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1.
Andreja ?gajnar Gotvajn Jana Zagorc-Kon?an Tatjana Ti?ler 《Canadian Metallurgical Quarterly》2007,133(1):89-94
The preoxidation of a highly polluted waste pharmaceutical fermentation broth using wet air oxidation (WAO) has been studied as a possible method for the effective removal of organics. The applied (pre)treatment method should enhance the biotreatability of the pharmaceutical fermentation broth in terms of reduced initial toxicity and higher biodegradability. Preliminary experiments in the pilot biological treatment plant were successful only at low organic loads, whereas the system collapses at higher ones. The characterization of the fermentation broth was started by common physicochemical analysis, whereas several bioassays were used to determine its impact on biological treatment plants and the environment. Toxicity prior to and after WAO was determined using the acute Vibrio fischeri test, measurement of inhibition of O2 consumption, and the Daphnia magna acute test. Ready biodegradability of the treated and untreated broth has also been assessed. WAO experiments were accomplished in the 2?L batch reactor at different temperatures (240/280°C) and operating pressures. WAO experiments confirmed reduction of the toxicity toward microorganisms, whereas oxidized wastewater was more toxic to daphnids. Biodegradability of the oxidized broth has also been enhanced. Further work has been focused on designing appropriate combination of WAO and biological processes. 相似文献
2.
Dragan Jocic Susana Vílchez Tatjana Topalovic Ricardo Molina Antonio Navarro Petar Jovancic Maria Rosa Juli Pilar Erra 《应用聚合物科学杂志》2005,97(6):2204-2214
This study examines in detail the influence of low‐temperature plasma and biopolymer chitosan treatments on wool dyeability. Wool knitted fabrics were treated and characterized by whiteness and shrink‐resistance measurements. Surface modification was assessed by contact‐angle measurements of human hair fibers, which were used as a model to study the wetting properties of the treated wool knitted fabrics. The dyeing behavior was assessed from the diffusion mechanism point of view. The dyeing kinetics were measured at two different pHs (4.2 and 6.5) and three different temperatures (60, 85, and 100°C) to gain information about the contribution of the surface modification treatment to the dyeing mechanism. The exhaustion and reflectance data were compared, and the apparent diffusion coefficients were calculated. On the basis of the obtained results, a model for the dyeing mechanism of the chitosan treated wool was proposed. When treated with chitosan, the polymer sheath spread on the surface of the fibers acted as a predominant dyeing site in very short dyeing times, thus interacting with the dye and in later stages imparting the dye to the wool fiber. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2204–2214, 2005 相似文献
3.
Tatjana Rades Chanho Pak Michèle Polisset-Thfoin Ryong Ryoo Jacques Fraissard 《Catalysis Letters》1994,29(1-2):91-103
NaY-supported bimetallic Pt-Pd catalysts have been studied by TEM, TPR and EXAFS. Small, randomly mixed particles are formed in the zeolite cages. When the Pt content is increased, a Pt core structure appears and the dispersion increases. Particle diameters are about 1–2 nm for bimetallic samples. 相似文献
4.
5.
Henny M. Borsboom Tatjana Claasen-Vujčić Harry J. G. Gaykema Toon Mehlkopf 《Magma (New York, N.Y.)》1997,5(1):33-37
The birdcage resonator is frequently used in conventional MRI because of its excellent attributes. Its use in low-field MRI
is restricted to field strengths higher than, for example, 0.1 T, dependent on the size of the coil. This is because of the
intrinsically low inductance value of the birdcage coils. Furthermore, the sensitivity of the birdcage at low field strengths
is significantly lower when compared to, for example, the solenoid. Both problems can be overcome with the multiturn technique
and a novel wound birdcage coil. The quadrature mode wound birdcage coil presented in this paper can be used at frequencies
as low as 100 kHz. Its sensitivity is also increased when compared to the conventional strip-ring birdcage. Homogeneity effective
volume, and methods to increase the resonator bandwidth to match the signal bandwidth are left intact. The latter is a typical
low-field problem. 相似文献
6.
