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1.
Crystal phase transition between the low- and high-temperature phases has been investigated for ethylene (E)-tetrafluoroethylene (TFE) alternating copolymer (ETFE) containing the third monomeric species by the temperature dependent measurements of wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) and differential scanning calorimetry. Nonafluoro-1-hexene (NFH) and hexafluoropropylene (HFP) were chosen as the third monomers, where they are different in the side-branch length, -(CF2)3CF3 and -CF3, respectively. In the case of E/TFE/NFH copolymer (ET-C4F9), the crystal phase transition temperature of the original ETFE two-components copolymer was not very much affected by the existence of NFH in the range of NFH content from 0.7 to 3 mol%. Contrarily, the crystal phase transition temperature of E/TFE/HFP copolymer (ET-CF3) was found to decrease drastically with increasing HFP content. The melting temperature and the higher-order structure were also affected sensitively depending on the HFP content. This difference in phase transition behavior between ET-C4F9 and ET-CF3 copolymers is reasonably interpreted as follows: the short side groups (-CF3) of HFP monomeric unit are included in the crystal lattice of E/TFE chains and the unit cell is expanded gradually with an increment of the HFP content, resulting in the decrease in phase transition point because of easier thermal motion of the chains. On the other hand, the long side groups [-(CF2)3CF3] of NFH monomeric units are excluded out of the crystal lattice and located on the lamellar surfaces or in the amorphous region and do not affect very much the phase transition temperature even when the NFH content is increased. In association with such a change in crystal structure, the long period of stacked lamellar structure was found to decrease remarkably in the case of NFH, whereas it does not change very much for HFP, consistent with the interpretation of the above-mentioned WAXD data. 相似文献
2.
Ji‐Sun Im Ju‐Hyung Lee Seung‐Kook An Ki‐Won Song Nam‐Ju Jo Jang‐Oo Lee Kohji Yoshinaga 《应用聚合物科学杂志》2006,100(3):2053-2061
A new type of polyimide/silica (PI/SiO2) hybrid composite films was prepared by blending polymer‐modified colloidal silica with the semiflexible polyimide. Polyimide was solution‐imidized at higher temperature than the glass transition temperature (Tg) using 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA) and 4,4′‐diaminodiphenyl ether (ODA). The morphological observation on the prepared hybrid films by scanning electron microscopy (SEM) pointed to the existence of miscible organic–inorganic phase, which resulted in improved mechanical properties compared with pure PI. The incorporation of the silica structures in the PI matrix also increased both Tg and thermal stability of the resulting films. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2053–2061, 2006 相似文献
3.
Atsuyoshi Nishina Kohji Kubota Hiromu Kameoka Toshihiko Osawa 《Journal of the American Oil Chemists' Society》1991,68(10):735-739
A substance with antioxidant properties was obtained from the hexane extract of roots ofRumex japonicus Houtt. The active component of the hexane extract was isolated and characterized as 2-acetyl-1,8-dihydroxy-3-methyl naphthalene,
trivially named musizin (MUS). The antioxidant activities of MUS in six types of fats and oils were higher than that of butyl
hydroxyanisole (BHA) and δ-tocopherol (δ-TOC). Together, TOC and MUS have a synergistic effect, because comparable amounts
of either had lower antioxidant activity than various combinations of the two antioxidants. When we studied the antioxidant
properties of a mixture of MUS and δ-TOC with methyl linoleate (MeLH), we found that the rates of destruction of the two antioxidants
were comparable, but that their destruction occurred sequentially, with MUS first followed by δ-TOC, after which the oxidation
of MeLH quickly occurred. Comparison of the antioxidant activity of MUS and its analogs suggests that only one of the two
hydroxyl groups in MUS is involved in its antioxidant activit. Intermolecular hydrogen bonding may be involved. 相似文献
4.
The tungsten-inert-gas (TIG) arc welding experiments of cemented carbide YG30 and steel 45 were carried out using the Ni-Fe-C filling alloys. The eta phases and mechanical properties of welded joints were analyzed by means of scanning electronic microscope (SEM) , transmission electronic microscope (TEM) coupled with selected diffraction, electronic probe microanalysis and bending strength method. The experimental results show that the chemical composition of the filling alloys affects eta phase formation. When the carbon and nickel contents in filling alloys are O. 61 wt% and 55. 29 wt% ,respectively, no eta phases form. And the joint bending strength is the highest to 1. 352 GPa. But if they are O. 01wt% and 55.38wt%, the eta phases are formed at the boundaries of the cemented carbide and the weld, and the thickness of eta phase layer is about 110 micrometers. And the joint bending strength is low. Usually, these eta phases are anomalously granular,and easy to accumulate at the boundaries between cemented carbides and the weld. They are multiple M6C rich in tungsten and iron. 相似文献
5.
