Analysis and comparison of machine learning classifiers and deep neural networks techniques for recognition of Farsi handwritten digits

The Journal of Supercomputing - Handwriting recognition remains a challenge in the machine vision field, especially in optical character recognition (OCR). The OCR has various applications such as...     

Modification of glassy carbon electrode with multi-walled carbon nanotubes and iron(III)-porphyrin film: Application to chlorate, bromate and iodate detection

In this study, multi-wall carbon nanotubes (MWCTs) is evaluated as a transducer, stabilizer and immobilization matrix for the construction of amperometric sensor based on iron-porphyrin. 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride (Fe(III)P) adsorbed on MWCNTs immobilized on the surface of glassy carbon electrode. Cyclic voltammograms of the Fe(III)P-incorporated-MWCNTs indicate a pair of well-defined and nearly reversible redox couple with surface confined characteristics at wide pH range (2-12). The surface coverage (Γ) and charge transfer rate constant (k_s) of Fe(III)P immobilized on MWCNTs were 7.68 × 10⁻⁹ mol cm⁻² and 1.8 s⁻¹, respectively, indicating high loading ability of MWCNTs for Fe(III)P and great facilitation of the electron transfer between Fe(III)P and carbon nanotubes immobilized on the electrode surface. Modified electrodes exhibit excellent electrocatalytic activity toward reduction of ClO₃⁻, IO₃⁻ and BrO₃⁻ in acidic solutions. The catalytic rate constants for catalytic reduction of bromate, chlorate and iodate were 6.8 × 10³, 7.4 × 10³ and 4.8 × 10² M⁻¹ s⁻¹, respectively. The hydrodynamic amperometry of rotating-modified electrode at constant potential versus reference electrode was used for detection of bromate, chlorate and iodate. The detection limit, linear calibration range and sensitivity for chlorate, bromate and iodate detections were 0.5 μM, 2 μM to 1 mM, 8.4 nA/μM, 0.6 μM, 2 μM to 0.15 mM, 11 nA/μM, and 2.5 μM, 10 μM to 4 mM and 1.5 nA/μM, respectively. Excellent electrochemical reversibility of the redox couple, good reproducibility, high stability, low detection limit, long life time, fast amperometric response time, wide linear concentration range, technical simplicity and possibility of rapid preparation are great advantages of this sensor. The obtained results show promising practical application of the Fe(III)P-MWCNTs-modified electrode as an amperometric sensor for chlorate, iodate and bromate detections.     

Noisy metrology: a saturable lower bound on quantum Fisher information

Quantum Information Processing - We present a general problem of quantum entanglement quantified by von Neumann entropy for N-level atomic system. Time evolution of state vector of the entire...     

Flow resistance in a compound gravel-bed bend

In this paper, the effect of a gravel-bed in a compound bend (similar to sinusoidal top view) of a natural river (Zayandehrud River flowing through Isfahan, Iran) has been investigated for flow resistance analysis, measuring the velocity with a micro current meter. The data were analysed and the following observations were made. In a compound bend, the law of the wall can be valid for up to 66% of the flow depth from the bed. The parabolic law is the most effective method for the determination of shear velocity. Based on the existing criteria for verifying the equilibrium boundary layer, the flow cannot be in equilibrium. The shear stress distribution and the sediment transport parameters have considerable influence on resistance to flow. Froude number and the flow depth relative to the representative gravel size have little effect on the flow resistance estimation.     

A new FMEA method by integrating fuzzy belief structure and TOPSIS to improve risk evaluation process

Failure mode and effect analysis (FMEA) model is a technique used to evaluate the risk. This paper aimed to propose a new FMEA model combining technique for order of preference by similarity to ideal solution (TOPSIS) and belief structure to overcome the shortcomings of the traditional index of FMEA. In this paper, the fuzzy belief TOPSIS method is combined with FMEA to introduce a belief structure FMEA to describe the expert knowledge by a number of linguists as a grammatical phenomenon. Moreover, the weights of components in FMEA index can be different from each other. Therefore, the flexibility of assigning weight to each factor in this method is more compatible to the real decision-making situation. In other word, TOPSIS method is applied to determine the preference of alternatives versus risk criteria. Using linguistic terms in the fuzzy belief approach, the risk factors described a more meaningful value and decision-makers’ judgment is assigned with belief degrees through evaluation of factors. Finally, a numerical case study about the preference of cause failures of steel production process is provided to illustrate the process of proposed method, and then result and discussion is performed for each case.     

Hydrogen peroxide sensor based on riboflavin immobilized at the nickel oxide nanoparticle-modified glassy carbon electrode

