Morphology development in polyethylene/polystyrene blends: the influence of processing conditions and interfacial modification

The influence of processing conditions and interfacial modification on the morphology evolution and the composition range within which fully co‐continuous high density polyethylene/polystyrene blend structures can exist during blending in a single screw extruder was studied. Blends ranging from pure A to pure B component, with and without compatibilizer, were prepared under two different shear rates. It was found that high shear rates displaced the breakdown–coalescence balance of the dispersed nodules to the side of coalescence, narrowing the percolation domain and the critical composition for full co‐continuity decreased with increasing shear rates. The addition of a tri‐block compatibilizer induced the percolation threshold of the polystyrene phase to begin at lower percentages of polyethylene but the phase inversion point did not change. The experimental results are discussed in the light of various theoretical models. Copyright © 2005 Society of Chemical Industry     

Thermal Analysis of Non-linear Convective–Radiative Hyperbolic Lumped Systems with Simultaneous Variation of Temperature-Dependent Specific Heat and Surface Emissivity by MsDTM and BPES

With the advent of temperatures near absolute zero, it is often claimed that at very low temperatures the effect of thermal wave propagation must be included by the hyperbolic heat conduction equation (HHCE). In this paper the non-linear convective–radiative HHCE is investigated. Opposite to common numerical analyses, analytical expressions are obtained for the temperature variations by the multi-step differential transformation method. Some conclusions about alteration of the specific heat of the material, temperature steeping, and Vernotte number have been formulated.     

Study of planar structure applying reciprocity technique combined with MGEC and analysis of discontinuity

The 3D structure electromagnetic computation presents several difficulties related to the volume mesh. In fact, the entire volume space must be taken into account even the smallest details. In this article, we propose a formulation based on the reciprocity theorem combined with the generalized equivalent circuit method to model a planar 3D structure with both coaxial and planar excitation. The major advantage of this formulation is the fact to reduce the computational volume into 2D ones in the discontinuity plane. In addition, we focused on the calculation of the discontinuity between the excitation source and the planar structure to determine the exact behavior of the electric coaxial excitation model. The obtained current density, electric field distributions, and the input impedance are presented and discussed in the following sections. An approximately good agreement of input impedance with those obtained by the simulator and measurement is shown.     

Investigation of the thermal behavior effect of the surrounding material environment on the swirling flame structure

This paper is focusing on the numerical simulation of a swirling flame, resulting from the interaction of multiple fires, evolving in a free and unlimited environment. A typical system, formed by a central fire source surrounded by four heat sources, is used. Since the thermal characteristic of the surrounding sources is the main engine for the rotation of flame, a detailed study is performed by varying the heating flux of these sources. This study shows that an increase of the heating flux of surrounding sources has as a result an intensification of the penetrating air puffs through the openings between the surrounding four heat sources. These puffs tangentially drive the central flame, thus producing a marked improvement on the angular momentum. Moreover, this study shows that the flame height is strongly affected by the flame rotation. Moreover, two different aspects of the flame height evolution are observed from the flow visualization and the thermal and dynamic fields for the different cases studied.     

Characterizations of friction welding joint interface for AISI 316

Because of heat amount is different from peripheral to central of friction welding interface, which is leaded to vary the characterizations along that interface. Current study, respectively, focused on the effect of different friction pressure on micro-structural and mechanical properties of that friction welding joint interface. Presently, these friction pressures are 110, 130, 150 and 170 MPa while kept all other conditions constant. The effects of different friction pressure on welding interface characterization were investigated by EDX, SEM, tensile, compression, impact and hardness tests. The tensile tests carried out on the standardized test piece with diameter 6 mm and 8 mm, thus, compression tests were extracted from the positions of 0°, 45° 90° with test specimen of 4 mm diameter and 6.5 mm length at weld center. Whereas, the impact test pieces were picked up in two positions, the first one is symmetrical, which it obtained to the respect of the rotation axis and the interface, on the other hand, the second one is non-symmetrical with the axis of rotation and symmetrical to the interface, for making the notch head coincide with the center of the welded joint, The obtained results showed that with reducing of friction pressure will present lack of bonding increasing from peripheral toward the welding center, which will responsible on reducing of the mechanical properties such as tensile, compression and impact strength.     

Dispersed phase morphology and fractionated crystallization of high-density polyethylene in PET/HDPE blends

The fractionated crystallization of high density polyethylene dispersed in a poly(ethylene terephthalate) matrix at composition of 15 wt-% was studied. The effect of the molecular weight of polyethylene with and without compatibilization was particularly addressed regarding its influence on the morphology of the blends. For non-compatibilized blends, the dramatic influence of the molecular weight of the polyethylene on the viscosity ratio and therefore on the dispersion is reflected on the relative intensities of the twin crystallization peaks of polyethylene that are developed upon cooling. These peaks reflect two sets of particles that are nucleated by more or less active heterogeneities. The influence of the addition of an ethylene-glycidyl methacrylate copolymer on the morphology and on the crystallization of the blends was also investigated. For a high molecular weight polyethylene, the compatibilizer shows less efficiency as far as dispersion is concerned.     

