Preliminary palaeomagnetic results of an Archaean dolerite dyke of west Greenland: geomagnetic field intensity at 2.8 Ga

The geomagnetic field intensity during Archaean times is evaluated from a palaeomagnetic and chronological study of a dolerite dyke intruded into the 3000 Ma Nuuk Gneisses at Nuuk (64.2°N, 51.7°W), west Greenland. Plagioclase from the dolerite dyke yields a mean K-Ar age of 2752 Ma. Palaeomagnetic directions after thermal demagnetization of the dyke and the gneiss reveal a positive baked-contact test, indicating that the high-temperature-component magnetization of the dyke is primary. Thellier experiments on 12 dyke specimens yield a palaeointensity value of 13.5±4.4 μT. The virtual dipole moment at ca. 2.8 Ga is 1.9±0.6 × 10²² Am², which is about one-quarter of the present value. The present study and other available data imply that the Earth's magnetic field at 2.7 ∼ 2.8 Ga was characterized by a weak dipole moment and that a fairly strong geomagnetic field similar to the present intensity followed the weak field after ca. 2.6 Ga.     

Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere

A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO₃) is a function of the DMS flux, because the reaction of DMS with NO₃ is the most important loss mechanism of NO₃. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO₃ in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO₃. The calculated ratio of the MSA to SO₂ production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO₄ ^2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO₄ ^2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO₃ is likely to be a more important sink of NO_x (NO+NO₂) than the reaction of NO₂ with OH, and to serve as a significant pathway of the HNO₃ production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO₄ ^2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO₃ during winter.     

Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH4-CO2 fluxes

Methane and CO₂ emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (δ¹³C_CH4 from −32.9‰ to −36.2‰), likely associated with oil, and enrichments of ¹³C in CO₂ (δ¹³C_CO2 up to +28.3‰) and propane (δ¹³C_C3H8 up to −8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 10¹-10⁴ g m⁻² d⁻¹ in macro-seeps, and up to 446 g m⁻² d⁻¹ from diffuse seepage. Positive CH₄ fluxes from dry soil were widespread throughout the investigated areas. Total CH₄ emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton a⁻¹, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO₂ fluxes were directly proportional to CH₄ fluxes, and the volumetric ratios between CH₄ flux and CO₂ flux were similar to the compositional CH₄/CO₂ volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the “Bernard ratio” C₁/(C₂ + C₃)) is inversely proportional to gas migration fluxes. The CH₄ “emission factor” (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global “emission-factor” data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH₄ emission from mud volcanoes may be significantly underestimated.     

Evolution of disk galaxies regulated by supernova remnants

Assuming that a disk galaxy is composed of an ambient pervasive gas, small clouds, molecular clouds and stars, its evolution is studied through examining the interchange processes among them. Main results obtained are: (1) The star formation rate is directed by the formation process of molecular clouds. (2) Depending upon the parameters there may be three or four types of evolution of disk galaxies: the no star formation case, the active in the past and inactive at present star formation case, the burst-like star formation case and the very active in star formation case.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan between 30 September–6 October, 1984.