A simple and sensitive electrochemical sensor based on nickel oxide nanoparticles/riboflavin-modified glassy carbon (NiONPs/RF/GC) electrode was constructed and utilized to determine H₂O₂. By immersing the NiONPs/GC-modified electrode into riboflavin (RF) solution for a short period of time (5–300 s), a thin film of the proposed molecule was immobilized onto the electrode surface. The modified electrode showed stable and a well-defined redox couples at a wide pH range (2–10), with surface-confined characteristics. Experimental results revealed that RF was adsorbed on the surface of NiONPs, and in comparison with usual methods for the immobilization of RF, such as electropolymerization, the electrochemical reversibility and stability of this modified electrode has been improved. The surface coverage and heterogeneous electron transfer rate constants (k _s) of RF immobilized on a NiO _x –GC electrode were approximately 4.83 × 10^?11 mol cm^?2, 54 s^?1, respectively. The sensor exhibits a powerful electrocatalytic activity for the reduction of H₂O₂. The detection limit, sensitivity and catalytic rate constant (k _cat) of the modified electrode toward H₂O₂ were 85 nM, 24 nA μM^?1 and 7.3 (±0.2) × 10³ M^?1 s^?1, respectively, at linear concentration rang up to 3.0 mM. The reproducibility of the sensor was investigated in 10 μM H₂O₂ by amperometry, the value obtained being 2.5 % (n = 10). Furthermore, the fabricated H₂O₂ chemical sensor exhibited an excellent stability, remarkable catalytic activity and reproducibility.     

Synthesis of modified catalyst and stabilization of CuO/NH4‐ZSM‐5 for conversion of methanol to gasoline

In this article, the catalytic conversion of methanol to gasoline range hydrocarbons has been studied over CuO/ NH₄‐ZSM‐5(3,5,7,9%) catalysts prepared via sono‐chemistry methods. In order to improve, copper oxide can be used as a booster on NH₄‐ZSM‐5 this catalyst property. Accordingly, the conversion process of Methanol to Gasoline (MTG) was conducted under a pressure of 1 atm and temperature of 400°C by a fixed‐bed reactor on copper oxide catalysts which were prepared based on synthetic NH₄‐ZSM‐5. The synthetic catalyst was investigated by such analyses as BET, XRD, FT‐IR, and SEM. Formation of copper oxide phase and proper distribution of copper oxide were proven on the basic level of using XRD analysis. BET analysis showed the reduction in catalyst level and SEM images depicted the proper distribution of particles. The present investigation is to study the effect of CuO loading on NH4‐ZSM‐5 support for conversion of methanol to gasoline range hydrocarbons. A series of CuO/ NH4‐ZSM‐5 catalysts were prepared, characterized, and experimented for their performance on methanol conversion and hydrocarbon yield.     

Perfect state transfer via quantum probability theory

The transfer of quantum states plays an important role in quantum information processing. In fact, the transfer of a quantum state from point A to point B with unit fidelity has been the center of attention during the last decades. One of the ways to aim this goal is to transfer a quantum state in a spin chain described by designing a Hamiltonian in which a mirror symmetry with respect to the network center is created. In this paper, we introduce a method based on the spectral distribution of the adjacency matrix and stratifying a spin network, with respect to an arbitrary vertex denoted by o which is called starting vertex (reference vertex), to make perfect quantum state transfer possible between antipodes in the spin network. Then we design the coupling coefficients in a way to create a mirror symmetry in the Hamiltonian with respect to the center of the network. In this method the initial state is encoded on the starting vertex and then it is received at its antipode. There is no need to consider any external control in this approach.     

Ce3+-doped LaF3 nanoparticles: Wet-chemical synthesis and photo-physical characteristics “optical properties of LaF3:Ce nanomaterials”

The most effective process parameters were determined to synthesize spherical LaF₃ nanoparticles with controllable size based on ethylenediaminetetraacetic acid (EDTA) via co-precipitation technique. Thermogravimetricdifferential thermal analysis, X-ray diffraction, scanning electron microscopy, dynamic light scattering and FT-IR spectroscopy were used to characterize the resulting powders. Detailed investigations revealed that the optimal LaF₃ host nano-material was obtained when NH₄F was used as a fluoride source in the presence of EDTA at pH = 5. Furthermore, photoluminescence spectra showed an intense double emission peak at 289 and 302 nm for cerium-doped LaF₃ nanocrystals excited at 253 nm, which was assigned to the well-known 5d→4f (²F_5/2 and ²F_7/2) transitions of Ce³⁺ levels due to luminescence center mechanism. The experimental results indicate that the synthesized LaF₃:0.05Ce powders with a band gap of 5.3 eV are promising phosphors for high density scintillators.     

Synthesis and architecture study of a reactive polybutadiene polyamine as a toughening agent for epoxy resin

In this study, a novel reactive toughener for the epoxy resin was developed and compared with traditional hydroxyl‐terminated polybutadiene (HTPB). For this purpose, the highly reactive aliphatic amine‐terminated polybutadiene (ATPB) was synthesized at ambient conditions by nucleophilic substitution amination. The characterizations of the product were provided by Fourier transform infrared and ¹H NMR spectroscopy. According to the mechanical test results, incorporation of ATPB into epoxy networks can significantly toughen the epoxy matrix. The addition of 10 phr ATPB increased the critical stress intensity factor (K_IC) and critical strain energy release rate (G_IC) of the epoxy from 0.85 to 2.16 MPa m^1/2 and from 0.38 to 3.02 kJ m^?2, respectively. Furthermore, unlike HTPB, the presence of the ATPB did not deteriorate the tensile strength of the matrix. The toughening and failure mechanisms were discussed based on the epoxy network morphological characteristics. The reduction in cross‐linking density and glass transition temperature of the epoxy system upon modification with liquid rubbers was confirmed by dynamic mechanical analysis. This article opens up the possibility of utilizing reactive flexible diamines with polybutadiene backbone as effective toughening agents for thermoset polymers. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44061.