Estimating the Long-Memory Parameter in Nonstationary Processes Using Wavelets

In this article, we propose two new semiparametric estimators in the wavelet domain in order to estimate the parameter of nonstationary long memory models. Compared to the Fourier transform, the advantage of the wavelet approach to analyze the behavior of nonstationary time series is that it can localize a process simultaneously in time and scale. We thus develop a Wavelet Exact Local Whittle estimator and a Wavelet Feasible Exact Local Whittle estimator, which extend the estimators of Phillips and Shimotsu (Ann Stat 32(2):656–692, 2004), Shimotsu and Phillips (Ann Stat 33(4):1890–1933, 2005; J Econom 130:209–233, 2006) and Shimotsu (Econom Theory 26(2):501–540, 2010) into the wavelet domain. Simulation experiments show that the new estimators perform better under most situations in the stationary and nonstationary cases. We also applied these two new semiparametric estimators to some financial series (daily stock market indices and exchange rates).     

Modelling of axis feed consumed energy for sustainable manufacturing

The accurate evaluation of electrical energy demanded by a CNC toolpath during a machining process is essential to determine its efficiency. Actually, the dynamic behavior of cutting forces seems to be neglected by investigators despite its influence on the consumed cutting energy during a face milling operation. This paper aims to investigate the effect of dynamic behavior of the machining system in order to take into account the dynamic response of the cutting forces on the axis feed power prediction. A dynamic cutting power model is developed in order to predict the consumed cutting energy. A parametric study is performed in order to show the impact of cutting conditions on the consumed energy values. The numerical results are compared to experimental ones.     

Fatty acids,sterols, and tocopherols composition in seed oil extracts from four moroccan ecotypes of Ceratonia siliqua L.

Morphological characterization was investigated by agro-morphological criteria related to carob seed size in four different moroccan regions collected in 2018 and 2019. There was no significant difference (p ≤ 0.05) on the seeds lengths and widths. However, a significant difference between seeds thickness and total seeds weight per pod (p ≤ 0.05) were observed between these four populations. The fatty acid, sterol, tocopherol, hydrocarbon, and the unoxygenated composition of carob seed extracts (Ceratonia siliqua L.) were studied. The mean fat yield of the seeds obtained is 1.53%–2.17%, 2.14%–2.15%, 1.61%–1.62%, 1.71%–1.75% for, respectively, the P1 (Meknes), P2 (Fez), P3 (Khemisset), and P4 (Marrakech) in 2018 and 2019. The seed oil was extracted with hexane and the analysis of the fatty fraction was performed by gas chromatography–mass spectrometry (GC–MS). Results show that the major fatty acids for 2018 and 2019 are linoleic acid (61.48%–61.52%, 52.12%–52.14%, 57.76%–58.15%, 61.33%–61.52%), palmitic acid (15.78%–15.81%, 16.44%–16.45%, 19.11%–18.37%, 20.24%–20.32%), oleic acid (11.03%–11.04%, 8.72%–8.82%, 8.51%–8.61%, 8.41%–8.53%), stearic acid (4.35%–3.14%, 5.40%–5.43%, 3.12%–3.13%, 0.96%–1.56%), and cerotic acid (0.62%–0.53%, 4.51%–4.52%, 4.03%–4.06%, 3.84%–3.87%). The unsaturated fatty acids (69.39% in 2018 and 69.68% in 2019) are the most dominant in the four seed extracts compared to the saturated fatty acids. In addition, the oil carob seeds analysis revealed the presence of γ-tocopherol, α-tocopherol and four sterols that included campesterol, stigmasterol, and β-sitosterol. Moreover, the determination of hydrocarbon and un-oxygenated compounds confirmed the existence of major compounds such as heptadecane, 2-methyltriacontane, 1-iodo hexadecane and 1-iodo octadecane. The hierarchical analysis based on the morphological and chromatographic characterization of the seeds allowed the identification of three groups. Consequently, the first group consisted of populations from Marrakesh (P4) and Khemisset (P3), the second group consisted of the P1 from Meknes, and the P2 from Fez constituted the third group.     

Discrimination des modes pour l’étude des discontinuités dans les circuits planaires

The study of the dispersion phenomena of a planar transmission line in boxed structure is very intricate. In this paper we will try to determine the origin of the different modes by varying the geometrical parameters of the structure at a given frequency. We will also study the complex modes and their effects on thee characterisation of the planar discontinuities.