Diluted chemical bath deposition of CdZnS as prospective buffer layer in CIGS solar cell

In this study, dilute chemical bath deposition technique has been used to deposit CdZnS thin films on soda-lime glass substrates. The structural, morphological, optoelectronic properties of as-grown films have been investigated as a function of different Zn²⁺ precursor concentrations. The X-ray diffractogram of CdS thin-film reveals a peak corresponding to (002) plane with wurtzite structure, and the peak shift has been observed with the increase of the Zn²⁺ concentration upon formation of CdZnS thin film. From morphological studies, it has been revealed that the diluted chemical bath deposition technique provides homogeneous distribution of film on the substrate even at a lower concentration of Zn²⁺. Optical characterization has shown that the transparency of the film is influenced by Zn²⁺ concentration and when the Zn²⁺ concentration is varied from 0 M to 0.0256 M, bandgap values of resulting films range from 2.42 eV to 3.90 eV while. Furthermore, electrical properties have shown that with increasing zinc concentration the resistivity of the film increases. Finally, numerical simulation validates and suggests that CdZnS buffer layer with composition of 0.0032 M Zn²⁺ concentration would be a promising candidate in CIGS solar cell.     

The availability of daylight from tropical skies—a case study of Malaysia

In Malaysia, no long-term daylight data are measured. It was only recently that the need to measure the availability of daylight became urgent when the importance of daylighting in buildings was rediscovered. The hourly daylight availability has been simulated for the Malaysian sky using daylight modelling techniques based on empirical and measured solar irradiation and cloud cover data. This paper presents the techniques involved in producing exterior illuminance data. These data were then compared with measured illuminance at Shah Alam and Bangi, Malaysia. The global illuminance levels are generally high, with values exceeding 80,000 lux at noon during the months when solar irradiation is highest. Even during the months when the ground receives less solar irradiation, the peak illuminance can reach 60,000 lux. Applications and uses of such data are in daylighting design, both for visual and thermal comfort, task illuminance and energy-conscious design of buildings. Recommendations are made at the end of the paper on the various climatic data that are required to be measured for overall daylighting design applications.     

Review of windcatcher technologies

Mechanical cooling systems in buildings are the main producers of carbon dioxide emissions, which have negative impacts on environment and amplify global warming, particularly in hot climate. Due to the lack of energy supply, windcatchers can be utilized as a sustainable attempt for cooling and ventilation purposes. The objective of this paper is to review and provide a comprehensive literature on windcatcher system for space cooling and ventilation. The concepts were discussed according to the relevant parameters of windcatcher, i.e. windcatcher attributes, windcatcher configurations and windcatcher technologies. The pros and cons of this green architectural feature have also been highlighted and the future research need in this realm of study is proposed.     

Unglazed Fiberglass Reinforced Polyester Solar Water Heater with Integrated Storage System

Theoretical and experimental investigations on an unglazed solar hot water heater with integrated storage system were conducted. The system was comprised of a collector and storage tank which was integrated into one unit. All parts of the system have been fabricated from fiberglass reinforced polyester (GFRP). The absorber plate has water tubes of semielliptical shape. The width and length of the absorber plate were 1.4 and 1.8?m, respectively. The absorber plate was fabricated from GFPR using a special resin composition that provides good thermal conductivity and absorptivity. The storage tank has a capacity of 496?L. The storage tank is of sandwich construction with a core material made of polyurethane foam that combines stiffness and lightness of the structure with very good thermal insulation properties. An average tank temperature of 53°C was achieved at an average solar radiation level of 700?W/m2 and ambient temperature of 28°C. The thermal efficiencies of the system were evaluated at 48 and 57% for cloudy and clear days, respectively. Transient performance of the system was predicted by solving the mathematical models consisting of energy balance equations of the system that have been converted to finite difference form and solved by a personal computer. The experimental results were in close agreement as has been found with the theoretical predictions.     

Performance of a dual-purpose solar continuous adsorption system

A conceptual design and performance of a dual-purpose solar continuous adsorption system for domestic refrigeration and water heating is described. Malaysian activated carbon and methanol are used as the adsorbent–adsorbate pair. The heat rejected by the adsorber beds and condensers during the cooling process of the refrigeration part is recovered and used to heat water for the purpose of domestic consumption. In a continuous 24-h cycle, 16.9 MJ/day of heat can be recovered for heating of water in the storage tanks. In the single-purpose intermittent solar adsorption system, this heat is wasted. The total energy input to the dual-purpose system during a 24-h operation is 61.2 MJ/day and the total energy output is 50 MJ/day. The latter is made up of 44.7 MJ/day for water heating and 5.3 MJ/day for ice making. The amount of ice that can be produced is 12 kg/day. Using typical value for the efficiency of evacuated tube collector of water heating system of 65%, the following coefficient of performances (COP's) are obtained: 44% for adsorption refrigeration cycle, 73% for dual-purpose solar water heater, 9.1% for dual-purpose solar adsorption refrigeration and 82.1% for dual-purpose of both solar water heater and refrigerator.     

