cm⁻¹ display similar vertical slopes implying similar spectral characteristics of the material at all altitudes. We calculated a mean vertical extinction profile for each latitude and derived the ratio of the haze scale height (H_haze) to the pressure scale height (H_gas) as a function of altitude. We inferred H_haze/H_gas values varying from 0.8 to 2.4. The aerosol scale height varies with altitude and also with latitude. Overall, the haze extinction does not show strong latitudinal variations but, at 1 mbar, an increase by a factor of 1.5 is observed at the north pole compared to high southern latitudes. The vertical optical depths at 0.5 and 1.7 mbar increase from 55°S to 5°N, remain constant between 5°N and 30°N and display little variation at higher latitudes, except the presence of a slight local maximum at 45°N. The spectral dependence of the haze vertical optical depth is uniform with latitude and displays three main spectral features centered at 630 cm⁻¹, 745 cm⁻¹ and 1390 cm⁻¹, the latter showing a wide tail extending down to ∼1000 cm⁻¹. From 600 to 750 cm⁻¹, the optical depth increases by a factor of 3 in contrast with the absorbance of laboratory tholins, which is generally constant. We derived the mass mixing ratio profiles of haze at the nine latitudes. Below the 0.4-mbar level all mass mixing ratio profiles increase with height. Above this pressure level, the profiles at 40°N, 45°N, 55°N, at the edge of the polar vortex, display a decrease-with-height whereas the other profiles increase. The global increase with height of the haze mass mixing ratio suggest a source at high altitudes and a sink at low altitudes. An enrichment of haze is observed at 0.1 mbar around the equator, which could be due to a more efficient photochemistry because of the strongest insolation there or an accumulation of haze due to a balance between sedimentation and upward vertical drag.