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A lignite (C, 67.4 wt%) was depolymerized with phenol, p-nitrophenol and o-chlorophenol using sulphuric acid as catalyst. The solubility of the lignite was enhanced by these treatments, with phenol being the most reactive reagent whereas p-nitrophenol was the least reactive. The distribution of nitro- and chloro-groups in the solubilized products was investigated by infrared spectrometry and it was found that these groups were redistributed among the pyridine- and methanol-soluble materials. It is suggested that benzene-soluble material is produced by self-depolymerization of coal or by degradation of pyridine- and methanol-soluble material. 相似文献
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Hamed Salimkhani Emre Erdem Selmiye Alkan Gursel Alp Yurum 《Journal of the American Ceramic Society》2021,104(8):4257-4271
Recently, lanthanides have been employed by researchers to examine their impact on the structure and properties of Li7La3Zr2O12 (LLZO) garnets. In this regard, we developed Europium oxide (Eu2O3) doped LLZO (Li7+δEuxLa3−δZr2−δO12−δ) solid electrolyte which demonstrates a cubic phase with the symmetry of Iad (No.230) at room temperature. In this investigation, different concentrations of Eu ranging from 0.1 to 0.6 atoms per formula unit (pfu) were doped into Li7La3Zr2O12 to evaluate the impact of Eu on the stability of the cubic phase and thereby the ionic conductivity. The results unveiled that upon doping Eu3+ ions, the Eu2+ state is also formed and is then self-doped into the structure in which Rietveld refinement coupled with XPS, EPR, and solid-state NMR suggests that Eu3+ ions most probably partially occupy Zr4+ (16a) site, the Eu2+ ions occupy La3+ (24d) site, and the Li+ ions occupy two different sites (24d and 96h). It was further found that such a site preference induces distortion at LaO8 polyhedrons opening up the neck for Li-ions diffusion, thereby enhancing the ionic conductivity. Moreover, it was revealed that Li-ions probably hop from 96h to 24d and then to 96h site to generate the Li-ion movement. Overall, by introducing Eu ions into the LLZO structure, an enhanced bulk ionic conductivity of 0.30 × 10−3 S/cm at 298 K with a minimum electronic conductivity of 2.547 × 10−9 S/cm at 298 K was achieved. 相似文献
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针对GB/T 13380-2007《交流电风扇和调速器》中有关交流电风扇能效检测的方法以及所要求的检测系统,对检测所用设备的影响进行分析,通过对检测结果的计算,最终得到测量结果的不确定度,以分析、评估检测结果的可靠性.最后根据现有实验室水平提出了对检测设备改进措施的建议. 相似文献
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Naoki Yuda Miyuki Tanaka Manabu Suzuki Yuzo Asano Hiroshi Ochi Keiji Iwatsuki 《Journal of food science》2012,77(12):H254-H261
Abstract: Polyphenols, retained in black tea wastes following the commercial production of tea beverages, represent an underutilized resource. The purpose of this study was to investigate the potential use of hot‐compressed water (HCW) for the extraction of pancreatic lipase‐inhibiting polyphenols from black tea residues. Black tea residues were treated with HCW at 10 °C intervals, from 100 to 200 °C. The resulting extracts were analyzed using high‐performance liquid chromatography‐mass spectrometry and assayed to determine their inhibitory effect on pancreatic lipase activity in vitro. Four theaflavins (TF), 5 catechins, 2 quercetin glycosides, quinic acid, gallic acid, and caffeine were identified. The total polyphenol content of extracts increased with increasing temperature but lipase inhibitors (TF, theaflavin 3‐O‐gallate, theaflavin 3′‐O‐gallate, theaflavin 3,3′‐O‐gallate, epigallocatechin gallate, and epicatechin gallate) decreased over 150 °C. All extracts inhibited pancreatic lipase but extracts obtained at 100 to 140 °C showed the greatest lipase inhibition (IC50s of 0.9 to 1.3 μg/mL), consistent with the optimal extraction of TFs and catechins except catechin by HCW between 130 and 150 °C. HCW can be used to extract pancreatic lipase‐inhibiting polyphenols from black tea waste. These extracts have potential uses, as dietary supplements and medications, for the prevention and treatment of obesity. Practical Application: Active forms of lipase inhibitors can be recovered from black tea residues. They could be used as dietary supplements or medications. 相似文献
6.
Yuda Yürüm Alpay Taralp T. Nejat Veziroglu 《International Journal of Hydrogen Energy》2009,34(9):3784-3798
Recent developments focusing on novel hydrogen storage media have helped to benchmark nanostructured carbon materials as one of the ongoing strategic research areas in science and technology. In particular, certain microporous carbon powders, carbon nanomaterials, and specifically carbon nanotubes stand to deliver unparalleled performance as the next generation of base materials for storing hydrogen. Accordingly, the main goal of this report is to overview the challenges, distinguishing traits, and apparent contradictions of carbon-based hydrogen storage technologies and to emphasize recently developed nanostructured carbon materials that show potential to store hydrogen by physisorption and/or chemisorption mechanisms. Specifically touched upon are newer material preparation methods as well as experimental and theoretical attempts to elucidate, improve or predict hydrogen storage capacities, sorption–desorption kinetics, microscopic uptake mechanisms and temperature–pressure–loading interrelations in nanostructured carbons, particularly microporous powders and carbon nanotubes. 相似文献
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ABSTRACT Recovery of organic material from Israeli Mishor Rotem oil shale with toluene under supercritical conditions was investigated. The rate of solubilization, change of structural aspects and molecular weights of solubilized products with time were investigated. Experiments to recover organic material from shale were performed in a stainless steel high pressure autoclave. Shale Sample was charged in a sintered glass crucible suspended from the cap of the autoclave; toluene was the solvent in all experiments. Solvent/shale ratio was 20; experimental temperature was 34O°C. The gaseous products were analyzed by gas chromatography. Molecular weights of the organic material recovered was measured by gel permeation chromatography technique. FTIR spectra of the organic material recovered and fractions isolated by extractive and chromatographical methods were measured. The amount of kerogen remaining in the spent shale was determined by oxidative derivative thermal gravimetry. A steady state in the production of solubles was reached within 60 minutes at 340°C with a yield of 60 percent. After this time no further amounts of organic material was recovered. The molecular weights of the recovered organic material decreased at extended times after the steady state was reached. It appeared that the structure of the organic material recovered remained unchanged until the steady state condition is reached whereupon some structural changes occurred. At extended times the organic material was converted into more aromatic and less hydroxyl containing structures of lower molecular weight. The organic material recovered upon reaching steady state was fractionated into 63 percent oils (pentane solubles) and 32 percent asphaltenes (toluene solubles). The oile contained aliphatics and monoaromatic structures and the asphaltenes contained polyaromatic polar structures. Gases which constituted 4 percent of the initial kerogen were produced during the heating period to 340°C. The amount of carbon monoxide produced remained constant and amounts of hydrogen, carbon dioxide and methane decreased after supercritical conditions were attained. 相似文献
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气动葫芦等非电气设备应用在爆炸性环境时,在正常工作过程中会因机械摩擦和碰撞产生热表面、明火、灼热气体/液体、机械火花、绝热压缩、振动波、化学反应放热、铝热反应、粉尘自燃、电弧和静电放电等点燃源,形成爆炸危险。这些设备可以通过限制运行速度、润滑、限定材质、采用隔爆外壳等措施来达到防燃要求。 相似文献