Slip MHD liquid flow and heat transfer over non-linear permeable stretching surface with chemical reaction

In the present study the magnetohydrodynamic (MHD) liquid flow and heat transfer over non-linear permeable stretching surface has been presented in the presence of chemical reactions and partial slip. By means of proper similarity variables, the fundamental equations of the boundary layer are transformed to ordinary differential equations which for the fixed values of the x-coordinate along the plate local similarity solution would be valid appropriately. The ordinary differential equations are solved numerically using an explicit Runge–Kutta (4, 5) formula, the Dormand–Prince pair and shooting method. As a result, the velocity profiles, the concentration profiles, temperature profiles, the wall shear stress, the local Sherwood number and the local Nusselt number for the various values of the involved parameters of the problem are presented and discussed in details.     

Simulation and optimization of a LiBr solar absorption cooling system with evacuated tube collectors

Solar radiation is a clean form of energy, which is required for almost all natural processes on earth. Solar-powered air-conditioning has many advantages when compared to a conventional electrical system. This paper presents a solar cooling system that has been designed for Malaysia and similar tropical regions using evacuated tube solar collectors and LiBr absorption unit. The modeling and simulation of the absorption solar cooling system is carried out with TRNSYS program. The typical meteorological year file containing the weather parameters for Malaysia is used to simulate the system. The results presented show that the system is in phase with the weather, i.e. the cooling demand is large during periods that the solar radiation is high. In order to achieve continuous operation and increase the reliability of the system, a 0.8 m³ hot water storage tank is essential. The optimum system for Malaysia's climate for a 3.5 kW (1 refrigeration ton) system consists of 35 m² evacuated tubes solar collector sloped at 20°.     

Predicting average energy conversion of photovoltaic system in Malaysia using a simplified method

This paper is about predicting the average conventional energy conversion by a photovoltaic system in Malaysia. The calculation is based on average number of days in a month. Average hourly energy flows are estimated based on knowledge of array test parameters, monthly average of hourly ambient temperature and monthly average of daily hemispherical radiation. The monthly average of diffuse component of radiation can be predicted based on hemispherical radiation, by using an appropriate empirical correlation related to the monthly average of diffuse fraction to monthly average of clearness index. The values of hourly average radiation are estimated based on a statistical model.     

Numerical modeling of CdS/CdTe and CdS/CdTe/ZnTe solar cells as a function of CdTe thickness

CdTe-based solar cells have long been of interest for terrestrial usage because of their high potential conversion efficiency (in the range of 18–24%) with low-cost manufacturability and concern over environmental effects. In order to conserve material and address environmental pollution concerns as well as to reduce carrier recombination loss throughout the absorber layer, efforts have been carried out to decrease the thickness of the CdTe absorption layer to 1 μm. As a result, to date, the experimental part of this study has realized cell efficiencies of 15.3% and 11.5% with 7 and 1.2-μm-thick CdTe layers, grown by close-spaced sublimation (CSS) [N. Amin, T. Isaka, T. Okamoto, A. Yamada, M. Konagai, Jpn. J. Appl. Phys. 38 (8) (1999) 4666; N. Amin, T. Isaka, A. Yamada, M. Konagai, Sol. Energy Matter. Sol. Cells 67 (2001) 195]. Since some problems remain with such thin 1 μm CdTe layers, possible methods to realize higher efficiency have been investigated using novel solar cell structures, with the help of numerical analyses tools. In the theory part of this study, numerical analysis with a 1-D simulation program named NSSP (Numerical Solar Cell Simulation Program) has been used to simulate these structures. We investigated the viability of CdTe thickness reduction to 1 μm together with the insertion of higher band-gap materials (i.e., ZnTe) at the back contacts to reduce carrier recombination loss there. The study shows potential results of the thickness reduction of CdTe absorption layer for a conventional CdS/CdTe/Cu-doped C structure with around 16% efficiency for cells below 3  μm CdTe. Decreases were found in spectral response that suggest from minority carrier recombination loss at the back contact interface. A higher band-gap material like ZnTe has been inserted to produce a back surface field (BSF) to inhibit the minority carrier loss at the back contact. An increase in the efficiency to about 20% has been found for a 1 μm-thin CdTe cell, which can be attributed to the increased BSF effect at the back contact of thinner CdTe-based cells.     

Challenges and future developments in proton exchange membrane fuel cells

Fuel cell system is an advanced power system for the future that is sustainable, clean and environmental friendly. The importance of fuel cell as the future power system is discussed in the light of future fossil fuel depletion, impending international law on green house gases control and the national renewable energy policy. The modern development of the proton exchange membrane fuel cell (PEMFC) for the last 20 years is then briefly reviewed and the current status of international and national research and development of this type of are established. The review also discuss the remaining research and development issues that still need to be resolved before these fuel cells are available for commercial application. The main thrust in PEMFC research and development is to lower the cost of the fuel cell by reduction in membrane and electrocatalyst costs. Although Europe, USA, Canada and Japan are leading fuel cell research and development as commercialization, it is not too late for Malaysia to master this technology and to apply it to niche markets in the future.