Optimization of waste quail eggshells as biocomposites for polyaniline in ammonia gas detection

A simple, cost-effective, and novel chemical sensor for ammonia (NH₃) gas detection was developed from polyaniline (PANI)/quail eggshell (QES) composites. QES is a natural waste enriched in calcium carbonate. In this work, pure PANI was synthesized from chemical oxidation method and PANI/QES composites were prepared from physical mixing of QES with the synthesized PANI at different mass ratio. A series of complementary techniques including Fourier transform infrared and ultraviolet-visible spectrometers, scanning electron microscope with energy dispersive detection coupled with mapping, thermogravimetric analysis, and X-ray diffractometer were used to characterize the physicochemical and textural properties of the biocomposites. From the results, PANI/QES composite with a mass ratio of 1 exhibited the lowest NH₃ detection limit of 5.24 ppm with a linear correlation coefficient (R²) of close to unity (0.9932) between the signal and NH₃ gas concentration. As a whole, the PANI/QES biocomposites synthesized from this work exhibited excellent selectivity toward NH₃ gas even in the presence of other gas impurities, such as acetone, ethanol, and hexane. For the sensor reusability, the PANI/QES biocomposites can be reused in the application of NH₃ gas detection for at least 4 cycles.     

Investigation of Generalized SIFs of cracks in 3D piezoelectric media under various crack-face conditions

This paper investigates the influence of crack geometry, crack-face and loading conditions, and the permittivity of a medium inside the crack gap on intensity factors of planar and non-planar cracks in linear piezoelectric media. A weakly singular boundary integral equation method together with the near-front approximation is adopted to accurately determine the intensity factors. Obtained results indicate that the non-flat crack surface, the electric field, and the permittivity of a medium inside the crack gap play a crucial role on the behavior of intensity factors. The mode-I stress intensity factors (K_{\mathrm{I}}) for two representative non-planar cracks under different crack-face conditions are found significantly different and they possess both upper and lower bounds. In addition, K_{\mathrm{I}} for impermeable and semi-permeable non-planar cracks treated depends strongly on the electric field whereas those of impermeable, permeable, and semi-permeable penny-shaped cracks are identical and independent of the electric field. The stress/electric intensity factors predicted by permeable and energetically consistent models are, respectively, independent of and dependent on the electric field for the penny-shaped crack and the two representative non-planar cracks. Also, the permittivity of a medium inside the crack gap strongly affects the intensity factors for all crack configurations considered except for K_{\mathrm{I}} of the semi-permeable penny-shaped crack.     

SGBEM–FEM coupling for analysis of cracks in 3D anisotropic media

A weakly singular symmetric Galerkin boundary element method (SGBEM) is coupled with the standard finite element method (FEM) in order to establish an accurate and efficient numerical technique for analysis of fractures in three‐dimensional, anisotropic, linearly elastic media. In the strategy, the weakly singular SGBEM developed by Rungamornrat and Mear (textitInt. J. Solids Struct. 2008; 45 :1283–1301; Comput. Methods Appl. Mech. Engrg 2008; 197 :4319–4332) is utilized to model a small‐scale region containing the crack while the (possibly large and complex) compliment region is treated by the FEM. The coupled technique exploits the positive features of both methods; the SGBEM proves to be a convenient and highly accurate method for obtaining mixed‐mode stress intensity factors along the crack front, whereas the FEM is very efficient for modeling large‐scale problems in the absence of cracks. An important aspect of the formulation and implementation of the technique is that continuity of displacement and traction across the interface between the SGBEM and FEM regions is enforced in a weak sense. This allows the two regions (one modeled by the SGBEM and the other by the FEM) to be discretized independently without the need for the resulting meshes to conform on the interface separating the regions, and this flexibility in the discretization process leads to a significant reduction in the modeling effort. To demonstrate the utility and accuracy of the technique, several boundary value problems involving both embedded and surface breaking cracks are treated, and it is shown that the coupled technique yields highly accurate stress intensity factors that exhibit only a slight dependence upon mesh refinement. Copyright © 2010 John Wiley & Sons, Ltd.     

Pt electrodeposited on CeZrO4/MCNT as a new alternative catalyst for enhancement of ethanol oxidation

Electrocatalytic preparation of Pt-based nanocomposites has been investigated for improvement of direct ethanol fuel cells (DEFCs). In this study, new alternative catalysts of Pt-decorated cerium zirconium oxide-modified multiwalled carbon nanotubes (Pt/CeZrO₄/MCNT) were successively prepared to improve the activity of the ethanol oxidation reaction (EOR). The prepared CeZrO₄ with a face-centered cubic (fcc) structure compatibly dispersed onto MCNT provides abundant active Pt sites for highly active catalysts. The fcc-structured Pt was also satisfactorily decorated onto CeZrO₄/MCNT, resulting in highly active Pt. The Ce⁴⁺/Ce³⁺ redox property can promote oxygen vacancies to improve the electrochemical activity for oxidation of carbonaceous species. An increase in roughness and a stabilized catalyst structure can also be produced by inserting Zr⁴⁺ into the ceria metal oxide. The prepared Pt/20%CeZrO₄/MCNT catalysts present excellent electrochemical active surface area, mass activity, CO tolerance and high electron kinetic transfer with low resistance and high stability over commercial PtRu/C toward EOR. This promising catalyst material could be introduced to enhance the anodic oxidation reaction in DEFCs.     

