Synthesis of heterocyclic metal complexes and their evaluation as marine antifoulants

4-Amino-3-thio-1,24-triazolidine (L₁) and 4-amino-5-thio-1,3,4-thiadiazole (L_II) as well as their metal complexes of the general formulae ML_I·2H₂O and ML_IICl (M; Pb(II), Cd(II) and Zn(II)) were prepared. With Sn(II), we obtained Sn(L_I)₂·2H₂O and SnL_IICl, respectively. The structures of the compounds were identified through elemental analysis, and IR and UV spectra measurements, in addition to thermal analysis in case of the metal complexes. The antifouling properties of the compounds were tested by their incorporation into paint formulations which were applied to PVC substrates and tested in water from Alexandria western harbour. When the compounds were added at 17·5% by volume, the coated panels were fouled after 3 months of immersion. The addition of 6·7% by volume of tributyltin oxide to 15·8% of the prepared compounds in one formulation elevated the paint efficiency and prevented fouling for 11 months. Paint containing solely tributyltin oxide at the same concentration was inactive against algae.     

On the determination of boundaries to manipulator workspaces

The accumulation of two independent, broadly applicable formulations for determining the boundary to manipulator workspaces, presented elsewhere, are compared in this paper. Insights gained from one method are used to explain behavior exhibited in the other. Results are also compared and validated. A numerical formulation based on continuation methods is used to map curves that are on the boundary of a manipulator workspace. Analytical criteria based on row rank deficiency criteria of the manipulator's analytical Jacobian are used to map a family of one-dimensional solution curves on the boundary. The other formulation, based on a similar rank-deficiency criteria, yields analytic boundaries parametrized in terms of surface patches on the boundary. Results concerning the applicability of the numerical method to open- and closed-loop systems are compared with those limited to the open-loop for the analytical method. Conclusions regarding the behavior of the manipulator on geometric entities characterized by singular curves, higher-order bifurcation points, and surfaces inside the workspace are drawn. Applicability of both methods and their limitations are also addressed.     

Sediment Concentration and Its Prediction by Perceptron Kalman Filtering Procedure

Predictions of the discharge and the associated sediment concentration are very useful ingredients in any water resources reservoir design, planning, maintenance, and operation. Although there are many empirical relationships between the discharge and sediment concentration amounts, they need estimation of model parameters. Generally, parameter estimations are achieved through the regression method (RM), which has several restrictive assumptions. Such models are locally valid and their structures and parameter values are questionable from region to others. This paper proposes a new approach for sediment concentration prediction provided that there are measurements of discharge and sediment concentration. The basis of the methodology is a dynamic transitional model between successive time instances based on two variables, namely, discharge and sediment concentration measurements. The transition matrix elements are estimated from the measurements through a special form of the artificial neural networks as perceptrons. The sediment concentration predictions from discharge measurements are achieved through a perceptron Kalman filtering (PKF) technique. In the meantime, this technique also provides temporal predictions. A certain portion of the measurement sequence is employed for the model parameter estimations through training and the remaining part is used for the model verification. Detailed comparisons between RM and PKF approaches are presented and, finally, it is shown that the latter model works dynamically by simulating the observation scatter diagram in the best possible manner with smaller prediction errors. The application of the methodology is performed for the discharge and sediment concentration measurements obtained from the Mississippi River basin at St. Louis, Missouri. It is found that the PKF methodology has smaller average relative, root-mean-square, and absolute errors than RM. Furthermore, graphical representation, such as the scatter and frequency diagrams, indicated that the PKF approach has superiority over the RM.     

Electroplating of nickel-cadmium alloys from alkaline solutions

The electroplating of Ni-Cd alloy coatings was carried out from alkaline baths (pH 10). For comparison, electroplating of the parent metals, Ni and Cd, was performed individually under the same conditions. The cathodic current efficiency for codeposition was high and decreased with increasing current density. The codeposition process is an anomalous type of plating with Cd being the preferentially deposited metal. The Ni content in the deposits increased with increasing current density. This increase in Ni content improves the corrosion resistance and microhardness of the deposits. X-ray diffraction analysis showed that the deposits consist of a mixture of Ni, β, γ, γ¹ phases.     