Ichiro Kawahata David I. Finkelstein Kohji Fukunaga 《International journal of molecular sciences》2022,23(11)
α-Synuclein is a protein with a molecular weight of 14.5 kDa and consists of 140 amino acids encoded by the SNCA gene. Missense mutations and gene duplications in the SNCA gene cause hereditary Parkinson’s disease. Highly phosphorylated and abnormally aggregated α-synuclein is a major component of Lewy bodies found in neuronal cells of patients with sporadic Parkinson’s disease, dementia with Lewy bodies, and glial cytoplasmic inclusion bodies in oligodendrocytes with multiple system atrophy. Aggregated α-synuclein is cytotoxic and plays a central role in the pathogenesis of the above-mentioned synucleinopathies. In a healthy brain, most α-synuclein is unphosphorylated; however, more than 90% of abnormally aggregated α-synuclein in Lewy bodies of patients with Parkinson’s disease is phosphorylated at Ser129, which is presumed to be of pathological significance. Several kinases catalyze Ser129 phosphorylation, but the role of phosphorylation enzymes in disease pathogenesis and their relationship to cellular toxicity from phosphorylation are not fully understood in α-synucleinopathy. Consequently, this review focuses on the pathogenic impact of α-synuclein phosphorylation and its kinases during the neurodegeneration process in α-synucleinopathy. 相似文献
6.
Recently, many channelized rivers tend to be heavily vegetated due to regime shifts in hydrological, fluvial and ecological processes. Dense vegetation in a river frequently obstructs a flood flow and reduces conveyance capacity of channels. On the other hand, river vegetation provides various ecological services such as habitats for various species and life, natural cycle of organic and inorganic substances, etc.. It is of engineering importance to understand vegetation hydrodynamics in order to preserve vegetation nature and keep a certain level of flow conveyance capacity. In view that willows tend to be densely vegetated along the shoreline of floodplains or sandbars, a field measurement, a physical model experiment and a numerical analysis were carried out for investigating hydrodynamics in an open channel with riparian vegetation. Discussion was made focusing on flow and shear layer structures developed around the vegetation canopy. 相似文献
7.
Back Cover: Tailored Synthesis of 162‐Residue S‐Monoglycosylated GM2‐Activator Protein (GM2AP) Analogues that Allows Facile Access to a Protein Library (ChemBioChem 20/2016) 下载免费PDF全文
8.
Kohji Ishida Kazuyuki Shimizu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1996,66(4):340-346
A novel repeated batch operation mode was proposed for ethanol fermentation, where the fermenter beer was periodically exchanged between the fermenter with biomass recycle and the distillation unit, to promote the selective removal of ethanol. Using the mathematical model developed, as based on the experimental results, the optimal operation of the proposed method was shown to attain high performance, with a productivity of about 12 g dm−3 h−1 and a product concentration of 400 g dm−3. 相似文献
9.
10.
Frictional anisotropy of oblique Ti nanocolumns grown by glancing angle deposition (GLAD) was investigated by ramp-scratch
experiments in forward (in the direction of the column tilt) and reverse (against the column tilt) directions using rectangular
and conical loading tips. Strong anisotropy in friction was generally observed, wherein the resistance or friction coefficient
in reverse scratching was higher than that in forward scratching, and the reverse resistance was sensitive to the tip shape.
In forward scratching, the nanocolumns bend with the column tilt direction, designated as the W-mode deformation. On the other
hand, in reverse scratching, the nanocolumns deflect against the column tilt in high normal force, designated as the A-mode
deformation. The deformation mode changes from the W-mode to the A-mode as the normal force increases in reverse scratching.
The mechanism of the frictional anisotropy was discussed on the basis of a simple deformation model of column by finite element
method. The anisotropy can be explained by the difference in the deformation mode. That is, compressive deformation in the
longitudinal direction and large deflection against the column tilt induce higher friction resistance in reverse scratching
than in forward scratching brought about by compliant bending deformation with the column tilt. 相似文献