Size effects in two-dimensional layered materials modeled by couple stress elasticity

In the present study, the effect of material microstructure on the mechanical response of a two-dimensional elastic layer perfectly bonded to a substrate is examined under surface loadings. In the current model, the substrate is treated as an elastic half plane as opposed to a rigid base, and this enables its applications in practical cases when the modulus of the layer (e.g., the coating material) and substrate (e.g., the coated surface) are comparable. The material microstructure is modeled using the generalized continuum theory of couple stress elasticity. The boundary value problems are formulated in terms of the displacement field and solved in an analytical manner via the Fourier transform and stiffness matrix method. The results demonstrate the capability of the present continuum theory to efficiently model the size-dependency of the response of the material when the external and internal length scales are comparable. Furthermore, the results indicated that the material mismatch and substrate stiffness play a crucial role in the predicted elastic field. Specifically, the study also addresses significant discrepancy of the response for the case of a layer resting on a rigid substrate.     

The effect of CuO on a Pt−Based catalyst for oxidation in a low-temperature fuel cell

Electrocatalytic oxidation of methanol, ethanol, and formic acid has currently attracted research attention for low-temperature fuel cells. However, the efficiencies of these fuel cells mainly depend on the electrocatalytic activities of Pt-based anodic catalysts due to the problems of low kinetics for small organic molecule electro-oxidation. An anode catalyst can be developed by the addition of some metal oxides into a Pt-based catalyst, which can effectively promote the electro-oxidation of fuels based on small organic molecules. In this work, a nanocomposite catalyst consisting of multi-wall carbon nanotubes (CNTs), copper oxide (CuO) and Pt nanoparticles was synthesized and used to improve fuel cell oxidation. Due to its low cost and oxophilic character, the metal oxide can play a major role in the oxidation of CO. The synthesis of xPt?yCuO/CNT electrocatalysts was executed through two steps: supporting of CuO nanoparticles on CNTs by the alcothermal method followed by Pt loading onto the prepared CuO/CNT by chemical reduction. The as-prepared catalysts were physically characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Raman spectroscopy, and electrochemical measurements. The results demonstrate that CuO is well dispersed onto the CNTs and that this oxide can further interact with the active Pt present on the as-prepared catalyst composites. The activity of various xPt?yCuO/CNT electrocatalysts was determined by cyclic voltammetry (CV), where x and y are the mass ratios of Pt and CuO, respectively. The presence of CuO was found to significantly contribute to enhanced electroactivity towards oxidation reactions. The 1Pt–3CuO/CNT electrocatalyst is a capable catalyst for improving low-temperature fuel cell applications.     

Soap bubbles in analytical chemistry. Conductometric determination of sub-parts per million levels of sulfur dioxide with a soap bubble

Soap bubbles provide a fascinating tool that is little used analytically. With a very low liquid volume to surface area ratio, a soap bubble can potentially provide a very useful interface for preconcentration where mass transfer to an interfacial surface is important. Here we use an automated system to create bubbles of uniform size and film thickness. We utilize purified Triton-X 100, a nonionic surfactant, to make soap bubbles. We use such bubbles as a gas-sampling interface. Incorporating hydrogen peroxide into the bubble provides a system where electrical conductance increases as the bubble is exposed to low concentrations of sulfur dioxide gas. We theoretically derive the conductance of a hollow conducting spherical thin film with spherical cap electrodes. We measure the film thickness by incorporating a dye in the bubble making solution and laser transmission photometry and find that it agrees well with the geometrically computed thickness. With the conductance of the bubble-making soap solution being measured by conventional methods, we show that the measured values of the bubble conductance with known bubble and electrode dimensions closely correspond to the theoretically computed value. Finally, we demonstrate that sub-ppm levels of SO(2) can readily be detected by the conductivity change of a hydrogen peroxide-doped soap bubble, measured in situ, when the gas flows around the bubble.     

Flow injection spectrophotometry using natural reagent from Morinda citrifolia root for determination of aluminium in tea

A flow injection (FI) spectrophotometric method with using natural reagent extracted from Morinda citrifolia root has been developed for determination of aluminium. The extract contained anthraquinone compounds which could react with Al³⁺ to form reddish complexes which had maximum absorption wavelength at 499.0 nm. The extract could be used as a reagent in FI system without further purification to obtain pure compound. A sensitive method for determination of aluminium in concentration range of 0.1-1.0 mg L⁻¹, with detection limit of 0.05 mg L⁻¹ was achieved. Relative standard deviations of 1.2% and 1.7% were obtained for the determination of 0.1 and 0.6 mg L⁻¹ Al³⁺ (n = 11). Sample throughput of 35 h⁻¹ was achieved with the consumption of 3 mL each of carrier and reagent solutions per injection. The developed method was successfully applied to tea samples, validated by the FAAS standard method. The method is simple, fast, economical and could be classified as a greener analytical method.