Analysis of real-time properties and rules for setting protocol parameters of MAP networks

This paper reports on an evaluation of real-time properties of MAP (Manufacturing Automation Protocol) networks by analytical considerations and measurements. Based on a model of the time schedule of a communication cycle figures for response times (transport system) and message delays (MAC layer) are given. The influence of some options for handling acknowledgments within the transport layer is shown. The message delay at MAC layer is separated into an implementation-dependent and a protocol-dependent protion, and an upper bound is derived. Rules for selecting protocol parameters affecting real time behavior are given. Aspects for improved implementations of communication controllers for MAP networks are discussed.     

Electrical properties of tri-n-butyl tin acrylate-methylmethacrylate copolymers

The copolymerization of tri-n-butyl tin acrylate (TBTA) with methylmethacrylate (MMA) has been investigated in dioxane. The composition of these copolymers was determined quantitatively by ¹H nuclear magnetic resonance (NMR) spectroscopy. The tin contents were estimated by gravimetric as well as thermogravimetric techniques (TGA). The reactivity ratio of such copolymers was estimated by application of the Kelen-Tudos method. The dielectric properties of the copolymers have been studied over a frequency range of 100–50 kHz at different temperatures from 20 to 70°C. The electrical conductivity for such copolymers was also measured. The results are interpreted in terms of the tin content of the copolymers.     

The sinuous antenna-A dual polarized feed for reflector-based searching systems

The sinuous antennas have a numerous applications in military and civil systems such as direction finding systems and reflector feeds due to their superior broadband characteristics and simultaneous polarization capability. In this paper, design, construction and measurements of planar sinuous antennas are investigated for 1–5 GHz frequency range. Feeding sections of this antenna are realized by using microstrip tapered baluns. We have determined the microstrip tapered balun dimensions using Ansoft HFSS-simulation program. The performances of the manufactured antenna are measured using HP vector network analyzer. Polarization patterns and return loss characteristics of the designed antenna that have been measured in anechoic chamber, are presented.     

Vibration and damping analysis of beams with composite coats

Numerical and experimental investigations of the dynamic behavior for coated laminate composite beams has been presented and discussed in the present work. A numerical technique is utilized to compute the eigen parameters of coated laminated composite beams. An attempt to study the variations in the natural frequencies and damping properties of laminated composite coated beams taking into account different lamina orientation of coat and various kinds of core isotropic material (steel and aluminium) is introduced. The variations of the eigen parameters vs. the code number of the coated layer with the use of various types of isotropic material are measured by utilizing (the frequency response displayed on) an (FFT) analyzer. The experimental and numerical work is carried out on four different fiber orientations, aligned longitudinally, transversely, making 45 ° with the fibers direction and randomly oriented. Comparison between experimental and numerical results shows a tight connection between them.     

Water and salt permeability of reinforcement polymer‐gel composite membrane

The charged mosaic polymer membrane (CMM) without reinforcement and the composite charged mosaic polymer membrane (CCMM) with reinforcement were investigated in terms of salt and water transport (permeability). The composite charged mosaic polymer membrane (CCMM) with reinforcement showed a unique transport behavior such as preferential material transport L_p and ω. Water permeability coefficient, L_p and salt permeability coefficient, ω were estimated by taking account of active layer thickness of composite polymer gel. The L_p and ω values of CCMM with reinforcement were larger than those of CMM without reinforcement. On the other hand, the reflection coefficient of CCMM, σ, showed negative value, which suggested preferential material transport to solvent transport. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Improvement of the engineering properties of asphalt pavements using a ‘soft’ compaction technique (AMIR-Compaction)

In most countries of the world asphalt pavement of road networks represents the biggest single investment in the transportation system. In Canada, asphalt pavement built over the past decade is worth more than 70 billion dollars (in 1984 dollars). In order to maintain the current road network at the present level of service and prevent it from further deterioration, over 6 billion dollars is needed anually.

Traditionally, asphalt overlays are widely used to rehabilitate existing deteriorated pavements. Unfortunately the new overlays have been observed to fail in a relatively short time. Thus the investment in overlays is lost.

Recent research based on the concept of relative rigidity has indicated that the rapid deterioration of new asphalt overlays is directly related to current construction equipment. It has been shown analytically and experimentally that steel rollers used in compacting the asphalt layer will result in surface cracks during construction. Traffic and environmental influences will accelerate the failure of the new layer.

This paper presents the results of a testing programme evaluating the engineering properties of asphalt slabs compacted by a new method using a compactor termed AMIR. The results showed that the AMIR compactor will prevent the formation of constitution cracks resulting in an increase of indirect tensile strength of 10% and an increase of direct tensile strength of up to 60% when compared to steel roller compacted asphalt slabs.