7.
Motivated by a study of similar problems stated for factors of words, we study forbidden subwords of a language or a word. A procedure for obtaining the set of all words avoiding a given set of subwords is presented. On the other hand, an algorithm for computing the set of minimal forbidden subwords for a word is given. The case of a two-letter alphabet appears to be particularly interesting and it is considered separately. 相似文献
8.
Tatjana?PirmanEmail author Vekoslava?Stibilj 《European Food Research and Technology》2003,217(6):498-503
The fatty acid composition of three raw and cooked freeze-dried common bean varieties (Phaseolus vulgaris), namely enjevec, Semenarna 22 and Cipro, and of the lentil (Lens esculenta), var. Anicia, was determined and the influence of storage on their composition was studied. Analyses of fatty acid composition were conducted by in situ transesterification and capillary column gas-liquid chromatography. In raw milled beans average values of about 16% saturated fatty acids (SAT), 6% monosaturated fatty acids (MUFA) and 78% polyunsaturated fatty acids (PUFA) were found. Somewhat different values of 15% of SAT, 25% MUFA and 60% PUFA were found in lentil. In cooked beans the content of all fatty acids was slightly decreased. In cooked lentil the decrease was almost 50%, but the ratios of SAT, MUFA and PUFA in both cases were practically the same. After two years of storage at 4 °C the fatty acid content in raw milled beans was unchanged, but altered in cooked ones. The amounts of linoleic (18:2, n-6) and -linolenic (18:3, n-3) acid decreased, but myristic (14:0), margaric (17:0) and arachidic (20:0) acids increased. It was found that freeze-dried cooked beans, prepared from raw seed beans, kept 2.5 years at 10 °C, have practically the same fatty acid composition as freeze-dried cooked beans 0.5 year after harvesting. 相似文献
9.
Two different Ti/Pt–Ir materials (commercial and home made) and Ti/PdO + Co3O4 were investigated for their electrocatalytic properties versus Cl2 evolution reaction. The materials were used in a batch electrochemical reactor to treat biologically recalcitrant di-azo compound. An electrochemically driven oxidation, mediated by a Cl2/Cl− couple, proved efficient for destruction of this complex organic molecule, causing cleavage of the conjugated double bonds and destruction of unsatured bonds. Both Ti/Pt–Ir materials performed well; lower kinetics obtained with the Ti/PdO + Co3O4 anode was caused by adsorption of the model compound, evidenced in preliminary voltammetric measurements. The dye oxidation reaction followed the second order kinetics with partial orders in the model compound and (time varying) chlorine concentrations equal to one. Specific energy consumption of 3.12 kWh m−3 proved the process more economic than the homogeneous phase oxidation. 相似文献
10.
Marina M. Radišić Tatjana M. Vasiljević Nikolina N. Dujaković Mila D. Laušević 《Food Analytical Methods》2013,6(2):648-657
This study presents an application of rapid and sensitive multiresidue method for the analysis of acephate, acetamipride, atrazine, carbendazim, carbaryl, carbofuran, dimethoate, imidacloprid, linuron, malathion, monocrotophos, monuron, propazine, simazine, and tebufenozide in fruits. The method involves an extraction procedure based on matrix solid-phase dispersion using diatomaceous earth as a dispersant and dichloromethane as the eluent. The target pesticides were determined using liquid chromatography–ion trap mass spectrometry. Quantification of the analytes was carried out using the most sensitive ion transition. Ion trap parameters, like activation q and time, were found to have a prominent influence on method sensitivity for some pesticides and they were optimized accordingly. The confirmation of residues detected in real samples was performed by repeated injection and acquiring additional ion transitions besides the ones used for quantification. The method was validated for accuracy, linearity, reproducibility, and sensitivity. Mean values for recoveries were in the range of 70–120 % for all tested matrices. Repeatability of the method, expressed as the relative standard deviation, was in general lower than 20 %. The applicability of the method to routine analysis was tested in real fruit samples with good performance. 相似文献