Second-Order optical non-linearities of {4-(dimethylamino) stilben z & e 4'-yl} dimesityl borane

Samples of {4-(dimethylamino) stilben Z & E 4'-yl} dimesityl borane (BNS) were synthesised and investigated for their non-linear optical properties. The results show that the quadratic hyperpolarisability of the Z-isomer is smaller than that of the E-isomer, the beta value found for the latter being as high as 60 × 10^?30 esu.     

2D crack growth simulation with an energetic approach

It is well known that the tearing resistance curve J–Δa is not a material property. A recent approach, based on an energetic critical parameter to model ductile tearing propagation, is used to model 3D effects. The approach considered in this work aims to estimate the dissipated energy in the fracture process during ductile tearing represented by an intrinsic parameter G_fr. A fracture criterion, which accounts for the crack extension length, is defined and lies on a critical energy release rate, noted G_c, which is compared to G_fr. Previously, this parameter was obtained from a numerical local energy release rate, which handicaps the application field of the approach: a fine mesh for the whole propagation area was needed and the criterion allowed only to model 1D propagation. A new manner to estimate G_c is then proposed in this article, based on the J plastic part variation, which allows to model 2D propagation by defining a local criterion. This new calculation method is validated on a CT specimen made in Tu52b ferritic steel, by comparing the results obtained from the two methods of G_c calculation. Then, the 2D crack growth case is studied, by modelling the propagation in a ring, loaded in compression. It is shown that a 3D effect, such as tunnel effect, could be successfully represented with this approach.     

Partner violence before and after individually based alcoholism treatment for male alcoholic patients.

This study examined partner violence in the year before and the year after individually based, outpatient alcoholism treatment for 301 married or cohabiting male alcoholic patients and used a demographically matched nonalcoholic comparison sample. In the year before treatment, 56% of the alcoholic patients had been violent toward their female partner, 4 times the rate of 14% in the comparison sample. In the year after treatment, violence decreased significantly to 25% of the alcoholic sample but remained higher than in the comparison group. Among remitted alcoholics after treatment, violence prevalence of 15% was nearly identical to the comparison sample and half the rate among relapsed patients (32%). Thus, partner violence decreased after alcoholism treatment, and clinically significant violence reductions occurred for patients whose alcoholism was remitted after treatment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

宽幅数码印刷机亮相IPEX 2002

当数码印刷、种类繁多的承印物以及经过改进的覆膜技术为印制精美耐用的户内、户外广告招贴的应用开辟了一条新的道路,建立了一种宽渠道的盈利模式时,宽幅印刷已经走向     

The UCLA Multidimensional Condom Attitudes Scale: Documenting the complex determinants of condom use in college students.

Describes the development and validation of the UCLA Multidimensional Condom Attitudes Scale (MCAS). The relationships between the MCAS and gender, sexual experience, intentions to use a condom, and past condom use were assessed. The MCAS has 5 distinct factors: (1) Reliability and Effectiveness of condoms, (2) the sexual Pleasure associated with condom use, (3) the stigma attached to persons who use condoms (Identity Stigma), (4) the Embarrassment About Negotiation and Use of condoms, and (5) the Embarrassment About the Purchase of condoms. Results strongly suggest that condom attitudes are multidimensional and thus cannot meaningfully be summed to a single global score. Results further indicate that men and women hold very different attitudes toward condoms. Implications of scale multidimensionality and directions for future research are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Surface designing of polypropylene by critical monitoring of the grafting conditions

The grafting of acrylic acid onto electron beam‐irradiated polypropylene was carried out using preirradiation method. The stability of peroxy radicals was investigated by electron spin resonance. It was found that the decay of peroxy radicals is much faster at 70°C than at 40°C and ambient temperature. The grafting has been observed to be strongly dependent on the monomer dilution in the reaction medium. The grafting was ascertained by attenuated total reflectance (ATR). The distribution of grafts across the samples was monitored by infrared microscopy. It was found that the graft management is considerably influenced by composition of the grafting medium. The grafting involving pure monomer leads to the surface enrichment with the polyacrylic acid chains. The samples grafted in pure monomer led to much lower contact angles as compared to the diluted monomer solution. The swelling of the grafted samples also showed a trend that was governed by the graft management. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 546–553, 2006     

Binding of tissue plasminogen activator to endothelial cells. The effect on functional properties. Localization of a ligand in the B-chain of tPA

The binding of 125I-labelled tissue plasminogen activator (tPA), the tPA A- or B-chain to endothelial cells (EC) were studied in suspensions of cultured human umbilical vein EC (HUVEC) or immortalized microvascular EC (HMEC). By determinations of the concentration-dependent binding it was shown that both the A-chain and the B-chain, which were isolated after partial reduction of two-chain tPA, contain ligands for binding to EC. The affinity for the B-chain was much higher than for the A-chain according to Scatchard analysis (Kd 24 and 515 nM, respectively), whereas the number of binding sites was higher for the A-chain than for the B-chain (Bmax 8 x 10(5) and 1.2 x 10(5), respectively). There were no cross interactions between the A- and B-chains and their binding sites. The binding of tPA to EC induced an almost 100-fold increase of the activation rate when compared to the same amount of enzyme in free solution, which in contrast to the fibrin-induced stimulation was not inhibited by antibodies against fibrin. The enzymatic activity of the B-chain was much less affected by the association to the cells. Both tPA and the tPA B-chain were largely protected against inhibition by an excess plasminogen activator type-1 (PAI-1) when bound to EC, whereas the same amount of free tPA was totally inactivated. The competition studies strongly indicated that an N-terminal segment in the B-chain, AKHRRSPGER, may be the ligand part of the B-chain. It is interesting to note that this polypeptide segment also participates in a binding site for PAI-1, necessary for effective inhibition. This implies a possible competition between PAI-1 and a tPA-receptor for binding of tPA. High molecular weight urokinase had no quenching effect on the binding of the B-chain to EC.     

Highly integrated direct conversion receiver for GSM/GPRS/EDGE with on-chip 84-dB dynamic range continuous-time /spl Sigma//spl Delta/ ADC

This paper describes a highly digitized direct conversion receiver of a single-chip quadruple-band RF transceiver that meets GSM/GPRS and EDGE requirements. The chip uses an advanced 0.25-/spl mu/m BiCMOS technology. The I and Q on-chip fifth-order single-bit continuous-time sigma-delta (/spl Sigma//spl Delta/) ADC has 84-dB dynamic range over a total bandwidth of /spl plusmn/135 kHz for an active area of 0.4 mm/sup 2/. Hence, most of the channel filtering is realized in a CMOS IC where digital processing is achieved at a lower cost. The systematic analysis of dc offset at each stage of the design enables to perform the dc offset cancellation loop in the digital domain as well. The receiver operates at 2.7 V with a current consumption of 75 mA. A first-order substrate coupling analysis enables to optimize the floor plan strategy. As a result, the receiver has an area of 1.8 mm/sup 2/.     

Bridging the generation gap between text planning and linguistic realization

Text planning is traditionally done as a separate process, independent of linguistic realization. However, I show in this paper that it is essential for a text planner to know the linguistic consequences of its actions. The choice of how to realize an element affects how much information is conveyed (e.g., “Floyd arrived safely in Boston” vs. “Floyd landed safely at Logan”) and what other information can be added (e.g., “Peter was deciding for an hour” vs. *“Peter made a decision for an hour”). The choice of realization also affects how the relative salience of the elements being expressed will be perceived (e.g., “The green car is in the garage” vs. “The car in the garage is green”). I have defined an intermediate level of representation for text planning, called the Text Structure. It is an abstract linguistic level that reflects germane linguistic constraints while abstracting away from syntactic detail. This representation allows the text planner to have greater control over the decisions, so that it can take advantage of the expressiveness of language to convey subtleties of meaning. More importantly, the Text Structure allows the generation process overall to be incremental, since it ensures that the text plan being composed will always be expressible in the language. La planification de textes est habituellement réalisée séparément, sans tenir compte de la réalisation linguistique. Cependant, ľauteur demontre dans cet article qu'il est essentiel à un planificateur de textes de connai̊tre les conséquences linguistiques de ses actions. Le choix de la méhode de réalisation ?un élément influe sur la quantité?informations qui est transmise (par ex.: 〈〈 Floyd est arrivé sain et sauf à Boston 〉〉 et 〈〈 Floyd a atterri sain et sauf àľaéroport Logan 〉〉) et sur quelle autre information peut ětre ajoutée. Le choix de la méthode de réalisation influe également sur la façon dont les caractères saillants des ééments qui sont exprimés seront perçus (par ex.: 〈〈 la voiture verte est dans le garage 〉〉 et 〈〈 la voiture dans le garage est verte 〉〉). L'auteur a défini un niveau intérmediaire de représentation pour la planification de textes qu'il a appelé structure de texte. Il; s'agit ?'un niveau linguistique abstrait qui refléte les contraintes linguistiques appropriées tout en s'éloignant du détail syntaxique. Cette représentation permet au planificateur de textes ?avoir un meilleur contrǒle des décisions, et done de tirer profit de la force ?expression du langage afin de tenir compte des subtiliés de sens. Plus important encore, la structure de texte permet au processus de génération ?ětre incrémentiel, car elle s'assure que le plan de texte en voie de composition soit toujours exprimable dans le langage.